CIDEP and CIDNP in Radiation Chemistry. Polarization Transfer between Electron and Nuclear Spin Systems

  • Alexander D. Trifunac
Conference paper


Polarization transfer between electron and nuclear spin systems (Overhauser CIDNP) can be observed in radiolytic reactions involving the hydrated electron. Time-resolved EPR provides details of CIDEP and flow FTNMR provides information on CIDNP in pulse radiolysis.


Hydrated Succinate Photolysis Phosphite Hypophosphite 


  1. 1.
    R. W. Fessenden and N. C. Verma, J. Am. Chem. Soc. 98, 243 (1976).CrossRefGoogle Scholar
  2. 2.
    A. D. Trifunac, K. W. Johnson, B. E. Clifft, and R. H. Lowers, Chem. Phys. Lett. 35, 566 (1975).ADSCrossRefGoogle Scholar
  3. 3.
    N. C. Verma and R. W. Fessenden, J. Chem. Phys. 65, 2139 (1976).ADSCrossRefGoogle Scholar
  4. 4.
    A. D. Trifunac and D. J. Nelson, J. Am. Chem. Soc. 99, 1745 (1977).CrossRefGoogle Scholar
  5. 5.
    F. J. Adrian, H. M. Vyas, and J. K. S. Wan, J. Chem. Phys. 65, 1454 (1976).ADSCrossRefGoogle Scholar
  6. 6. (a)
    J. Bargon and H. Fischer, Z. Naturforsch. 22A, 1556 (1967);ADSGoogle Scholar
  7. (b).
    R. G. Lawler, Soc. 89, 5519 (1967).Google Scholar
  8. 7. (a)
    M. J. Thomas, P. J. Wagner, M. L. Manion-Schilling, and H. D. Roth, J. Am. Chem. 99, 3842 (1977);CrossRefGoogle Scholar
  9. (b).
    M. L. Manion-Schilling, R. S. Hutton, and H. D. Roth, in pressGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 1979

Authors and Affiliations

  • Alexander D. Trifunac
    • 1
  1. 1.Chemistry DivisionArgonne National LaboratoryArgonneUSA

Personalised recommendations