Skip to main content
SpringerLink
Log in

Time Resolved Very High Temperature NMR Study of the Cooling Process of CaO-Al2O3 Liquids

  • Conference paper
Nuclear Magnetic Resonance Spectroscopy of Cement-Based Materials

Abstract

Nuclear Magnetic Resonance of 27Al is a powerful tool, able to describe the local structure around aluminum nuclei in both crystalline and amorphous solids but also to characterize the average structure and the dynamics of aluminum bearing liquids at very high temperature (T>2000 C). From time resolved very high temperature NMR measurements performed during the cooling of a calcium aluminate liquid levitated droplet, 27Al relaxation time and chemical shift temperature dependence have been determined. The correlation times derived from the relaxation time of 27Al are shown to be closely correlated to the viscosity suggesting that they are due to the same microscopic fluctuations. The thermal dependence of the chemical shift is an image of the variation of the liquid structure with temperature.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Massiot D, Coté B, Taulelle F and Coutures JP (1994) in Colombet P and Grimmer AR (ed) Application of NMR spectroscopy to Cement Science. Gordon and Breach Science Publishers p 153.

    Google Scholar 

  2. Frydman L and Harwood JS (1995) J. Am. Chem. Soc. 117: 5367.

    Article  CAS  Google Scholar 

  3. Massiot D, Touzo B, Trumeau D, Magnenet C, Montouillout V, Florian P, Bessada C, Douy A, Coutures JP (1997), in this issue and references therein.

    Google Scholar 

  4. Coutures JP, Massiot D, Bessada C, Echegut P, Rifflet JC, Taulelle F (1990) C. R. Acad. Sci. 310: 1041.

    CAS  Google Scholar 

  5. Coutures JP, Massiot D, Florian P and Coté B in Colombet P and Grimmer AR (ed) Application of NMR spectroscopy to Cement Science. Gordon and Breach Science Publishers p 429.

    Google Scholar 

  6. Poe BT, McMillan PF, Coté B, Massiot D and Coutures JP (1993) Science 259: 786.

    Article  CAS  Google Scholar 

  7. Florian P, Massiot D, Poe BT, Farnan I and Coutures JP (1995) Solid State NMR 5: 233.

    Article  CAS  Google Scholar 

  8. Massiot D, Trumeau D, Touzo B, Farnan I, Rifflet JC, Douy A and Coutures JP (1995) J. Phys. Chem. 99: 16455.

    Article  CAS  Google Scholar 

  9. Touzo B, Trumeau D, Massiot D, Farnan I, and Coutures JP (1995) J. Chim. Phys. 92: 1871.

    CAS  Google Scholar 

  10. Touzo B, Trumeau D, Coutures JP and Massiot D, submitted to J. Am. Chem. Soc.

    Google Scholar 

  11. McMillan PF, Petuskey WT, Massiot D, Coté B, Landron C and Coutures JP (1996) J. Non Cryst. Solids 195: 261.

    Article  CAS  Google Scholar 

  12. Touzo B (1995) PhD thesis, University of Orleans, France.

    Google Scholar 

  13. Abragam A (1961) Principles of Nuclear Magnetism. Clarendon Press, Oxford.

    Google Scholar 

  14. Urbain G (1983) Rev. Int. Hautes Temp. Refract. 20: 135.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Centre de Recherche sur la Physique des Hautes Températures, CNRS, 45071, Orléans cedex 2, France

    Dominique Massiot, Bruno Touzo, Dominique Trumeau, Ian Farnan, Jean-Claude Rifflet, Catherine Bessada, André Douy & Jean-Pierre Coutures

Authors
  1. Dominique Massiot
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Bruno Touzo
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Dominique Trumeau
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Ian Farnan
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Jean-Claude Rifflet
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Catherine Bessada
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. André Douy
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. Jean-Pierre Coutures
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. CTG Italcementi-Ciments Français, rue des Technodes, 78931, Guerville, France

    Pierre Colombet

  2. ESPCI, 10 rue Vauquelin, 75231, Paris Cedex 5, France

    Hélène Zanni

  3. Institut für Chemie, Humboldt-Universität, Rudower Chaussee, Haus 4.1, 12484, Berlin, Germany

    Arnd-Rüdiger Grimmer

  4. Dipartimento di Scienza dei Materiali, Chimica e Technologia dei Materiali, Universita degli Studi di Milano, Via Emanueli 15, 20126, Milano, Italy

    Piero Sozzani

Rights and permissions

Reprints and permissions

Copyright information

© 1998 Springer-Verlag Berlin Heidelberg

About this paper

Cite this paper

Massiot, D. et al. (1998). Time Resolved Very High Temperature NMR Study of the Cooling Process of CaO-Al2O3 Liquids. In: Colombet, P., Zanni, H., Grimmer, AR., Sozzani, P. (eds) Nuclear Magnetic Resonance Spectroscopy of Cement-Based Materials. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-80432-8_7

Download citation

  • DOI: https://doi.org/10.1007/978-3-642-80432-8_7

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-80434-2

  • Online ISBN: 978-3-642-80432-8

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation