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I3C NMR Spectroscopy of Some Pyrimidine Nucleosides, 5’-AMP-di-Na-Salt, NAD+ and NADH-di-Na-Salt. The Analysis of Coupling Constants 3JI3C6-HI’, 3JI3C2-HI’ and 3JI3C8-HI’ and Rotary Isomerism about a Glycosidic Bond

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Magnetic Resonance and Related Phenomena

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Abstract

Conformational Properties of 5 J-uridinc (I) 5 J-2’-deoxy-uridine(2), 5 J-2’-chlorouridine (3), 5’-AMP-di-Na-salt (4), NAD+ (5) and NADH-di-Na-salt (6) have been investigated by the I3C NMR spectroscopy method. Chemical shifts of carbon atoms of carbohydrate fragments in (5) and (6) are corrected and spin-spin couping constants (SSCC) 3JI3C6-HI’, 3JI3C2-HI’ and 3JI3C8-HI’ as well as glycosidic torsional angles have been determined. It is shown that rotatory isomerism changes with different substituents at C-2’ of a carbohydrate fragment as well as in β,γ pydidine base positions.

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Authors and Affiliations

  1. Institute of Physics, Byelorussian SSR Academy of Sciences, Minsk, 230602, USSR

    A. F. Abramov

Authors
  1. A. F. Abramov
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Editors and Affiliations

  1. Department of Physics, Institute of Cybernetics of the Academy of Sciences of the Estonian SSR, USSR

    E. Kundla , E. Lippmaa  & T. Saluvere ,  & 

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© 1979 Springer-Verlag Berlin Heidelberg

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Abramov, A.F. (1979). I3C NMR Spectroscopy of Some Pyrimidine Nucleosides, 5’-AMP-di-Na-Salt, NAD+ and NADH-di-Na-Salt. The Analysis of Coupling Constants 3JI3C6-HI’, 3JI3C2-HI’ and 3JI3C8-HI’ and Rotary Isomerism about a Glycosidic Bond. In: Kundla, E., Lippmaa, E., Saluvere, T. (eds) Magnetic Resonance and Related Phenomena. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-81344-3_433

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  • DOI: https://doi.org/10.1007/978-3-642-81344-3_433

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-81346-7

  • Online ISBN: 978-3-642-81344-3

  • eBook Packages: Springer Book Archive

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