Abstract
Configuration stability and stereodynamics of different ionic particles in alcaline derivatives of 1,3-dicarbonyl compounds’ solutions were investigated by 1H and 13C spectroscopy and conductometry. In aprotic dipolar solvents and methanol free ions were proved to give the main contribution to the “trans” (E,Z and E,E) form. E,Z⇄E,E transition was shown to be a rotation in a “free” enolate-anion.
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
A. Petrov, S. Esakov and B. Ershov, Russian Journal of Organic Chemistry, 11, 680, (1975);
A. Petrov, S. Esakov and B. Ershov, Russian Journal of Organic Chemistry, 12, 775 (1976).
A. Petrov and B. Ershov, ibid, 14, 867 (1978).
A. Petrov, S. Bizunock and B. Ershov, ibid., 14, 447 (1978).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1979 Springer-Verlag Berlin Heidelberg
About this paper
Cite this paper
Ershov, B., Petrov, A., Esakov, S. (1979). NMR Investigation of Alkaline Derivatives of 1,3-Dicarbonyl Compounds. In: Kundla, E., Lippmaa, E., Saluvere, T. (eds) Magnetic Resonance and Related Phenomena. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-81344-3_422
Download citation
DOI: https://doi.org/10.1007/978-3-642-81344-3_422
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-81346-7
Online ISBN: 978-3-642-81344-3
eBook Packages: Springer Book Archive