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Rheology, Dielectric, Relaxation, and Adhesion of Thermodynamically Confined Diblock Copolymer Chains

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Ordering in Macromolecular Systems

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Abstract

Various thermodynamic requirements exist in strongly segregated A-B diblock copolymer systems. Some of them, e.g., an osmotic requirement of uniform segment density distribution in microdomains, impose a constraint on the block conformation. On the other hand, there always exists an elastic requirement of randomizing the conformation. These contradicting requirements thermodynamically confine the copolymer chains, thereby providing them some unique properties. Those properties are briefly reviewed and their thermodynamic origins are discussed.

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Author information

Authors and Affiliations

  1. Department of Macromolecular Science, Faculty of Science, Osaka University, Toyonaka, Osaka 560, Japan

    H. Watanabe & T. Kotaka

Authors
  1. H. Watanabe
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  2. T. Kotaka
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Editor information

Editors and Affiliations

  1. Department of Macromolecular Science, Osaka University, Faculty of Science, Toyonaka, 560 Osaka, Japan

    Akio Teramoto , Masamichi Kobayashi  & Takashi Norisuye ,  & 

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© 1994 Springer-Verlag Berlin Heidelberg

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Watanabe, H., Kotaka, T. (1994). Rheology, Dielectric, Relaxation, and Adhesion of Thermodynamically Confined Diblock Copolymer Chains. In: Teramoto, A., Kobayashi, M., Norisuye, T. (eds) Ordering in Macromolecular Systems. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-78893-2_20

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  • DOI: https://doi.org/10.1007/978-3-642-78893-2_20

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-78895-6

  • Online ISBN: 978-3-642-78893-2

  • eBook Packages: Springer Book Archive

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