Abstract
Liquid crystals are excellent solvents for organic molecules. Non-mesomorphic guest molecules may be incorporated in liquid crystals up to fairly high concentrations without destruction of the.distant order prevailing in the liquid crystalline matrix. The guest molecules couple to the anisotropic intermolecular interaction field of the oriented host but can diffuse rather freely within the solvent. The anisotropic guest-host interaction leads to a highly anisotropic tumbling motion of nonspherical guest molecules within the liquid crystal matrix. In the time average this anisotropic tumbling leads to an appreciable orientation of the guest with respect to the axis of preferred solvent alignment. The liquid crystalline solutions can be oriented homogeneously by electric, magnetic or mechanical forces, that is bulk samples of highly oriented solute molecules can be easily prepared.
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References
Kelker, H., Scheurle, B.: Angew. Chem. (Internat. Edit.) 8, 884 (1969).
Spiesecke, H., Jourdan, J. B.: Angew. Chem. (Internat. Edit.) 6, 450 (1967).
Pohl, L., Steinsträßer, R.: Z. Naturforsch. 26b, 26 (1971).
Steinsträßer, R.: Angew. Chem. 84, 636 (1972).
Englert, G., Saupe, A.: Mol. Cryst. 1, 503 (1966).
Meiboom, S., Luz, Z.: Fourth International Liquid Crystal Conference, Kent, Ohio (1972).
Sackmann, E., Möhwald, H.: J. Chem. Phys. 58, 5407 (1973).
Sackmann, E., Meiboom, S., Snyder, L. C., Meixner, A. E., Dietz, R. E.: J. Am. Chem. Soc. 90, 3567 (1968a).
Robinson, C.: Mol. Cryst. 1, 467 (1966).
Panar, W., Phillips, W. D.: J. Am. Chem. Soc. 90, 3880 (1968).
Samulski, E., Tobolsky, A. V.: Mol. Cryst. and Liq. Cryst. 7, 433 (1969).
Lawson, K. D., Flautt, T. J.: J. Am. Chem. Soc. 89, 5489 (1967).
Black, P. J., Lawson, K. D., Flautt, T. J.: J. Chem. Phys. 50 542 (1969).
Mandell, L, Fontell, K., Ekwall, P.: Adv. Chem. Ser. 63, 89 (1967).
Seelig, J.: J. Am. Chem. Soc. 92, 3881 (1970).
Cladis, P. E., Rault, J., Burger, J.-P.: Mol. Cryst. and Liq. Cryst. 13, 1 (1971).
Brière, G., Gaspard, F.: Chem. Phys. Letters 1 706 (1968).
Borrett, S., Brière, G.: J. Chim. Phys. 9, 970 (1965).
Berremen, D Phys. Rev. Letters 28 1683 (1972).
Caesar, G. P., Gray, H. B.: J. Am. Chem. Soc. 91 191 (1969).
Maier, W., Englert, G.: Z. Elektrochemie 62, 1020 (1958).
Kelker, H., Hatzand, R., Wirzing, G.: Z. Analyt. Chem. 267 161 (1973).
Haas, W., Adams, J., Flannery, J. B.: Phys. Rev. Letters, 25, 1326 (1970).
Mainusch, K.-J., Müller, U., Pollmann, P., Stegemeyer, H.: Z. Naturforsch. 27A 1677 (1972).
Helfrich, W., Oh, Ch. S.: Mol. Cryst. and Liq. Cryst. 14 289 (1971).
Sackmann, E., Meiboom, S., Snyder, L. C.: J. Am. Chem. Soc. 89, 5981 (1967).
Sackmann, E.: Chem. Phys. Letters 3, 253 (1969).
Bässler, H.: Festkörperprobleme XI, (O. Madelung Ed.), Vieweg/Pergamon: 1971.
Wysocki, J. J., Adams, J., Haas, W.: Phys. Rev. Letters 20 1024 (1968).
Meyer, R. B.: Appl. Phys. Letters 9, 281 (1968).
De Gennes, P. G.: Solid State Commun. 6, 163 (1968).
Bässler, H., Labes, M. M.: J. Chem. Phys. 51 1846 (1969).
Diehl, P., Khetrapal, C. L, Kellerhals, H. P., Lienhard, U., Niederberger, W.: J. Magn. Res. 1 527 (1969).
Buckingham, A. D., Pople, J. A.: Trans. Farad. Soc. 59, 2421 (1963).
Ducros, P.: Bull. Soc. Franc. Mineral. Crist. 83, 85 (1960).
Andrew, E. R., Wynn, V. T.: Proc. Roy. Soc., 291A, 257 (1966).
Saupe, A., Englert, G.: Phys. Rev. Letters 11, 402 (1963).
Englert, G., Saupe, A.: Z. Naturforsch. 19a 172 (1964).
Saupe, A.: Angew. Chem. 80 99 (1969).
Meiboom, S., Snyder, L. C.: Science 162, 1337 (1968).
Luckhurst, G. R.; Quart. Rev. Chem. Soc. 22, 179 (1968).
Hilbers, C. W., Mac Lean, C.: In N.M.R. Basic Principles and Progress Vol. 7 (Diehl, P., Fluck E., Kosfeld, R., Eds) (Springer-Verlag Berlin) 1972.
Diehl, P., Khetrapal, C. L.: N.M.R. Basic Priniciples and Progress Vol. 1 (Diehl, P.,Fluck, E., Klosfeld, R., Eds.) (Berlin Springer-Verlag) 1970.
Meiboom, S., Snyder, L. C.: Acc. Chem. Res. 4 81 (1971).
Snyder, L. C.: J. Chem. Phys. 43 4041 (1965).
Buckingham, A. D., Love, I.: J Magn. Resonance 2 338 (1970).
Krugh, T. R., Bernhein, R. A.: J. Am. Soc. 91 2385 (1969).
Herschbach, D. R., Laurie, V. W.: J. Chem. Phys. 37, 1668 (1962).
Saupe, A., Englert, G., Povh, A.: Adv. Chem. Ser. 63, 51 (1967).
Meiboom, S., Snyder, L. C.: J Am. Chem. Soc. 89, 1038, 5981, (1967)
Bastiansen, O., Fritsch, F. N., Hedgerg, K.: Acta Cryst. 17 538 (1964).
Sackmann, E.: J Chem. Phys. 51, 2984 (1969).
Gazzard, J. J., Sheppard, N.: Mol. Phys. 21 169 (1971).
Cocivera, M.: J. Chem. Phys., 47, 3061 (1967).
Diehl, P., Henrichs, P. M., Niederberger, W.: Mol. Phys. 20 139 (1971).
Sackmann, E., Meiboom, S., Snyder, L. C.: J. Am. Chem. Soc., 90 2183 (1968).
Luckhurst, G. R.: In Liquid Crystals and Plastic Crystals (Gray, G. W., Winsor, P. A. Eds) (Ellis Horwood Limited Chichester) (1974).
Luckhurst, G. R.: Fourth International Liquid Crystal Conference, Kent, Ohio, USA (1972).
Krebs, P., Sackmann, E.: Mol. Phys. 23, 437 (1972).
Krebs, P.: Doctoral Thesis, Stuttgart (1973).
Hubbell, W. L., McConnell, H. M.: J. Am. Chem. Soc. 93, 314 (1971).
Jost, P., Waggoner, A. S., Griffith, O. H.: In: “Structure and Function of Biological Membranes” (Rothfield, L. J., Ed.) New York: Academic Press pp. 84–144 1971.
Sackmann, E., Träuble, H.: J. Am. Chem. Soc. 94, 4482 (1972).
Smith, I. C. P.: “The Spin Label Method” in Biological Application of Electron Spin Resonance. (Swartz, H. M., Bolton, J. R., Brog, D. C., Eds.) New York: Wiley Interscience, pp. 483–539 1972.
Falle, H. R., Luckhurst, G. R.: J. Magn. Resonance 3, 161 (1970).
Falle, H. R., Luckhurst, G. R., Lemaire, H., Morat, C., Rassat, A., Rey, P.: Mol. Phys.11, 49 (1966).
Agranat, I., Rabinovitz, M., Falle, H. R., Luckhurst, G. R., Ockwell, J. N.: J. Chem. Soc. (1970), 294.
Lemaire, H.: J. Chim. Phys. 64, 559 (1967).
Krebs, P., Sackmann, E., Voss, J.: Chem. Phys. Letters 8, 417 (1972).
Glarum, S. H., Marshall, J. H.: J. Chem. Phys. 44, 2884 (1966).
Glarum, S. H., Marshall, J. H.: J. Chem. Phys., 46, 55 (1967).
Möbius, K., Haustein, H., Plato, M.: Z. Naturforsch. 23a, 1626 (1968).
McConnell, H. M., Strathdee, J.: Mol. Phys. 2, 129 (1959).
McLachlan, A. D.: Mol. Phys. 3, 233 (1960).
Hall, G. G., Hardisson, A.: Proc. Roy. Soc. London, 278A, 129 (1964).
Stone, A. J.: Mol. Phys. 6, 509 (1963); 7, 311 (1964).
Snyder, L. C., Amos, T.: J. Chem. Phys. 41, 1773 (1964); 42, 3670 (1965).
Haustein, H., Möbius, K., Dinse, K. P.: Z. Naturforsch. 24a, 1768 (1969).
Dinse, K. P., Biehl, R., Möbius, K., Haustein, H.: Chem. Phys. Letters 12, 399 (1971).
Hutchison, C. A., Mangum, B. W.: J. Chem. Phys. 29, 952 (1958).
Kottis, P., Lefebvre, R.: J. Chem. Phys. 41, 3660 (1964).
van der Waals, J. H., de Groot, M. S.: Mol. Phys. 3, 190 (1960).
Kottis, P.: Ann. Physique 4, 459 (1960).
Heppke, G., Schneider, F.: Ber. Bunseng. Physik. Chem. 75,61 (1971).
McClure, D. S.: J. Chem. Phys. 22, 1668 (1954).
Labhart, H.: Adv. Chem. Phys. 13, 179 (1967).
Liptay, W.: Angew. Chem. 81, 195 (1969).
Weber, G.: Biochem. J. 75, 335 (1960).
Albrecht, A. C.: J. Mol. Spectrosc., 6, 84 (1961).
Zimmermann, H., Joop, N.: Z. Elektrochem. 66, 342 (1962).
Zimmermann, H., Joop, N.: Z. Elektrochem. 65, 66 (1962).
Dörr, F.: Angew. Chem. 78, 457 (1966).
Dörr, F.: In “Creation and Detection of the excited state” (Lamola, A. A., Ed.) Vol. I New York. M. Dekker, pp. 53–122 (1971).
Jablonski, A.: Acta Phys. Polon. 3, 421 (1934).
Thulstrup, E. W., Michl, J., Eggers, J. H.: J. Phys. Chem. 74, 3868 (1970).
Thulstrup, E. W., Eggers, J. H.: Chem. Phys. Letters 1, 690 (1968).
Dörr, F., Gropper, H.: Ber. Bunseng. Physik. Chem. 67, 193 (1963).
Sackmann, E., Voss, J.: Chem. Phys. Letters 14, 528 (1972).
Beens, H., Möhwald, H., Rehm, D., Sackmann, E., Weller, A.: Chem. Phys. Letters 8, 341 (1971).
Baur, G., Stieb, A., Meier, G.: Mol. Cryst. and Liq. Cryst. in press (1973).
Chalelain, P.: Acta Cryst. 4, 435 (1951).
Hochstrasser, R. M.: “Molecular Aspects of Symmetry” New York: W. A. Benjamin 1966.
Birks, J. B.: “Photophysics of Aromata Molecules” London: Wiley-Interscience 1970.
Saupe, A., Maier, W.: Z. Naturforsch. 16a, 816 (1961).
Saeva, F. D., Wysocki, J. J.: J. Am. Chem. Soc. 93, 5928 (1971).
De Vries, H.: Acta Cryst. 4, 219 (1966).
Mauguin, C.: Bull. Soc. Franc. Mineral 34, 71 (1911).
Stegemeyer, H., Mainusch, K. J.: Chem. Phys. Letters. 16, 38 (1972).
Fergason, J. L.: Mol. Cryst. and Liq. Cryst. 1, 293 (1966).
Mainusch, K.-J., Pollmann, P., Stegemeyer, H.: Ber. Bunseng. Physik. Chem. 77, (1973).
Sackmann, E., Rehm, D.: Chem. Phys. Letters 4, 537 (1970).
Caesar, G. P., Levenson, R. A., Gray, H. B.: J. Am. Chem. Soc., 91, 772 (1969).
Flitcroft, N., Huggins, D. K., Kaesz, H. D.: Inorg. Chem. 3, 1123 (1964).
Maier, W., Saupe, A.: Z. Naturforsch. 14a, 882 (1959).
Maier, W., Saupe, A.: Z. Naturforsch. 15a, 287 (1960).
Saupe, A.: Mol. Crystals 1 527 (1966).
Krieger, T. J., James, H. M.: J. Chem. Phys. 22, 796 (1954).
McMillan, W. L. Phys. Rev. A4, 1238 (1971).
Chen, D. H., James, P. G., Luckhurst, G. R.: Mol. Cryst. and Liq. Cryst. 8, 71 (1969).
Humphries, R. L., James, P. G., Luckhurst, G. R.: J. Chem. Soc. (Farad. Trans. II) 68, 737 (1972).
Saupe, A., Nehring: Mol. Cryst. Liq. Cryst. 8, 403 (1969).
Lefebvre, C.: In: “Physical methods of organic chemistry (A. Weissberger Ed.) New York: Interscience (1960) Ch. 36.
Sackmann, E., Krebs, P., Rega, H. U., Voss, J., Möhwald, H.: Mol. Cryst. and Liq. Cryst. 24 283 (1973).
Robertson, J. C., Yim, C. T., Gilson, D. F. R Canad. J. Chem. 49 2346 (1969).
Wulf, A.: J. Chem. Phys. 55, 4512 (1971).
Chandrasekhar, S., Madhusudana, M. V.: Acta Cryst. A27 303 (1971).
Dewar, M. J. S., Schröder, J. P.: J. Am. Chem. Soc. 86, 5235 (1964).
Chow, L. C., Martire, D. E.: J. Phys. Chem. 75, 2005, (1971).
Humphries, R. L., Luckhurst, G. R.: Faraday Symposium No. 5, Liquid Crystals (1971).
Zielinski, W. L., Freeman, D. H., Martire, D. E., Chow, L. C.: Anal. Chem. 42, 176 (1970).
Kelker, H.: Ber. Bunsenges. 67, 698 (1963).
Kelker, H.: Z. Analyt. Chem. 198 254 (1963).
Kelker, H., von Schivizhoffen, E.: Adv. Chromatography, (J. C. Giddings and R. A. Keller Eds.) 6, 247 (1968).
Kelker, H., Verhelst, A.: J. Chromatogr. Sci. 7, 79 (1969)
Kelker, H., Scheurle, B., Sabel, J., Jainz, J., Winterscheidt, H.: Mol. Cryst. and Liq. Cryst. 12 113 (1971).
Martire, D. E., Blasco, P. A., Carone, P. F., Chow, L. C., Vicini, H.: J. Phys. Chem. 72 3489 (1968).
Svedberg, T.: Kolloid Z. 18, 54, 101 (1916).
Bacon, W. E., Brown, G. H.: Mol. Cryst. and Liq. Cryst. 6, 155 (1969)
Paleos, C. M., Labes, M. M.: Mol. Cryst. and Liq. Cryst. 11 385 (1970).
Baturin, A. A., Amerik, Y. B., Krentsel, B. A., Mol. Cryst. and Liq. Cryst. 16 117 (1972)
Barnett, W. E., Sohn, W. H.: Chem. Communications 1002 (1971).
Fergason, J. L.: Scientific American, 211 76 (1964).
Sackmann, E.: J. Am. Chem. Soc. 93, 7088 (1971)
Voss, J., Sackmann, E.: Z. Naturforsch. 28A 1496 (1973).
Zimmerman, G., Chow, L., Paik, U.: J. Am. Chem. Soc. 80 3528 (1958).
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Sackmann, E. (1975). Scientific Applications of Liquid Crystals. In: Applications of Liquid Crystals. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-80954-5_2
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