Electronic and Vibrational Dephasing in Solution by Dynamic Symmetry Breaking
Part of the Springer Series in Chemical Physics book series (CHEMICAL, volume 62)
A new type of Raman dephasing due to interconversion between two symmetrically related structures is described. The line is broadened by fluctuations not in the vibrational frequency but in the sign of the Raman polarizability.
KeywordsVibrational Frequency Dynamic Symmetry Symmetric Stretch Resonance Raman Spectrum Pure Dephasing
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© Springer-Verlag Berlin Heidelberg 1996