Skip to main content
SpringerLink
Log in

Röntgenfluoreszenzanalyse mit Synchrotronstrahlung

  • Chapter
Analytiker-Taschenbuch

Part of the book series: Analytiker-Taschenbuch ((ANALYTIKERTB,volume 12))

Zusammenfassung

In dem großen Kanon von Analysenprinzipien zur Bestimmung von Elementspuren sind Multielementmethoden besonders gefragt. Im Prinzip sollte die Röntgenftuoreszenzanalyse (RFA) zur Befriedigung dieses Bedarfs einen wesentlichen Beitrag liefern können, denn ein Vorteil der Methode liegt darin, daß die die Fluoreszenz beeinflussenden Parameter eine stetige Abhängigkeit von der Kernladungszahl Z besitzen (Moseleysches Gesetz) und der die Fluoreszenzintensität bestimmende Photoionisationswirkungsquerschnitt sowie die als Konkurrenzprozess auftretende Auger-Elektronenemission elementare physikalische Prozesse sind, die sich für isolierte Atome genau berechnen lassen.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 59.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 74.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literatur

  1. - Agrawal B (1991) X-Ray Spectroscopy. Springer, Berlin

    Google Scholar 

  2. - Anatov A, Grigoryeva I, Shchipov N, Baryshev V, Kulipanov G (1991) Focusing Shaped Pyrographite Monochromators in Synchrotron Radiation Experiments. Nucl. Instr. Meth. A308, 442

    Google Scholar 

  3. - Bachrach R (1992) Synchrotron Radiation Research Bd 1–2. Plenum, New York

    Book  Google Scholar 

  4. - Baryshev V, Kulipanov G, Skrinsky A (1986) Review of X-Ray Fluorescent Analysis using Synchrotron Radiation. Nucl. Instr. Meth. A246, 739

    CAS  Google Scholar 

  5. - Baryshev V, Kulipanov G, Shrinsky A (1991) X-Ray Fluorescent Elemental Analysis, Handbook on Synchrotron Radiation, Vol 3. North-Holland, Amsterdam

    Google Scholar 

  6. - Bavdaz M, Knöchel A, Ketelsen P, Petersen W, Gurker N, Salehi M, Dietrich T (1988) Imaging Multielemental Analysis with Synchrotron excited X-Ray Fluorescence Radiation. Nucl. Instr. Meth. A266, 308

    CAS  Google Scholar 

  7. - Bearden J (1967) X-Ray Wavelengths. Rev Mod Phys 39, 78

    Article  CAS  Google Scholar 

  8. - Bertin E (1984) Principles and Practice of X-Ray Spectrometric Analysis. Plenum, New York

    Google Scholar 

  9. - Chen JR, Chao EC, Minkin JA, Back JM, Jones KW, Rivers ML, Sutton SR (1990) The Uses of Synchrotron Radiation Sources for Elemental and Chemical Microanalysis. Nucl. Instr. Meth. B49, 533

    CAS  Google Scholar 

  10. - Davies ST, Bowen DK, Prins M. Bos A (1984) Trace Element Analysis by Synchrotron Radiation excited XRF. Adv in X-Ray Anal Vol 27, 557

    Article  CAS  Google Scholar 

  11. - Devoti R, Zontone F, Tuniz C, Zanini F (1991) A Synchrotron Radiation Microprobe for X-Ray Fluorescence and Microtomography at ELETTRA. Focussing with bent Crystals. Nucl. Instr. Meth. B54, 424

    Google Scholar 

  12. - Doster J, Gardner R (1982) The Complete Spectral Response for EDXRF Systems. X-Ray Spect. 11, 173

    Article  CAS  Google Scholar 

  13. - Eastman D, Farge Y (1983) Handbook on Synchrotron Radiation 1–4. North Holland, Amsterdam

    Google Scholar 

  14. - Engström P, Larsson S, Rindby A, Buttkewitz A, Garbe S, Gaul G, Knöchel A, Lechtenberg F (1991) A Submicron Synchrotron X-ray Beam generated by Capillary Optics. Nucl. Instr. Meth. A 302, 547

    Google Scholar 

  15. - Erko A, Khzmalian E, Panchenko L, Redkin S, Zinnenko V, Chevalier P, Dhez, P, Khan Malek C, Freund A, Vidal B (1992) First Test of a Bragg-Fresnel X-Ray Fluorescence Microscopy Proceed, 3. Int, Symp on X-Ray Microscopy, Springer Ser Opt Sci V 67, Springer 217

    Google Scholar 

  16. - Herausgeber: European Synchrotron Radiation Society (ESRS) (1990) World Compendium of Synchrotron Radiation Facilities. ESRS

    Google Scholar 

  17. - Fuchs E, Oppholzer H, Rehm H (1990) Particle Beam Micro Analysis: Fundamentals, Methods, Applications. VCH, Weinheim

    Google Scholar 

  18. - Gardner R, Wielopolski L, Doster J (1976) Adaption of Fundamental Parameters Monte Carlo Simulation to EDXRF. Adv X-Ray Anal 21, 129

    Google Scholar 

  19. - Gilfrich J, Skelton E, Nagel D, Webb A, Qadri S, Kirkland J (1983) X-Ray Fluorescence Analysis using Synchrotron Radiation (SR). Adv X-Ray Anal 26, 313

    CAS  Google Scholar 

  20. - Gilfrich J (1989) Synchrotron Radiation X-Ray Analysis. Adv X-Ray Anal 32, 1

    CAS  Google Scholar 

  21. - Goshi A, Aoki S, Iida A, Hayakawa S, Yamaji H, Sakurai K (1987) Jpn J Appl Phys 26, L1260

    Article  Google Scholar 

  22. - Gohshi Y (1991) Ultratrace Analysis by Synchrotron Radiation. Nucl. Instr. Meth. A303, 544

    CAS  Google Scholar 

  23. - Gordon B (1982) Sensitivity Calculations of Multielemental Trace Analysis by Synchrotron Radiation induced X-Ray Fluorescence. Nucl. Instr. Meth. A204, 223

    Google Scholar 

  24. - Gordon B, Jones K (1988) Nucl. Instr. Meth. B10/11, 293

    Google Scholar 

  25. - Gordon B, Hanson A, Jones K, Pounds J, Schidlovsky G, Rivers M, Sutton S, Spanne P (1990) The Application of Synchrotron Radiation to Microprobe Trace-Element Analysis of Biological Samples. Nucl. Instr. Meth. B45, 527

    CAS  Google Scholar 

  26. - Goulding F (1977) Some Aspects of Detectors and Electronics for X-Ray Fluorescence Analysis. Nucl. Instr. Meth. 142, 213

    Article  CAS  Google Scholar 

  27. - Haken E, Wolf H (1987) Atom- und Quantenphysik. Springer, Berlin

    Google Scholar 

  28. - Hanson A (1986) The Calculation of Scattering Cross Sections for Polarized X-Rays. Nucl. Instr. Meth. A243, 583

    CAS  Google Scholar 

  29. - Hanson A, Gordon K, Pounds J, Kwiatek W, Long G, Rivers M, Sutton S (1987) Trace Element Measurements using white Synchrotron Radiation. Nucl. Instr. Meth. B24/25, 400

    Google Scholar 

  30. - Hasnain S (1990) Synchrotron Radiation and Biophysics. Harwood, Chichester

    Google Scholar 

  31. - Hayakawa S, Iida A, Aoki S, Goshi Y (1989) Development of a Scanning X-Ray Microprobe with Synchrotron Radiation. Rev Sci Inst 60, 2452

    Article  CAS  Google Scholar 

  32. - Hayakawa S, Goshi Y, Iida A, Aoki S, Ishikawa M (1990) X-Ray Microanalysis with Energy tuneable Synchrotron X-Rays. Nucl. Instr. Meth. B49, 555

    CAS  Google Scholar 

  33. - He T, Gardner R, Verghese K (1992) A General Geometry Monte Carlo Simulation Code for EDXRF Analysis. Adv X-Ray Anal 35, 727

    Article  Google Scholar 

  34. - Herman GT (1980) Image Reconstruction from Projections. Academic Press, New York

    Google Scholar 

  35. - Hormes J, Chauvistre R, Schmitt W, Pantelouris M (1992) Examples for the Industrial Use of Synchrotron Radiation. Acta Phys Pol A92(37)

    Google Scholar 

  36. - in EAS83 Vol 4, S 307–348

    Google Scholar 

  37. - Iida A, Sakurai K, Gohshi Y (1985) Energy Dispersive X-Ray Fluorescence Analysis with Synchrotron Radiation. Nucl. Instr. Meth. A228, 556

    Google Scholar 

  38. - Vorlesungsmanuskript 18. IFF-Fereinkurs KFA Jülich Synchrotronforschung in der Festkörperforschung. Herausgeber: KFA Jülich

    Google Scholar 

  39. - Vorlesungsmanuskript 23. IFF-Ferienkurs KFA Jülich Synchrotronforschung zur Erforschung kondensierter Materie. Herausgeber: KFA Jülich

    Google Scholar 

  40. - Jaklevic J, Giauque R, Thompson A (1985) Quantitative X-Ray Fluorescence Analysis using Monochromatic Synchrotron Radiation. Nucl. Instr. Meth. B10, 303

    Google Scholar 

  41. - Janssens K. Universität Antwerpen, Dept Chemie priv Mitteilung

    Google Scholar 

  42. - Janssens K, Vincze L, van Espens P, Adams F (1993) Simulation of Conventional and Synchrotron Energy-Dispersive X-Ray Spectrometers. X-Ray Spect 22

    Google Scholar 

  43. - Jenkins R (1988) X-Ray Fluorescence Spectrometry. Chem Anal Vol 99. Wiley, Chichester

    Google Scholar 

  44. - PIXE (1988) A novel Technique for Elemental Analysis. Wiley, Chichester

    Google Scholar 

  45. - Jones K, Gordon B (1989) Trace Element Determination with Synchrotron induced X-Ray Emission, Anal Chem 61, 341

    Article  Google Scholar 

  46. - Ketelsen P, Knöchel A, Petersen W (1986) Synchrotron Radiation excited X-Fluorescence Analysis using a Graphite Monochromator. Fres Z Anal Chem 323, 807

    Article  CAS  Google Scholar 

  47. - Khvostova V (1987) Samples for X-Ray Fluorescence Analysis using Synchrotron Radiation. Nucl. Instr. Meth. A261, 295

    CAS  Google Scholar 

  48. - Khostova VP, Trunova V, Baryshev V, Zolotarev K (1991) The SRXFA Technique in Analytical Concentrates Analysis. Nucl. Instr. Meth. A308, 315

    Google Scholar 

  49. - Klockenkämper R (1987) X-Ray Spectral Analysis. Present Status and Trends. Spectrochim Acta B42, 423

    Google Scholar 

  50. - Klockenkämper R (1991) Analytiker Taschenhandbuch Bd 10, Springer, Berlin

    Google Scholar 

  51. - Klockenkämper R, Knoth J, Prange A, Schwenke H (1992) Totalreflection X-Ray Fluorescence Spectrometry. Anal Chem 4, 1115

    Article  Google Scholar 

  52. - Knöchel A, Petersen W, Tolkiehn G (1983) X-Ray Fluorescence Analysis with Synchrotron Radiation. Nucl. Instr. Meth. A208, 659

    Google Scholar 

  53. - TXRF, PIXE, SYXRF (1990) Principles critical comparison and applications. Fres J Anal Chem 337, 614

    Google Scholar 

  54. - Knoll G (1991) Radiation Detection and Measurement. Wiley, New York

    Google Scholar 

  55. - Leo W (1987) Techniques for Nuclear and Particle Physics Experiments. Springer, Berlin

    Google Scholar 

  56. - van Langevelde F, Lenglet W, Overwater R, Vis R, Huizing A, Viegers M, Zegers C, Heide J (1987) X-Ray focusing for Synchrotron Radiation Microprobe Analysis at the SRS, Daresbury. Nucl. Instr. Meth. A257, 436

    Google Scholar 

  57. - van Langevelde F, Tros G (1990) The Synchrotron Radiation Microprobe at the SRS. Nucl. Instr. Meth. B49, 544

    Google Scholar 

  58. - van Langevelde F, Janssens K, Adams F, Vis R (1992) Prediction of the Optical Characteristics and Analytical Qualities of an X-Ray Fluorescence Microprobe at the ESRF, Grenoble. Nucl. Instr. Meth. A317, 383

    Google Scholar 

  59. - Lechtenberg F, HASYLAB (1992) private Mitteilung

    Google Scholar 

  60. - Lifshin E (1992) Characterization of Materials. VCH Verlag

    Google Scholar 

  61. - Mantler M (1987) Advances in Fundamental Parameter Methods for quantitative X-Ray Fluorescence Analysis. Adv X-Ray Anal 30, 97

    Article  CAS  Google Scholar 

  62. - Mantler M (1986) X-Ray Fluorescence Analysis for Multiple Layer Films Anal Chem Acta 188, 20

    Article  Google Scholar 

  63. - Margaritando (1988) Introduction to Synchrotron Radiation. Oxford Uni Press, New York

    Google Scholar 

  64. - Maenhaut W (1990) Recent Advances in Nuclear and Atomic Spectrometric Techniques for Trace Element Analysis. Nucl. Instr. Meth. B49, 518

    CAS  Google Scholar 

  65. - Mayer-Kuckuk T (1980) Atomphysik. Teubner, Stuttgart

    Google Scholar 

  66. - McMaster W et al (1969) Compilation of X-Ray Cross Sections herausgegeben von Lawrence Rad Lab. UCRL-59174, Section II, Rev 1

    Google Scholar 

  67. - Pantenberg FJ Beier T, Heinrich F, Mommsen H (1992) The Fundamental Parameter Method applied to X-Ray Fluorescence Analysis with Synchrotron Radiation. Nucl. Instr. Meth. B68,125

    Google Scholar 

  68. - Petersen W, Ketelsen P, Knöchel A, Pausch R (1986) New Developments of X-Ray Fluorescence Analysis with Synchrotron Radition. Nucl. Instr. Meth. A246, 731

    CAS  Google Scholar 

  69. - Petersen W, Ketelsen P, Knöchel A (1986) XSPEK - A new Program for the Evaluation of Energy Dispersive X-Ray Fluorescence Spectra Nucl. Instr. Meth. A245, 535

    Article  CAS  Google Scholar 

  70. - Prins M, Davis S, Bowen D (1984) Experimental Comparison of Synchrotron Radiation with other Methods of Excitation of X-Rays for Trace Element Analysis. Nucl. Instr. Meth. A222,324

    Google Scholar 

  71. - Przybylowicz W, Lankosz M, van Langevelde F, Kucha H, Wyszomirski P (1992) Trace Element Determinations in selected Geological Samples using a 15 ke V Microprobe at the SRS Daresbury. Nucl. Instr. Meth. B68, 115

    CAS  Google Scholar 

  72. - Pushkin S, Mizgina T, Feorov T (1987) Elemental Composition Study of Atmospheric Aerosols by the X-Ray-Fluorescence Method using Synchrotron Radiaton. Nucl. Instr. Meth. A261,290

    CAS  Google Scholar 

  73. - Rivers ML (1988) X-Ray Fluorescence Imaging with Synchrotron Radiation 2. Int Symp on X-Ray Microscopy, Upton (NY). Ser Opt Sci 56, 233, Springer, Germany

    Google Scholar 

  74. - Rivers ML, Sutton SR, Jones KW (1992) Proceed, 3. Int Symp on X-Ray Microscopy X-Ray Fluorescence Microscopy. Ser Opt Sci 67, 212, Springer, Germany

    Google Scholar 

  75. - Fundamentals of Energy Dispersive X-Ray Analysis (1984) Butterworths

    Google Scholar 

  76. - Sherman J (1955) The Theoretical Derivation of Fluorescent X-Ray Intensities from Mixtures. Spectrochim Acta 7, 285

    Google Scholar 

  77. - Sparks C (1976) Quantitative X-Ray Fluorescence Analysis using Fundamental Parameters. Adv X-Ray Anal 19, 19

    Google Scholar 

  78. - Sparks C in WIN80 S 459–512

    Google Scholar 

  79. - Sutton SR, Rivers ML, Smith JV (1988) Advances in Geochemistry and Cosmochemistry. Trace Element Microdistributions with the Synchrotron X-Ray Fluorescence Microprobe. Ser Opt Sci 56, 438, Springer, Germany

    Google Scholar 

  80. - Sutton RS, Rivers ML, Bajt S (1993) Synchrotron X-Ray Fluorescence microprobe analysis with bending magnets and insertion devices. Nucl. Instr. Meth. B75, 553

    CAS  Google Scholar 

  81. - Tertian R, Claisse F (1982) Principles of Quantitative X-Ray Fluorescence Analysis. Heyden, London

    Google Scholar 

  82. - Thompson A, Underwood J, Wu J, Giauque R, Jones K (1988) Nucl. Instr. Meth. A266, 318

    CAS  Google Scholar 

  83. - Thompson AC, Chapman KL, Sparks GE, Yun W, Lai B, Legnini D, Vicarro PJ, Rivers ML, Bilderback DH, Thiel DJ (1992) Focussing Optics for a Synchrotron based X-Ray Microprobe. Nucl. Instr. Meth. A319, 320

    CAS  Google Scholar 

  84. - in EAS83 Vol 1A, S 315

    Google Scholar 

  85. - Tolkiehn G, Petersen W (1983) A Method for the quantitative Determination of Synchrotron Radiation X-Ray Spectra for Absolute XRF Trace Element Detection. Nucl. Instr. Meth. A215, 515

    Google Scholar 

  86. - Traxel K, Chen J, Kneis H, Martin B, Nobiling R, Pelte D, Povh B (1981) Nucl. Instr. Meth. A181, 141

    Google Scholar 

  87. - Trunova V, Danilovich V, Baryshev V (1991) Application of SR-XFA for Identification of the Basic Composition of High-Temperature Semiconductors. Nucl. Instr. Meth. A308, 321

    CAS  Google Scholar 

  88. - Tuniz C, Zanini F, Jones KW (1991) Probing the Environment with Accelerator-based Techniques. Nucl. Instr. Meth. B56/57, 877

    Google Scholar 

  89. - Underwood JH, Thompson A, Wu Y, Giaque R (1988) X-Ray Microprobe using Multilayer Mirrors. Nucl. Instr. Meth. A266, 296

    CAS  Google Scholar 

  90. - Verghese K, Michael M, He T, Gardner R (1988) A New Analysis Principle for EDXRF: The Monte Carlo - Library Least-Squares Principle. Adv X-Ray Anal 31,461

    Article  CAS  Google Scholar 

  91. - Vis RD, van Langevelde F (1991) On the Development of X-Ray Microprobes using Synchrotron Radiation. Nucl. Instr. Meth. B54, 417

    CAS  Google Scholar 

  92. - Vincze L, Janssens K, Adams F (1993) A general Monte-Carlo Simulation of Energy dispersive X-Ray Fluorescence Spectra Spectrochim. Acta 48B, 553

    CAS  Google Scholar 

  93. - Wille K (1992) Physik der Teilchenbeschleuniger und Synchrotronstrahlungsquellen. Teubner, Stuttgart

    Google Scholar 

  94. - Winnick H, Doniach S (1980) Synchrotron Radiation Research. Plenum, New York

    Google Scholar 

  95. - Winnick (1987) H Synchrotron Radiation Facilities. Nucl. Instr. Meth. A261, 9

    Google Scholar 

  96. - Wu Y, Thompson A, Underwood J, Giauque R, Chapman R, Rivers ML, Jones KW (1990) A tuneable X-Ray Microprobe using Synchrotron Radiation. Nucl. Instr. Meth. A291(146)

    Google Scholar 

  97. - Worgan JS (1982) Nucl. Instr. Meth. 201 85

    Article  CAS  Google Scholar 

  98. - X-Ray Data Booklet. Published by: Lawrence Berkeley Lab, Technical Information Dept PUB-490 Rev.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institut für Anorganische und Angewandte Chemie, Universität Hamburg, Deutschland

    Gerhard Gaul & Arndt Knöchel

Authors
  1. Gerhard Gaul
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Arndt Knöchel
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. Bismarckstr. 4, D-69469, Weinheim, Deutschland

    Helmut Günzler

  2. Fachbereich Chemie, Universität Leipzig, Talstr. 35, D-04103, Leipzig, Deutschland

    Rolf Bordsorf

  3. Institut für anorganische und analytische Chemie, Friedrich-Schiller-Universität, Steiger 3, D-07743, Jena, Deutschland

    Klaus Danzer (Chemische Fakultät) (Chemische Fakultät)

  4. Institut Fresenius, Im Maisel, D-65232, Taunusstein, Deutschland

    Wilhelm Fresenius

  5. Weimarerstr. 69, D-67071, Ludwigshafen, Deutschland

    Walter Huber

  6. Dr. Karl Thomae GmbH Analytik/Qualitätskontrolle, Postfach 1755, D-88400, Biberach, Deutschland

    Ingo Lüderwald

  7. Institut für Spektrochemie und angewandte Spektroskopie, Postfach 10 13 52, D-44013, Dortmund 1, Deutschland

    Günter Tölg

  8. Robert-Bosch-Krankenhaus, Auerbachstr. 110, D-70376, Stuttgart, Deutschland

    Hermann Wisser

Rights and permissions

Reprints and permissions

Copyright information

© 1994 Springer-Verlag Berlin/Heidelberg

About this chapter

Cite this chapter

Gaul, G., Knöchel, A. (1994). Röntgenfluoreszenzanalyse mit Synchrotronstrahlung. In: Günzler, H., et al. Analytiker-Taschenbuch. Analytiker-Taschenbuch, vol 12. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-78858-1_6

Download citation

  • DOI: https://doi.org/10.1007/978-3-642-78858-1_6

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-78859-8

  • Online ISBN: 978-3-642-78858-1

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation