Summary
Slope changes of the lattice constants and dc magnetization measurements as a function of the oxygen content of powder 123 samples, indicate the existence of three phases with phase boundaries at x ≅ 6.75 and x ≅ 6.91. In addition, a splitting of the derivative of the magnetization curve appears at x ≥ 6.95. These results are discussed in terms of a three-phase model. It is shown that oxygen inhomogeneities of the grains cannot be the reason for the double peaks in specific heat and magnetization.
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Conder, K. et al. (1994). Indications for a Phase Separation in YBa2Cu3O7−x . In: Sigmund, E., Müller, K.A. (eds) Phase Separation in Cuprate Superconductors. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-78805-5_16
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DOI: https://doi.org/10.1007/978-3-642-78805-5_16
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