Abstract
Photochemistry is the study of interactions between radiant energy and chemical species, and a fundamental understanding of photochemistry is essential for atmospheric chemists. All the chemistry that takes place in the atmosphere is in some form influenced by solar radiation, which initiates production of many key reactive species and loss of many otherwise stable molecules. Spectroscopy is the investigation of how strongly and at which wavelengths an atom or a molecule absorbs light. The spectroscopy of atmospheric molecules determines which molecule absorbs light in what region of the atmosphere, and hence influences the photochemistry of the atmosphere. Atmospheric photochemistry and spectroscopic detection of atmospheric species are the two main subjects of this paper.
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References
Airborne Antarctic Ozone Experiment (AAOE) special issue (1989). J Geophys Res D 94(9) and (14)
Airborne Arctic Stratospheric Expedition (AASE) special issue (1990). Geophys Res Lett 17: 313–564
AASE-II issue (1993) Science 261: 1128–1158
AASE-II special issue (in press, 1993) Geophys Res Lett
Arpag KA, Johnston PV, Miller HL, Sanders RW, Solomon S (submitted, 1993 ) Observations of the stratospheric BrO column over Colorado, 40°N. J Geophys Res
Burkholder JB, Talukdar RK, Ravishankara AR, Solomon S (in press, 1993) Temperature dependence of the HNO3 UV absorption cross sections. J Geophys Res D
Burkholder JB, Wilson RR, Gierczak T, Talukdar RK, McKeen SA, Orlando JJ, Vaghjiani GL, Ravishankara AR (1991) Atmospheric fate of CF3Br, CF2Br2, CF2C1Br, and CF2BrCF2Br. J Geophys Res D 96: 5025–5043
Farman JC, Gardiner BG, Shanklin JD (1985) Large losses of total ozone in Antarctica reveal seasonal C10x/NOx interaction. Nature 315: 207–210
Fish DJ, Freshwater RA, Oldham DJ, Roscoe HK, Jones, RL (1992) Measurements of stratospheric composition using a star-pointing spectrometer. Quadrennial Ozone Symposium, Charlottesville, VA, U.S.A
Herman JR (1979) The problem of nighttime stratospheric NO3. J Geophys Res 84: 6336–6338
Hinkley ED, Ku RT, Kelly PL (1976) In Hinkley ED (ed) Laser monitoring of the atmosphere. Springer-Verlag, New York, pp. 237–95
Hubler G, Perner D, Platt U, Tonnissen A, Ehhalt DH (1984) Groundlevel OH radical concentration:new measurements by optical absorption. J Geophys Res D 89: 1309–1319
McKenzie RL, Johnston PV, McElroy CT, Kerr JB, Solomon S (1991) Altitude distributions of stratospheric constituents from ground-based measurements at twilight. J Geophys Res D 96: 15499–15511
Meier RR, Anderson DE Jr. (1982) Radiation field in the troposphere and stratosphere from 240–1000 nm-1. General analysis. Planet Space Sei 30: 923–933
Mount GH (1992) The measurement of tropospheric OH by long path absorption. I. Instrumentation. J Geophys Res D 97: 2427–2444
Mount GH, Sanders RW, Schmeltekopf AL, S.Solomon (1987) Visible spectroscopy at McMurdo Station, Antarctica. 1. Overview and daily variations of NO2 and O3, Austral spring, 1986. J Geophys Res D 92: 8320–8328
Perliski L, Solomon S (1993) On the evaluation of air mass factors for atmospheric nearultraviolet and visible absorption spectroscopy. J Geophys Res D 98: 10363–10374
Proffitt MH, McLaughlin RJ (1983) Fast-response dual-beam UV absorption ozone photometer suitable for use on stratospheric balloons. Rev Sei Inst 54: 1719–1728
Rattigan O, Lutman ER, Jones RL, Cox RA (1992a) Temperature dependent absorption cross sections of gaseous nitric acid and atmospheric photolysis rates of nitric acid. Ber Bunsenges Phys Chem 96: 399–404
Rattigan O, Lutman ER, Jones RL, Cox RA, Clemitshaw K, Williams J (1992b) Corrigendum:Temperature dependent absorption cross sections of gaseous nitric acid and methyl nitrate. J Photochem Photobiol A: Chem 69: 125–126
Rattigan O, Lutman ER, Jones RL, Cox RA, Clemitshaw K, Williams J (1992c) Temperature dependent absorption cross sections of gaseous nitric acid and methyl nitrate. J Photochem Photobiol 66: 313–326
Rigaud P, Naudet JP, Huguenin D (1983) Simultaneous measurements of vertical distributions of stratospheric NO3 and O3 at different periods of the night. J Geophys Res C 88: 1463–1467
Sanders RW, Solomon S, Smith JP, Perliski L, Miller HL, Mount GH, Keys JG, Schmeltekopf AL (submitted, 1993) Visible and near-ultraviolet spectroscopy at McMurdo Station, Antarctica. 9. Observations of OCIO from April-October 1991. J Geophys Res D
Smith JP, Solomon S (1990) Atmospheric NO3. 3. Sunrise disappearance and the stratospheric profile. J Geophys Res D 95: 13819–13827
Smith JP, Solomon S, Sanders RW, Miller HL, Perliski L, Keys JG, Schmeltekopf AL (1993) Atmospheric NO3. 4. Vertical profiles at middle and polar latitudes at sunrise. J Geophys Res D 98: 8983–8989
Solomon S (1988) The mystery of the Antarctic ozone hole. Rev Geophys 26: 131–148
Solomon S, Schmeltekopf AL, Sanders RW (1987) On the interpretation of zenith sky absorption measurements. J Geophys Res D 92: 8311–8319
Talukdar RK, Vaghjiani GL, Ravishankara AR (1992) Photodissociation of bromocarbons at 193 nm, 222 nm, and 248 nm - quantum yields of Br atom at 298 K. J Chem Phys 96: 8194–8201
Weaver A, Arpag K, Miller HL, Sanders RW, Solomon S (to be published, 1993 )
Webster CR, May RD (1987) Simultaneous in situ measurements and diurnal variations of NO2, O3, jNO2, CH4, H2O, and CO2 in the 40- to 26-km region using an open path tunable diode laser spectrometer. J Geophys Res D 92: 11931–11950
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Weaver, A., Ravishankara, A.R. (1994). Atmospheric Photochemistry and Spectroscopy. In: Moortgat, G.K., Barnes, A.J., Le Bras, G., Sodeau, J.R. (eds) Low-Temperature Chemistry of the Atmosphere. NATO ASI Series, vol 21. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-79063-8_6
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DOI: https://doi.org/10.1007/978-3-642-79063-8_6
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