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Static Light Scattering of Polyelectrolyte Complex Solutions

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Macromolecular Complexes in Chemistry and Biology

Abstract

The study of highly diluted polyelectrolyte complex (PEC) solutions by physico-chemical methods allows the assessment of the influence of the molecular characteristics of the polyelectrolyte components and of the external parameters of the systems investigated. Especially static light scattering (SLS) has been proved to provide instructive quantitative data about the course of PEC formation and the structural parameters of the generated particles. After a brief survey of the characterization of PEC solutions by SLS an improved algorithm of light scattering curve analysis for higher aggregated structures is described. Its efficiency will be demonstrated by the results of SLS studies on the complex formation between anionically and cationically modified poly(acrylamide) of high molecular weight in comparison with the information obtained by other methods.

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Authors
  1. H. Dautzenberg
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  2. J. Koetz
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  3. K.-J. Linow
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  4. B. Philipp
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  5. G. Rother
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Editor information

Editors and Affiliations

  1. Dept. of Chemistry, Indiana-Purdue University, 402 N. Blackford Street, Indianapolis, IN, 46202-3274, USA

    Paul Dubin

  2. Exxon Research & Engineering Company, Route 22, East, Annandale, NJ, 08801, USA

    J. Bock  & Donald N. Schulz  & 

  3. Dept. of Chemical Engineering, VPI & SU, Blacksburg, VA, 24061, USA

    Richie Davis

  4. Biological Transport Laboratory, School of Engineering and Applied Scence, Washington University, St. Louis, MO, 63130-4899, USA

    Curt Thies

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© 1994 Springer-Verlag Berlin Heidelberg

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Dautzenberg, H., Koetz, J., Linow, KJ., Philipp, B., Rother, G. (1994). Static Light Scattering of Polyelectrolyte Complex Solutions. In: Dubin, P., Bock, J., Davis, R., Schulz, D.N., Thies, C. (eds) Macromolecular Complexes in Chemistry and Biology. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-78469-9_8

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  • DOI: https://doi.org/10.1007/978-3-642-78469-9_8

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-78471-2

  • Online ISBN: 978-3-642-78469-9

  • eBook Packages: Springer Book Archive

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