Quadrupolar Relaxation Mechanism of Ionic Nuclei 7Li and 23Na in Basic Solvents

  • A. I. Mishustin
  • A. I. Podkovyrin
  • Yu. M. Kessler
Conference paper

Abstract

It is found that T4 of 7Li and23Na in diluted LiClO4 (NaClO4) solutions in basic solvents (amides, dimethylsulfoxide, acetone) are not affected by addition of “inert” solvents (acetonitrile, nitromethane, CH2Cl2) up to x ≈ 0,7. It is shown that T,is dominated by the chemical exchange rather than diffusional motions

Keywords

Acetone DMSO Acetonitrile Amide CH2Cl2 

References

  1. 1.
    A.I. Miehustin, Yu.M. Kessler, J. Solution Chem. 4, 779 (1975)CrossRefGoogle Scholar
  2. 2.
    Yu.M. Kessler, A.I. Mishuatin, A.I. Podkovyrin, J. Solution Chem. 6, 111 (1977)CrossRefGoogle Scholar
  3. 3.
    A.K. Covington, K.E. Newman, T.H. Lilley, JCS, Faraday Tr. 1, p. 973 (1973)CrossRefGoogle Scholar
  4. 4.
    K.A. Valiev, Thesis, Sverdlovsk (1963)Google Scholar
  5. 5.
    C.A. Melendres, H.G. Hertz, J. Chem. Phys. 61, 4156 (1974)ADSCrossRefGoogle Scholar
  6. 6.
    V.I. Chizhik, Magn. Res. Relat. Phen. Proc. XVI Congr. AMPERE, Bucharest (1971)Google Scholar
  7. 7.
    A.G. Marahall, J. Chem. Phys. 52, 2527 (1970)ADSCrossRefGoogle Scholar
  8. 8.
    H. Wennerstrom, Molec. Phys. 24, 69 (1972)ADSCrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 1979

Authors and Affiliations

  • A. I. Mishustin
    • 1
  • A. I. Podkovyrin
    • 1
  • Yu. M. Kessler
    • 1
  1. 1.Department of General and Physical ChemistryMoscow Institute of Chemical EngineeringMoscowUSSR

Personalised recommendations