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Muonium Substituted Molecules

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Exotic Atoms in Condensed Matter

Part of the book series: Springer Proceedings in Physics ((SPPHY,volume 59))

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Abstract

The manner in which Muon Spin Rotation and Level Crossing Resonance are used to characterise muonium substituted organic radicals is described, and illustrated with spectra for the ethyl radical and related species. Comparison with ESR data for the unsubstituted radicals reveals significant structural and hyperfine isotope effects which can be traced to the effects of zero point motion. The first comparable results for a diamagnetic species, exhibiting a quadrupole isotope effect by comparison with conventional NQR data, are presented and discussed.

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References

  1. D C Walker, “Muon and muonium chemistry” Cambridge (1983)

    Google Scholar 

  2. D G Fleming, D M Garner, L C Vaz, D C Walker, J H Brewer and K M Crowe, “Positron and Muonium Chemistry” Advances in Chemistry Series, ed H J Ache (Am Chem Soc, Washington DC) 175 (1979) 279

    Google Scholar 

  3. E Roduner, W Strub, P Burkhard, J Hochmann, P W Percival, H Fischer, M Ramos and B C Webster, “Chem Phys 67 (1982) 275 (for more recent references, see also E Roduner: “The positive muon as a probe in free radical chemistry”, Springer Verlag Lecture Notes in Chemistry 49 (1988)

    Article  Google Scholar 

  4. M C R Symons, “Chemical and biochemical aspects of ESR spectroscopy” Van Nostrand Reinhold (1978)

    Google Scholar 

  5. S F J Cox and M C R Symons, Radiat Phys Chem 27 (1986) 53

    Google Scholar 

  6. Estimated by E Roduner: private communication (1990)

    Google Scholar 

  7. E Roduner and D M Garner, Hyp Int 32 (1986) 733

    Article  ADS  Google Scholar 

  8. P W Percival, J-C Brodovitch, S-K Leung, D Yu, R F Kiefl, D M Garner, D J Arseneau, D G Fleming, A Gonzalez, J R Kempton, M Senba, K Venkataswaran and S F J Cox, Chem Phys Lett 163 (1989) 241

    Article  ADS  Google Scholar 

  9. A Abragam, CR Acad Sci (Paris) 299 (1984) 95

    Google Scholar 

  10. R F Kiefl, S R Kreitzman, M Celio, R Keitel, G M Luke, J H Brewer, D R Noakes, P W Percival, T Matsuzaki and K Nishiyama, Phys Rev A34 (1986) 681

    ADS  Google Scholar 

  11. M Heming, E Roduner, B D Patterson, W Odermatt, J Schneider, H Baumeler, H Keller and I M Savic, Chem Phys Lett 128 (1986) 100

    Article  ADS  Google Scholar 

  12. M J Ramos, D McKenna, B C Webster and E Roduner, J Chem Soc Faraday Trans I 80 (1984) 255 and 267

    Article  Google Scholar 

  13. P W Percival, J-C Brodovitch, S-K Leung, D Yu, R F Kiefl, D M Garner, G M Luke, K Venkataswaran and S F J Cox, “Intramolecular motion in organic radicals”, IOP Short Meetings Series (IOP Bristol) 22 (1989) 99

    Google Scholar 

  14. P W Percival, R F Kief!, SR Kreitzman, D M Garner, S F J Cox, G M Luke, J H Brewer, K Nishiyama and K Venkataswaran, Chem Phys Lett 135 (1987) 465

    Article  ADS  Google Scholar 

  15. P W Percival, J-C Brodovitch, S-K Leung, D Yu, R F Kiefl, G M Luke, K Venkataswaran and S F J Cox, Chem Phys 127 (1988) 137

    Article  Google Scholar 

  16. E Roduner and I D Reid, Israel J Chem 29 (1989) 3

    Google Scholar 

  17. T A Claxton and A M Graham, J Chem Soc Faraday Trans I 83 (1988) 2307

    Google Scholar 

  18. T A Claxton, S F J Cox, A M Graham, Dj Maric, P F Meier and S Vogel, Proc μSR 90 (Hyperfine Interactions 65 (1990) 913)

    Article  Google Scholar 

  19. M C R Symons, Hyp Int 17–19 (1984) 771, and

    Article  Google Scholar 

  20. S F J Cox, T A Claxton and M C R Symons. Radiat Phys Chem 28 (1986) 107

    Google Scholar 

  21. S F J Cox, G H Eaton, J E Magraw and C A Scott, Chem Phys Lett 160 (1989) 85

    Article  ADS  Google Scholar 

  22. P W Percival, Radiochimica Acta 26 (1979) 1

    Google Scholar 

  23. S F J Cox, J A S Smith and M C R Symons, Proc μSR 90 (Hyperfine Interactions 65 (1990) 993)

    Article  Google Scholar 

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© 1992 Springer-Verlag Berlin, Heidelberg

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Cox, S.F.J. (1992). Muonium Substituted Molecules. In: Benedek, G., Schneuwly, H. (eds) Exotic Atoms in Condensed Matter. Springer Proceedings in Physics, vol 59. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-76370-0_17

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  • DOI: https://doi.org/10.1007/978-3-642-76370-0_17

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-76372-4

  • Online ISBN: 978-3-642-76370-0

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