Skip to main content

Exposure to Oxidant Gases and Acidic Particles in the United States

  • Conference paper
Advances in Controlled Clinical Inhalation Studies

Part of the book series: ILSI Monographs ((ILSI MONOGRAPHS))

  • 57 Accesses

Abstract

Primary public health issues associated with air pollution in the United States involve ozone (and other oxidants), toxic organic substances, and possibly acidic particles. The precursor pollutant sources are common for oxidants and acid aerosols, and each can accumulate in urban and rural areas. National Ambient Air Quality Standards (NAAQS) presently exist for ozone (O3), the nitrogen oxides, carbon monoxide, particulate matter, sulfur dioxide, and lead. There are none for sulfuric acid, even though there is a World Health Organization (WHO) (1985) guideline for that substance. The US EPA (1988) is evaluating the need for a standard. Other oxidant gases, such as formaldehyde (HCHO) and nitric acid (HNO3), do not have standards. The WHO (1985), however, has guidelines for HCHO.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Similar content being viewed by others

References

  • Appel BR, Hoffer EM, Tokiwa Y, Kothny EL (1982) Measurement of sulfuric acid and particulate strong acidity in the Los Angeles basin. Atmos Environ 16: 589–593

    Article  CAS  Google Scholar 

  • Atkinson R, Lloyd AC (1984) Evaluation of kinetic and mechanistic data for modeling of photochemical smog. J Phys Chem Ref Data 13:315–444

    Article  CAS  Google Scholar 

  • Berglund RL, Dittenhoefer AC, Ellis HM, Watts BJ, Hansen JL (1988) Evaluation of the stringency of alternate forms of a national ambient air quality standard for ozone. TR-12 Acid and Waste Management Association, Pittsburgh, pp 343–369

    Google Scholar 

  • Cadle SH (1985) Seasonal variations in nitric acid, nitrate, strong aerosol acidity and ammonia in an urban area. Atmos Environ 19:181–188

    Article  CAS  Google Scholar 

  • Calvert JG, Stockwell WR (1983) Acid generation in the troposphere by gas-phase chemistry. Environ Sci Technol 17:428a-43a

    Article  CAS  Google Scholar 

  • Cleveland WS, Kleiner B, McRae JE, Warner JL (1976) Photochemical air pollution: transport from New York City area into Connecticut and Massachusetts. Science 191:179–181

    Article  PubMed  CAS  Google Scholar 

  • Cobourn WG, Husar RB (1982) Diurnal and seasonal patterns of particulate sulfur and sulfuric acid in St Louis, July 1977-June 1978. Atmos Environ 16:1441–1450

    Article  CAS  Google Scholar 

  • Commins BT, Waller RE (1967) Observations from a ten-year study of pollution at a site in the city of London. Atmos Environ 1:49–68

    Article  CAS  Google Scholar 

  • Ellestad TG (1980) Aerosol composition of urban plumes passing over a rural monitoring site. Ann NY Acad Sci 338:202–218

    Article  CAS  Google Scholar 

  • Finlayson-Pitts BJ, Pitts JN Jr (1976) Photochemistry of the polluted atmosphere. Science 192:111–119

    Article  Google Scholar 

  • Folinsbee LJ, McDonnell WF, Horstman DH (1988) Pulmonary function and symptom responses after 6.6 hour exposure to 0.12ppm ozone with moderate exercise. J Air Pollut Control Assoc 38:28–35

    CAS  Google Scholar 

  • Gearhart JM, Schlesinger RB (1989) Sulfuric acid induced changes in the physiology and structure of the tracheobronchial airways. Environ Health Perspect 79: 127–137

    Article  PubMed  CAS  Google Scholar 

  • Gillani NV, Kohli S, Wilson WE (1981) Gas-to-particle conversion of sulfur in power plant plumes-I. Parameterization of the conversion rate for dry moderately polluted ambient conditions. Atmos Environ 15:2293–2313

    Article  CAS  Google Scholar 

  • Gillani Colby JA, Wilson WE (1983) Gas-to-particle conversion of sulfur in power plant plumes. III. Parameterization of plume-cloud interaction. Atmos Environ 17:1753–13

    Article  Google Scholar 

  • Graedel TE, Farrow LA, Weber TA (1976) Kinetic studies of the photochemistry of the urban atmosphere. Atmos Environ 10:1095–1116

    Article  CAS  Google Scholar 

  • Ito K, Thurston GD (1987) The estimation of London England aerosol exposures from historical visibility records. Proceedings of the 80th International Air Pollution Control Association (APCA) Annual Meeting, Pittsburgh, p 422

    Google Scholar 

  • Jeffries HE, Sexton KG, Salmi CN (1981) Effects of chemistry and meteorology on ozone calculations using simple trajectory models and the EKMA procedure. US Environmental Protection Agency (USEPA), Research Triangle Park NC (EPA-450/4–81-034)

    Google Scholar 

  • Koenig JQ, Pierson WE, Horike M (1983) The effects of inhaled sulfuric acid on pulmonary function in adolescent asthmatics. Am Rev Respir Dis 128:221–225

    PubMed  CAS  Google Scholar 

  • Larson TV, Covert DS, Frank R (1978) Respiratory NH3: a possible defense against inhaled acid sulfate compounds In: Folinsbee LF et al. (eds) Environmental stress: individual human adaptations. Academic, New York, pp 91–99

    Google Scholar 

  • Lioy PJ, Dyba RV (1989) Tropospheric ozone: the dynamics of human exposure. Toxicol Ind Health 5:493–504

    PubMed  CAS  Google Scholar 

  • Lioy PJ, Lippmann M (1986) Measurement of exposure to acidic sulfur aerosols. In: Lee SD, Schneider T, Grant LD, Verkerk PJ (eds) Aerosols: research risk assessment and control strategies. Lewis, Chelsea, pp 743–752

    Google Scholar 

  • Lioy PJ, Waldman JM (1989) Acidic sulfate aerosols: characterization and exposure. Environ Health Perspect 79:15–34

    Article  PubMed  CAS  Google Scholar 

  • Lioy PJ (1989) Expose to oxidants and acids. Ann Rev Public Health 10:69–84

    Article  CAS  Google Scholar 

  • Lioy PJ, Samson PJ, Tanner RL, Leaderer BP, Minnich T, Lyons W (1980) The distribution and transport of sulfate “species” in the New York metropolitan area during the 1977 summer aerosol study. Atmos Environ 14:1391–1407

    Article  CAS  Google Scholar 

  • Lioy PJ, Vollmuth TA, Lippmann M (1985) Persistence of peak flow decrement in children following ozone exposures exceeding the NAAQS. J Air Pollut Control Assoc 35:1068–1071

    CAS  Google Scholar 

  • Lioy PJ, Spektor D, Thurston G, Citak K, Lippmann M et al. (1987) The design considerations for ozone and acid aerosol exposure and health investigations: the Fairview Lake summer camp-photochemical smog case study. Environ Int 13:271–283

    Article  CAS  Google Scholar 

  • Lippmann M (1985) Airborne acidity: estimates of exposure and human effects. Environ Health Perspect 63:63–70

    Article  PubMed  CAS  Google Scholar 

  • Lippmann M (1989) Effects of ozone on respiratory function and structure. Annu Rev Public Health 10:49–68

    Article  PubMed  CAS  Google Scholar 

  • Lodge JP Jr (1969) Selections of the smoke of London Two Prophecies. Maxwell, Elmsford

    Google Scholar 

  • Lyons WA, Olsson LE (1972) Mesoscale air pollution transport in the Chicago lake breeze. J Air Pollut Control Assoc 22:876–881

    Google Scholar 

  • Mage DT, Raizenne M, Spengler J (1985) The assessment of individual human exposures to ozone in a health study. In: Lee SD (ed) Trans APCA 4:238–249

    Google Scholar 

  • Martinez JR, Singh HB (1979) Survey of the role of NO in nonurban ozone formation. USEPA (US Environmental Protection Agency) Research Triangle Park (EPA report #EPA-450/4–79-035)

    Google Scholar 

  • McDonnell WF, Horstman DH, Hazucha MJ, Seal E, Haak ED et al. (1983) Pulmonary effects of ozone exposure during exercise: dose response characteristics. J Appl Physiol 54:1345–1352

    Google Scholar 

  • Morandi MT, Kneip TJ, Cobourn WG, Husar R, Lioy PJ (1983) The measurement of H2SO4 and other sulfate species at Tuxedo NY with a thermal analysis flame photometric detector and simultaneously collected quartz filter samples. Atmos Environ 17:843–848

    Article  CAS  Google Scholar 

  • Paul RA, Biller WF, McCurdy T (1987) National estimates of population exposure to ozone. Proceedings of the 80th International Air Pollution Control Association (APCA) Annual Meeting, Pittsburgh, pp 87–427

    Google Scholar 

  • Pierson WR, Brachaczek WW, Truex TJ, Butler JW, Korniski TJ (1980) Ambient sulfate measurements on Allegheny Mountain and the question of atmospheric sulfate in the northeastern US. Ann NY Acad Sci 338:145–173

    Article  CAS  Google Scholar 

  • Raizenne ME, Stern B, Burnett PT, Franklin CA, Spengler JD (1989) Acute Pulmonary function responses to ambient acid aerosol exposures. Environ Health Perspect 79:129–186

    Article  Google Scholar 

  • Rombout PJ, Lioy PJ, Goldstein BG (1986) Rationale for an 8-hour ozone standard. J Air Pollut Control Assoc 36:913–917

    CAS  Google Scholar 

  • Samet JM, Marbury MC, Spengler JD (1988) Health effects and sources of indoor air pollution, part II. Am Rev Respir Dis 137:221–242

    Article  PubMed  CAS  Google Scholar 

  • Schlesinger RB (1985) Effects of inhaled acids on respiratory tract defense mechanisms. Environ Health Perspect 63:25–38

    Article  PubMed  CAS  Google Scholar 

  • Schlesinger RB, Naumann BD, Chen LC (1983) Physiological and histological alterations in bronchial mucociliary clearance system of rabbits following intermittent oral and nasal inhalation of sulfuric acid mist. J Toxicol Environ Health 12:441–465

    Article  PubMed  CAS  Google Scholar 

  • Speizer FE (1989) Studies of acid aerosols in six cities and in a new multicity investigation; design issues. Environ Health Perspect 79:69–72

    Article  Google Scholar 

  • Spektor DM, Yen BM, Lippmann M (1989) Effect of concentration and cumulative exposure of inhaled sulfuric acid on tracheobronchial particle clearane in healthy humans. Environ Health Perspect 79:167–172

    Article  PubMed  CAS  Google Scholar 

  • Spengler JD, Keeler GJ, Koutrakis P, Raizenne ME (1989) Exposures to acid aerosols. Environ Health Perspect 79:48–52

    Article  Google Scholar 

  • Spengler JD, Brauer M, Koutrakis P (1990) Acid air and health. Environ Sci Technol 24:946–955

    Article  CAS  Google Scholar 

  • Spicer CW, Holdren MW, Keigley GW (1983) The ubiquity of peroxyacetyl nitrate in the continental boundary layer. Atmos Environ 17:1055–1058

    Article  Google Scholar 

  • Tanner RL, Marlow WH (1977) Size discrimination and chemical composition of ambient airborne sulfate particles by diffusion sampling. Atmos Environ 11:1143–1150

    Article  CAS  Google Scholar 

  • Tanner RL, Leaderer BP, Spengler JD (1981) Acidity of atmospheric aerosols: a summary of data concerning their chemical nature and amounts of acid. Environ Sci Technol 15:1150–1153

    Article  CAS  Google Scholar 

  • Tuazon EC, Winer AM, Pitts JN Jr (1981) Trace pollutant concentrations in a multiday smog epidose in the California South Coast Air Basin by long path Fourier transformation infrared spectrometry. Environ Sci Technol 15:1232–1237

    Article  CAS  Google Scholar 

  • US EPA (Environmental Protection Agency) (1985) Air quality criteria for ozone and other photochemical oxidants, vols I-IV EC AO, Research Triangle Park NC (EPA-600/8–84-20b)

    Google Scholar 

  • US EPA (Environmental Protection Agency) (1990) Acid aerosols issue paper. USEPA, Research Triangle Park NC (EPA report #EPA-600/8–88-005A)

    Google Scholar 

  • US EPA (Environmental Protection Agency) (1990) National air quality emissions trends report (1988). (EPA Office of Air Quality Planning and Standards #EPA-450/4–90-002 March 1990)

    Google Scholar 

  • Vukovich FM, Fishman J (1986) The climatology of summertime ozone and sulfur dioxide (1977–1981). Atmos Environ 20:2423–2433

    Article  CAS  Google Scholar 

  • Waldman JM, Lioy PJ, Thurston G, Lippmann M (1990) Analyses of spatial and temporal patterns in sulfate aerosol acidity and neutralization within a metropolitan area. Atmos Environ 24B:115–126

    Google Scholar 

  • Waldman JD, Lioy PJ, Zelenka M, Jing L, Lin YN, He QC, Qian ZM, Chapman R, Wilson WE (1991) Wintertime measurements of aerosol acidity and trace elements in Wuhan A City in Central China. Atmos Environ 24B: (in press)

    Google Scholar 

  • Waller RE, Lawther PJ (1957) Further observations on London fog. Br Med J 4:1473–1475

    Article  Google Scholar 

  • Wolff GT, Lioy PJ (1980) Development of an ozone river associated with synoptic scale episodes in the eastern United States. Environ Sci Technol 14:1257–1260

    Article  CAS  Google Scholar 

  • Wolff GT, Kelly NA, Ferman MA (1982) Source regions of summertime ozone and haze episodes in the eastern United States. Water Air Soil Pollut 18:65–81

    Article  CAS  Google Scholar 

  • World Health Organization (1985) World Health Organization Working Group on air quality guidelines for major urban air pollutants. WHO, Bilthoven, pp 14–19

    Google Scholar 

  • Yocum JE (1982) Indoor-outdoor air quality relationships: a critical review. J Air Pollut Control Assoc 32:500–520

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1993 Springer-Verlag Berlin Heidelberg

About this paper

Cite this paper

Lioy, P.J. (1993). Exposure to Oxidant Gases and Acidic Particles in the United States. In: Mohr, U., Bates, D.V., Fabel, H., Utell, M.J. (eds) Advances in Controlled Clinical Inhalation Studies. ILSI Monographs. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-77176-7_4

Download citation

  • DOI: https://doi.org/10.1007/978-3-642-77176-7_4

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-77178-1

  • Online ISBN: 978-3-642-77176-7

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics