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Phase Equilibria and Phase Diagrams

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Part of the Springer Series in Solid-State Sciences book series (SSSOL, volume 5)

Abstract

Crystal growth can be called, in a wide sense, the science and technology of controlling phase transitions that lead to a (single crystalline) solid. Hence thorough knowledge of the thermodynamics of phase transitions and skill in deducing from phase diagrams the consequences for crystal growth are among the keys to efficient work in that area. In this chapter we will familiarize ourselves with the thermodynamic basis of phase diagrams. The discussion will first center upon liquid-solid equilibria and later expand the concepts to vapor-condensed phase equilibria. This general presentation is then illustrated in Chap. 4 with a broad discussion of specific systems and the consequences of their phase equilibria for the selection of specific crystal growth techniques. Large parts of this chapter are structured after a monograph on principles of phase diagrams by GORDON [3.1]. The presentation has also benefited from recent reviews by YEH [3.2] and KRÖGER [3.3]. For supplementary reading a more advanced presentation by PELTON and THOMPSON [3.33] is particularly recommended.

Keywords

Phase Diagram Triple Point Isothermal Section Liquid Solution Invariant Reaction 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

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Copyright information

© Springer-Verlag Berlin Heidelberg 1979

Authors and Affiliations

  1. 1.Department of Physics and Department of Materials Science and EngineeringUniversity of UtahSalt Lake CityUSA

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