Abstract
Technological progress has certainly made life more pleasant but it has also increased the danger of environmental pollution. Groundwater is among the most seriously threatened environmental resources. Although groundwater contamination has occurred for centuries, population demands and agricultural activities, as well as increased industrialization, have certainly exacerbated the problem. Much of the concern over groundwater quality is due to the occurrence of anthropogenic organic compounds in these water resources; this concern is reflected by the U.S. priority pollutants list in which organic compounds are the majority (114/129≈88%) [Callahan et al. 1979].
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Bailey GW, White JL, Rothberg T (1968) Adsorption of organic herbicides by montmorillonite. Role of pH and chemical character of adsorbate. Soil Sci Soc Am Proc 32:222–234.
Bolt GH, Bruggenwert MGM (1978) Soil Chemistry. A. Basic elements. John Wiley & Sons, Inc, New York.
Bolt GH, Van Riemsdijk WH (1987) Surface chemical processes in soil. In: Stumm W (ed) Aquatic surface chemistry, John Wiley & Sons, Inc, New York Chichester Toronto Singapore, p 127.
Briggs AA (1981) Theoretical and experimental relationships between soil adsorption, octanol/water partition coefficients, water solubilities, bioconcentration factors, and the parachor. J Agric Food Chem 29:1050–1057.
Brown DS, Flag EV (1981) Empirical prediction of organic pollutant sorption in natural sediments. J Environ Qual 10:382–387.
Callahan MA, Slimak M, Gbel N, May I, Fowler C, Freed R, Jennings P, DuPree R, Whitmore F, Maestri B, Holt B, Gould C (1979) Water related environmental fate of 129 priority pollutants. EPA-44014-79029a,b, NTIS.
Chiou CT, Peters LJ, Freed VJ (1979) A physical concept of soil-water equilibria for non ionic organic compounds. Science 206:831–832.
Davis GA, Gloor R (1981) Adsorption of dissolved organics in lake water by aluminum oxide. Effect of molecular weight. Environ Sci Techn 15:1223–1229.
Dick SG, Fuerstenau DW, Healy TW (1971) Adsorption of alkylbenzene sulfonate surfactants at the alumina-water interface. J Colloid Interface Sci 37:595–602.
Dixon JB, Weed SB (eds) (1977) Minerals in soil environments. Soil Science Society of America, Madison, WI.
Felsot A, Dahm PA (1979) Sorption of organophosphorous and carbamate insecticides by soil. J Agric Food Chem 27:557–559.
Fenn DB, Mortland MM (1972) Interlamelar metal complexes on layer silicates:2. Phenol complexes in smectites. In: Proc. Int. Clay Conf., Madrid, 591–603.
Gerstl Z (1989) Predicting the mobility and availability of toxic organic chemicals. In: Gerstl Z, Chen Y, Mingelgrin U, Yaron B (eds) Toxic organic chemicals in porous media. Springer, Berlin Heidelberg New York, p 151.
Grim RE (1968) Clay mineralogy. McGraw Hill, New York.
Hassett JJ, Banwart WL, Wood SG, Means JC (1981) Sorption of α-Naphthol; implications concerning the limits of hydrophobic sorption. Soil Sci Soc Am J 45:38–42.
Hassett JJ, Banwart WL, Griffin RA (1983) Correlation of compound properties with sorption characteristics of nonpolar compounds by soils and sediments: concept and limitations. In: Francis CW, Auerback SI (eds) Characterization, treatment and disposal, environment and solid wastes. Butterworth Publishers, p 161.
Haymaker JW, Thompson JM (1972) Adsorption. In: Goring CM, Haymaker JM (eds) Organic chemicals in the soil environment, Dekker, New York p 49.
Horzempa LM, Di Toro DM (1983) The extent of reversibility of polychlorinated biphenil adsorption. Water Res 17:851–859.
Howard PH (ed)(1989) Handbook of environmental fate and exposure data for organic chemicals. Lewis Publishers, Inc, Chelsea, Michigan.
Israelachvili JN (1985) Intermolecular and surface forces. Academic Press, London
Javfert CT, Westall JC, Glieder E, Schwarzenbach RP (1990) Distribution of hydrophobic ionogenic organic compounds between octanol and water: organic acids. Enviro Sci Technol 24:1795–1803.
Jones RAY (1979) Physical and mechanistic organic chemistry. Cambridge University Press, Cambridge U.K.
Karickhoff S, Brown DS, Scott T (1979) Sorption of hydrophobic pollutants on natural sediments. Wat Res 13:241–248.
Karickhoff SW (1984) Organic pollutant sorption in aquatic systems. J Hydraul Eng 110:707–735.
Kenaga EE, Goring CAI (1980) Aquatic Toxicology. Eaton JG, Parrish PR, Hendricks (eds), ASTM special publication 770, Philadedelphia.
Kortum G (1966) Lehrbuch der elektrochemie. Verlag Chemie, GMBH Weinheim
Kown BT, Ewing BB (1969) Effect of the organic adsorption on clay ion exchange properties. Soil Sci 108:321–325.
Lee SL, Rao PSC, Nkedi-Kizza P, Delfino JJ (1990) Influence of solvent and sorbent characteristics on distribution of pentachlorophenol in octanol-water and soil-water systems. Environ Sci Technol 24:654–661.
Lyman WJ, Reehl WF, Rosenblatt DH (eds) (1982) Handbook of chemical property estimation methods; Environmental behavior of organic compounds. Mc Graw-Hill, New York.
Means JC, Wood SG, Hassett JJ, Banwart WL (1980) Sorption of polynuclear aromatic hydrocarbons by sediments and soils. Environ Sci Technol 14:1524–1528.
Mingelgrin U, Gerstl Z (1983) Reevaluation of partitioning as a mechanism of nonionic chemical adsorption in soils. J Environ Qual 12:1–11.
Mortland MM (1970) Clay-organic complexes and interactions. Adv Agron 22:75–117
Nemethy G, Scheraga HA (1962) Structure of water and hydrophobic bonding in proteins. II: model for the thermodynamics properties of aqueous solutions of hydrocarbons. J Chem Phys 36:3401–3411.
Philen OD Jr, Weed SB, Weber JB (1970) Estimation of surface charge density of mica and vermiculite by competitive adsorption of Diquat vs. Paraquat. Soil Sci Soc Am Proc 34:527–531.
Philen OD Jr, Weed SB, Weber JB (1971) Surface charge characteristics of layer silicates by competitive adsorption of two organic divalent cations. Clays Clay Miner 19:295–302.
Rao PSC, Davison JM (1980) Estimation of pesticide retention and transformation parameters required in nonpoint source pollution models. In: Overcash MR, Davison JM (eds) Environmental impact of nonpoint source pollution. Ann Arbor Science Publischers, Ann Arbor, p 23.
Salzman S, Yariv S (1975) Infrared study of the sorption of phenol and p-nitrophenol by montmorillonite. Soil Sci Soc Am J 39:474–479.
Schindler PW, Walti E, Furst B (1976) The role of surface hydroxyl groups in the surface chemistry of metal oxides. Chimia 30:107–109.
Schofield RK (1949) Effect of electric charges carried by clay particle. J Soil Sci 1:1–8.
Schwarzenbach RP, Westall J (1981) Transport of non polar organic compounds from surface water to groundwater. Laboratory sorption studies. Environ Sci Technol 15:1360–1367.
Scwarzenbach RP, Westall J (1985) Sorption of hydrophobic trace organic compounds in groundwater system. Wat Sci Tech 17:39–55.
Sposito G (1984) The surface chemistry of soils. Oxford University Press, New York.
Stumm W, Morgan JJ (1981) Aquatic Chemistry. 2nd edn. John Wiley & Sons, Inc, New York London Sidney Toronto.
Thomas JM (1961) The existence of endothermic adsorption. J Chem Ed 38:138–139.
Thurman EM (1985) Organic geochemistry of natural waters. Nijhoff M, Junk W, Dordrecht Boston Lancaster.
Tipping H, Cooke JP (1981) Adsorption of organic matter by alumina. Geochim Cosmoch Acta 46:75–80.
Weast RC, Lide DR, Astle MJ, Beyer WH (eds) (1990) Handbook of Chemistry and Physics, 70th edn. CRC Press, Inc, Boca Raton, Florida.
Weber WJ Jr, Voice TC, Pirbazari M, Hunt GE, Ulanoff DM (1983) Sorption of hydrophobic compounds by sediments, soils and suspended solids. II. Sorbent evaluation studies. Water Res 17:1443:1452.
Weber WJ Jr, McGinley PM, Katz LE (1991) Sorption phenomena in subsurface systems: concept, models and effect on contaminant fate and transport. Wat Res 25:499–528.
Westall JC (1987) Adsorption mechanisms in aquatic surface chemistry. In: Stumm W (ed) Aquatic surface chemistry. 1st edn. John Wiley & Sons, Inc, New York London Sidney Toronto, p 3.
Zettlemoyer AC, Micale FJ (1971) Solution adsorption thermodynamics for organics on surfaces. In: Faust SD, Hunter JV (eds) Organic compounds in aquatic environments. Marcel Dekker, Inc, New York, p 165.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1993 Springer-Verlag Berlin Heidelberg
About this paper
Cite this paper
Lopez, A., Petruzzelli, D. (1993). Interactions of Toxic Organics with Subsoils Components. In: Petruzzelli, D., Helfferich, F.G. (eds) Migration and Fate of Pollutants in Soils and Subsoils. NATO ASI Series, vol 32. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-77862-9_5
Download citation
DOI: https://doi.org/10.1007/978-3-642-77862-9_5
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-77864-3
Online ISBN: 978-3-642-77862-9
eBook Packages: Springer Book Archive