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Part of the book series: Springer Series in Solid-State Sciences ((SSSOL,volume 10))

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Abstract

The covalency of the elemental semiconductors may be described in different ways in the different phonon models. In the shell model, COCHRAN [9.25] found that interionic core-shell interactions are important for the description of the flat TA branches in Si, Ge, and α-Sn. An alternative approach stems from the molecular picture using valence field forces [9.10]. The most pictorial way of description is the bond charge model (BCM) which in its general form [9.12] is a very powerful method to understand the mechanical properties of these crystals, although the dielectric properties are not well described.

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© 1979 Springer-Verlag Berlin Heidelberg

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Bilz, H., Kress, W. (1979). Diamond Structure Crystals. In: Phonon Dispersion Relations in Insulators. Springer Series in Solid-State Sciences, vol 10. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-81347-4_9

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  • DOI: https://doi.org/10.1007/978-3-642-81347-4_9

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-81349-8

  • Online ISBN: 978-3-642-81347-4

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