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Polymerization of Phenyl Substituted Cyclic Olefins with Metallocene/Aluminoxane Catalysts

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Abstract

The ethene/phenylnorbornene and ethene/phenyl-DMON copolymerization was investigated by using two Cs-symmetric ([Me2C (Fluo) (Cp)] ZrCl2 III), [Ph2C (Fluo) (Cp)] ZrCl2 IV) and two C2-symmetric ([Me2Si (Ind)2] ZrCl2 I), [Ph2Si (Ind)2] ZrCl2 II) catalysts with methylaluminoxane (MAO) as cocatalysts. The copolymerization parameters are calculated according to 13C-NMR measurements. The Cs-symmetric catalysts are very suitable for yielding amorphous copolymers with glass transition temperatures of 230 °C and molecular masses greater than 100000 g × mol−1. These copolymers could be used as materials for optical discs and fibres

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Abbreviations

DMON:

1,4,5,8-dimethano-l, 2,3,4,4a, 5,8,8a-octahydro-naphthalene

P-Norb:

phenylnorbornene

P-DMON::

phenyl-DMON

V-Norb:

vinyl-norbornene

Me:

methyl

Ph:

phenyl

Ind:

indenyl

Fluo:

fluorenyl

Tg:

glass transition temperature

Tm:

melting point

Wt%:

weight %

References

  1. Kaminsky W, Spiehl R (1989) Makromol Chern 190: 83

    Article  Google Scholar 

  2. Kaminsky W, Bark A, Arndt M (1991) Makromol Chern, Makromol Symp 47: 83

    Article  CAS  Google Scholar 

  3. Kaminsky W, Bark A, Steiger R (1992) J Molecular Catalysis 74: 109

    Article  CAS  Google Scholar 

  4. Kaminsky W, Bark A, Däke I (1990). In: Keii T, Soga K (eds) Catalytic olefin polymerization,Kodansha, Tokyo,P 425

    Chapter  Google Scholar 

  5. Kaminsky W, Bark A (1992) Polymer Intern 28: 251

    Article  CAS  Google Scholar 

  6. Spaleck W, Antberg M, Dolle V, Klein R, Rohrmann J, Winter A (1990) New J Chern 14: 499

    CAS  Google Scholar 

  7. Ewen JA, Jones RL, Razavi A, Ferrara JD (1988) J Am Chern Soc 110: 6255

    Article  CAS  Google Scholar 

  8. Winter A, Rohrmann J, Antberg M, Dolle V, Spaleck W (1990) Ger Offen DE 3,907,965 (Chern

    Google Scholar 

  9. Kaminsky W, Noll A (1993) Polymer Bulletin 31: 175

    Article  CAS  Google Scholar 

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Author information

Authors and Affiliations

  1. Institute for Technical and Macromolecular Chemistry, University of Hamburg, Bundesstr. 45, D-20146, Hamburg, Germany

    W. Kaminsky & A. Noll

Authors
  1. W. Kaminsky
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  2. A. Noll
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Editor information

Editors and Affiliations

  1. Max-Planck-Institut für Kohlenforschung, D-45470, Kaiser-Wilhelm-Platz 1, Mülheim, Germany

    Gerhard Fink

  2. Institut für Makromolekulare Chemie, Albert-Ludwigs-Universität Freiburg, Hermann-Staudinger-Haus, D-79104, Stefan-Meier-Straße 31, Freiburg, Germany

    Rolf Mülhaupt

  3. Universität Konstanz, D-78434, Konstanz, Germany

    Hans H. Brintzinger

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© 1995 Springer-Verlag Berlin Heidelberg

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Kaminsky, W., Noll, A. (1995). Polymerization of Phenyl Substituted Cyclic Olefins with Metallocene/Aluminoxane Catalysts. In: Fink, G., Mülhaupt, R., Brintzinger, H.H. (eds) Ziegler Catalysts. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-79136-9_8

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  • DOI: https://doi.org/10.1007/978-3-642-79136-9_8

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-79138-3

  • Online ISBN: 978-3-642-79136-9

  • eBook Packages: Springer Book Archive

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