Abstract
We compared various statistical thermodynamic theories with experimental results for isotropic—liquid crystal phase behaviors in many stiff-chain liquid-crystalline polymer solutions. Among the theories, the scaled particle theory for wormlike hard spherocylinders most successfully explained the experimental phase behaviors in neutral polymer systems, and the same theory considering the electrostatic interaction in a perturbative way was favorably compared with a phase diagram for a charged stiff polymer system. Good agreements between this theory and experiment were also obtained for the osmotic pressure and the orientational order parameter of poly(γ-benzyl L-glutamate) solutions.
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References
Onsager L (1949) Ann. N.Y. Acad. Sci. 51: 627
Flory PJ (1956) Proc. Roy. Soc. (London) A234: 73
Cotter MA (1974) Phys. Rev. A 10: 625
Cotter MA (1977) J. Chem. Phys. 66: 1098
Cotter MA, Martire DE (1970) J. Chem. Phys. 53: 4500
Cotter MA, Martire DE (1970) J. Chem. Phys. 52: 1909
Lasher G (1970) J. Chem. Phys. 53: 4141
Khokhlov AR, Semenov AN (1981) Physica 108A: 546
Khokhlov AR, Semenov AN (1982) Physica 112A: 605
Sato T, Teramoto A (1990) Mol. Cryst. Liq. Cryst. 178: 143
Flory PJ (1953) Principles of Polymer Chemistry, Cornell Univ. Press, Ithaca, New York
Itou T, Van K, Teramoto A (1985) J. Appl. Polym. Sci., Appl. Polym. Symp. 41: 35
Itou T, Teramoto A (1984) Polym. J. 16: 779
Wee EL, Miller WG (1971) J. Phys. Chem. 75: 1446
Miller WG, Rai JH, Wee EL (1974) Liquid Crystals and Ordered Fluids 2: 243
Miller WG, Wu CC, Wee EL, Santee GL, Rai JH, Goebel KG (1974) Pure Appl. Chem. 38: 37
Kubo K, Ogino K (1979) Mol. Cryst. Liq. Cryts. 53: 207
Kubo K (1981) Mol. Cryst. Liq. Cryst. 74: 71
Itou T, Funada S, Shibuya F, Teramoto A (1986) Kobunshi Ronbunshu 43: 191
Itou T, Teramoto A (1988) Macromolecules 21: 2225
Conio G, Bianchi E, Ciferri A, Tealdi A, Aden MA (1983) Macromolecules 16: 1264
Laivins GV, Gray GD (1985) Macromolecules 18: 1753
Yanaki T, Norisuye T, Hiroshi F (1980) Macromolecules 13: 1462
Itou S, Nishioka N, Norisuye T, Teramoto A (1981) Macromolecules 14: 904
Itou T, Chikiri H, Teramoto A, Aharoni SM (1988) Polym. J. 20: 143
Lifshitz IM (1969) Soviet Phys. JETP 28: 1280
Lifshitz IM, Grosberg AY, Khokhlov AR (1978) Rev. Mod. Phys. 50: 684
DuPré DB, Yang S (1991) J. Chem. Phys. 94: 7466
Yamazaki T, Abe A (1987) Polym. J. 19: 777
Abe A, Yamazaki T (1989) Macromolecules 22: 2145
Sato T, Shoda T, Teramoto A (1993) to be submitted to Macromolecules
Itou T, Teramoto A (1984) Macromolecules 17: 1419
Sato T, Teramoto A (1991) Physica A176: 72
Stroobants A, Lekkerkerker HNW, Odijk T (1986) Macromolecules 19: 2232
Philip JR, Wooding RA (1970) J. Chem. Phys. 52: 953
Inatomi S, Sato T, Teramoto A (1992) Macromolecules 25: 5013
Sato T, Kakihara T, Teramoto A (1990) Polymer 31: 824
Sato T, Norisuye T, Fujita H (1984) Macromolecules 17: 2696
Sho T, Sato T, Norisuye T (1986) Biophys. Chem. 25: 307
Okuyama K, Arnott S, Moorhouse R, Walkinshaw MD, Atkins EDT, Wolf-Ullish C (1980) In: French AD, Gardner KH (Eds) Fiber Diffraction Methods, American Chemical Society, Washington DC
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© 1994 Springer-Verlag Berlin Heidelberg
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Sato, T., Teramoto, A. (1994). Phase Equilibria in Liquid Crystalline Polymer Solutions: Theory and Experiment. In: Teramoto, A., Kobayashi, M., Norisuye, T. (eds) Ordering in Macromolecular Systems. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-78893-2_13
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DOI: https://doi.org/10.1007/978-3-642-78893-2_13
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