Abstract
Low temperature (193°K) spectra of menthol isomers in CH2Cl2 solution show that menthol and neomenthol exist practically in one conformation with equatorial alkyl groups; in isomenthol and neoisomenthol conformations with axial methyl group are more favoured (K193° ≃ 2 and 1.5). T1-s from menthol isomers are in accordance with their relative thermodynamic stability.
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References
F. Bohlmann, R. Zeisberq and E. Klein, Org.Magn.Resonance 7, 426 (1975).
T. Pehk, E. Lippmaa, Proceedings of the XlXth Congress Ampere, Heidelberg 1976, p. 329.
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© 1979 Springer-Verlag Berlin Heidelberg
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Pehk, T. (1979). Conformational Analysis and Carbon-13 Spin-Lattice Relaxation in Menthol Isomers. In: Kundla, E., Lippmaa, E., Saluvere, T. (eds) Magnetic Resonance and Related Phenomena. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-81344-3_432
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DOI: https://doi.org/10.1007/978-3-642-81344-3_432
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