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Magnetic Resonance in Superionic Conductors

Chapter
Part of the Topics in Current Physics book series (TCPHY, volume 15)

Abstract

Nuclear magnetic resonance can be a powerful tool for studying motions of ions and therefore has had extensive application [6.1] in the field of superionic conductors. Being concerned here with basic physics, we make the following distinction between superionic (SI) and low-ionic-conductivity materials: in the latter only a small number of independent particles or vacancies hop whereas large numbers are involved in the former. Thus correlated motion is a major aspect of the problem, and it is of interest to see what can be learned about this from nuclear magnetic resonance (NMR). To understand the features of the dynamics which can be delineated and how NMR might be useful in distinguishing correlated from independent particle motion, we consider this technique in conjunction with bulk conductivity and infrared or Raman spectroscopy (Chap.5).

Keywords

Nuclear Magnetic Resonance Electron Paramagnetic Resonance Electron Paramagnetic Resonance Spectrum Superionic Conductor Paramagnetic Impurity 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 6.1
    M.S. Whittingham, B.G. Silbernagel: In Solid Electrolytes: General Principles, Characterization, Materials, Applications, ed. by P. Hagenmuller, W. van Gool (Academic Press, New York 1977).Google Scholar
  2. 6.2
    R. Kubo: J. Phys. Soc. Jpn. 12, 570 (1957).MathSciNetADSCrossRefGoogle Scholar
  3. 6.3
    C. Zener: In Imperfections in Nearly Perfect Crystals, ed. by W. Shockley, J.H. Hollomon, R. Maurer, F. Seitz (Wiley and Sons, New York 1950).Google Scholar
  4. 6.4
    P.M. Richards: Phys. Rev. B 16, 1393 (1977).MathSciNetADSCrossRefGoogle Scholar
  5. 6.5
    P.A. Fedders: Phys. Rev. B 17, 40 (1978).ADSCrossRefGoogle Scholar
  6. 6.6
    S. Alexander, P. Pincus: Phys. Rev. B 18, 2011 (1978).ADSCrossRefGoogle Scholar
  7. 6.7
    A.N. Garroway, R.M. Cotts: Phys. Rev. A 7, 635 (1973).ADSCrossRefGoogle Scholar
  8. 6.8
    A.D. Le Claire: In Fast Ion Transport in Solids, ed. by W. van Gool (North-Holland, New York 1973).Google Scholar
  9. 6.9
    A. Abragam: The Principles of Nuclear Magnetism (Oxford University Press, New York 1961) Chap.8.Google Scholar
  10. C.P. Slichter: Principles of Magnetic Resonance, 2nd ed. Springer Series in Solid-State Sciences, Vol.1 (Springer, Berlin, Heidelberg, New York 1978).Google Scholar
  11. 6.10
    Ref.6.9, pp.58-63.Google Scholar
  12. 6.11
    D.C. Look, I.J. Lowe: J. Chem. Phys. 44, 2995 (1966).ADSCrossRefGoogle Scholar
  13. 6.12
    R. Kubo, K. Tomita: J. Phys. Soc. Jpn. 9, 888 (1954).ADSCrossRefGoogle Scholar
  14. 6.13
    R.D. Hogg, S.P. Vernon, V. Jaccarino: Phys. Rev. Lett. 39, 481 (1977).ADSCrossRefGoogle Scholar
  15. 6.14
    P.M. Richards: Phys. Rev. B 18, 6358 (1978).ADSCrossRefGoogle Scholar
  16. 6.15
    N. Bloembergen, E.M. Purcell, R.V. Pound: Phys. Rev. 73, 679 (1948).ADSCrossRefGoogle Scholar
  17. 6.16
    R.E. Walstedt: Phys. Rev. Lett. 19, 146, 816 (1967).ADSCrossRefGoogle Scholar
  18. 6.17
    P.A. Fedders: Phys. Rev. B 13, 2768 (1976).ADSCrossRefGoogle Scholar
  19. 6.18
    D. Wolf: J. Mag. Res. 17, 1 (1975).Google Scholar
  20. 6.19
    U.v. Alpen, H. Schulz, G.H. Talat, H. Böhm: Solid State Commun. 23, 911 (1977).ADSCrossRefGoogle Scholar
  21. 6.20
    W.L. Roth, F. Reidinger, S. La Placa: In Superionic Conductors, ed. by G.D. Mahan, W.L. Roth (Plenum Press, New York 1976) and references therein.Google Scholar
  22. 6.21
    P.M. Richards, F. Borsa: In Local Properties at Phase Transitions, Proceedings of the International School of Physics “Enrico Fermi”, Course LIX, ed. by K.A. Müller, A. Rigamonti (North-Holland, New York 1976).Google Scholar
  23. 6.22
    B.G. Silbernagel, F.R. Gamble: Phys. Rev. Lett. 32, 1436 (1974).ADSCrossRefGoogle Scholar
  24. 6.23
    P.M. Richards: Solid State Commun. 25, 1019 (1978).ADSCrossRefGoogle Scholar
  25. 6.24
    D. Wolf: J. Phys, C 10, 3545 (1977).ADSCrossRefGoogle Scholar
  26. 6.25
    J.C.. Wang, M. Gaffari, S. Choi: J. Chem. Phys. 63, 772 (1975).ADSCrossRefGoogle Scholar
  27. 6.26
    J.B. Boyce, J.C. Mikkelsen, M. O’Keeffe: Solid State Commun. 21, 955 (1977).ADSCrossRefGoogle Scholar
  28. 6.27
    D.M. Follstaedt, P.M. Richards: Phys. Rev. Lett. 37, 1571 (1976).ADSCrossRefGoogle Scholar
  29. 6.28
    C. Korn, D. Zamir: J. Phys. Chem. Solids 31, 489 (1970).ADSCrossRefGoogle Scholar
  30. 6.29
    D. Jerome, J.P. Boilot: J. Phys. (Paris) 35, L–129 (1974).Google Scholar
  31. 6.30
    R.E. Walstedt, R. Dupree, J.P. Remeika, A. Rodriguez: Phys. Rev. B 15, 3442 (1977).ADSCrossRefGoogle Scholar
  32. 6.31
    J.B. Boyce, J.C. Mikkelsen: Bull. Am. Phys. Soc. 21, 285 (1976).Google Scholar
  33. 6.32
    B.A. Huberman, J.B. Boyce: Solid State Commun. 25, 759 (1978).ADSCrossRefGoogle Scholar
  34. 6.33
    H. Schulz, V. Tscherry: Acta Crystallogr. B 28, 2168 (1972).CrossRefGoogle Scholar
  35. 6.34
    P.M. Richards: Phys. Lett. 69A, 58 (1978).ADSGoogle Scholar
  36. 6.35
    P.A. Fedders: Phys. Rev. B 17, 2098 (1978).ADSCrossRefGoogle Scholar
  37. 6.36
    B. Morosin, J.C. Mikkelsen: Acta Cryst. B 35 (1979, in press).Google Scholar
  38. 6.37
    D.M. Follstaedt, R.M. Biefeld: Phys. Rev. B. 18, 5928 (1978).ADSCrossRefGoogle Scholar
  39. 6.38
    F.G. Brown: The Physics of Solids (Benjamin, New York 1967) Chap.10.Google Scholar
  40. 6.39
    B. Morosin, P.S. Peercy: Phys. Lett. 53A, 147 (1975).ADSGoogle Scholar
  41. 6.40
    D.M. Follstaedt: Unpublished.Google Scholar
  42. 6.41
    K.D. Becker, G.W. Herzog, D. Kanne, H. Richtering, E. Stadler: Ber. Bunsenges. Phys. Chem. 14, 527 (1970).Google Scholar
  43. J.B.
    Boyce, B.A. Huberman: Solid State Commun. 21, 31 (1977).CrossRefGoogle Scholar
  44. 6.42
    G. Burns, F.H. Dacol, M.W. Shafer, R. Alben: Solid State Commun. 24, 753 (1977).ADSCrossRefGoogle Scholar
  45. 6.43
    J.B. Boyce: Private communication.Google Scholar
  46. 6.44
    P.M. Richards: Unpublished.Google Scholar
  47. 6.45
    M.S. Whittingham, P.S. Connell, R.A. Huggins: J. Solid State Chem. 5, 321 (1972).ADSCrossRefGoogle Scholar
  48. 6.46
    E.L. Venturini, J.B. Boyce: Private communication.Google Scholar
  49. 6.47
    V. Jaccarino: Private communication.Google Scholar
  50. 6.48
    A. Abragam, B. Bleaney: Electron Paramagnetic Resonance of Transition Ions (Oxford University Press, New York 1970).Google Scholar
  51. 6.49
    C. Evora, V. Jaccarino: Phys. Rev. Lett. 39, 1554 (1977).ADSCrossRefGoogle Scholar
  52. 6.50
    G.R. Luckhurst: In Electron Spin Relaxation in Liquids, ed. by L.T. Muus, P.W. Atkins (Plenum Press, New York 1972) p.313.CrossRefGoogle Scholar
  53. 6.51
    A. Carrington, G.R. Luckhurst: Mol. Phys. 8, 125 (1964).ADSCrossRefGoogle Scholar
  54. 6.52
    W.M. Walsh, J. Jeener, N. Bloembergen: Phys. Rev. 139, A1338 (1965).ADSCrossRefGoogle Scholar
  55. 6.53
    R.S. Title, G.V. Chandrashekhar: Solid State Commun. 20, 405 (1976).ADSCrossRefGoogle Scholar
  56. 6.54
    J.P. Boilot, J. Thery, R. Collonges: Mater. Res. Bull. 8, 1143 (1973).CrossRefGoogle Scholar
  57. 6.55
    H.S. Story, W.C. Bailey, I. Chung, W.L. Roth: In Ref.20.Google Scholar
  58. 6.56
    L.V. Dmitrieva, Z.N. Zonn, G.M. Shakhdinarov: Sov. Phys.-Solid State 12, 32 (1970).Google Scholar
  59. 6.57
    R.C. Barklie, K. O’Donnell, A. Murtagh: J. Phys. C 10, 4815 (1977).ADSCrossRefGoogle Scholar
  60. J.P. Boilot, A. Kahn, J. Thery, R. Collongues, J. Antoine, D. Viven, C. Chevrette, D. Gourier: Electrochim. Acta 22, 741 (1977).CrossRefGoogle Scholar

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© Springer-Verlag Berlin Heidelberg 1979

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