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Separation of Copolymers by Composition through Gradient High-Performance Liquid Chromatography

  • Gottfried Glöckner

Abstract

Azeotropic copolymers of this system (stat-copoly(S/AN); r s = 0.41; r AN = 0.04) contain 24 mass% AN or 61.9 mol% S. Products of about this composition are commercially available. Furthermore, S/AN is of importance for high-impact ABS composite polymers. S/ANs with less than 40 mass% AN are soluble in common organic solvents whereas copolymers richer in AN require DMF or DMSO which are solvents even for polyacrylonitrile.

Keywords

Block Copolymer Methyl Methacrylate Methyl Acrylate Silica Column Gradient HPLC 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    Scholtan W, Kwoll FJ (1972) Makromol Chem 151: 33CrossRefGoogle Scholar
  2. 2.
    Teramachi S, Obata R, Yamashita K, Takemoto N (1977) J Macromol Sci All: 535Google Scholar
  3. 3.
    Ogawa S, Sakai M (1981) J Polym Sci A-2, Polym Phys 19: 1377Google Scholar
  4. 4.
    Teramachi S, Fukao T (1974) Polym J 6: 532CrossRefGoogle Scholar
  5. 5.
    Glöckner G, Francuskiewicz F, Müller K-D (1971) Plaste and Kautschuk 18: 654Google Scholar
  6. 6.
    Glöckner G, Kroschwitz H, Meissner C (1982) Acta Polymerica 33: 614CrossRefGoogle Scholar
  7. 7.
    Glöckner G (1983) Pure Appl Chem 55: 1553CrossRefGoogle Scholar
  8. 8.
    Glöckner G, van den Berg JHM (1984) Chromatographia 19: 55CrossRefGoogle Scholar
  9. 9.
    Glöckner G, van den Berg JHM, Meijerink NL, Scholte TG, Koningsveld R (1984) Macro-molecules 17: 962CrossRefGoogle Scholar
  10. 10.
    Glöckner G, Koningsveld R (1983) Makromol Chem, Rapid Commun 4: 529CrossRefGoogle Scholar
  11. 11.
    Glöckner G, van den Berg JHM, Meijerink NL, Scholte TG (1986) In: Kleintjens L and Lemstra P (eds) Integration of fundamental polymer science and technology, Elsevier, Barking, UK p 85CrossRefGoogle Scholar
  12. 12.
    Glöckner G, van den Berg JHM, (1987) J Chromatogr 384: 135CrossRefGoogle Scholar
  13. 13.
    Glöckner G, van den Berg JHM (1987) Chromatographia 24: 233CrossRefGoogle Scholar
  14. 14.
    Danielewicz M, Kubin M, Vozka S (1982) J Appl Polym Sci 27: 3629CrossRefGoogle Scholar
  15. 15.
    Teramachi S, Hasegawa A, Shima Y, Akatsuka M, Nakajima M (1979) Macromolecules 12: 992CrossRefGoogle Scholar
  16. 16.
    Sato H, Takeuchi H, Tanaka Y (1986) Macromolecules 19: 2613CrossRefGoogle Scholar
  17. 17.
    Mourey TH (1986) J Chromatogr 357: 101CrossRefGoogle Scholar
  18. 18.
    Sparidans RW, Claessens HA, van Doremaele GHJ, van Herk AM (1990) J Chromatogr 508:319CrossRefGoogle Scholar
  19. 19.
    Danielewicz M, Kubin M (1981) J Appl Polym Sci 26:951CrossRefGoogle Scholar
  20. 20.
    Glöckner G, van den Berg JHM (1986) J Chromatogr 352: 511CrossRefGoogle Scholar
  21. 21.
    Teramachi S (1984) personal communicationGoogle Scholar
  22. 22.
    Mori S (1987) J Chromatogr 411: 355CrossRefGoogle Scholar
  23. 23.
    Mori S, Uno Y (1987) Analyt Chem 59: 90CrossRefGoogle Scholar
  24. 24.
    Teramachi S, Hasegawa A, Motoyama K (1987) Polym Preprints, Japan 36: E441Google Scholar
  25. 24a.
    Teramachi S, Hasegawa A, Motoyama K (1987) Polym Preprints, Japan 36: 3169Google Scholar
  26. 25.
    Sato H, Mitsutani K, Shimidzu I, Tanaka Y (1988) J Chromatogr 447: 387CrossRefGoogle Scholar
  27. 26.
    Mori S (1989) J Appl Polym Sci 38: 95CrossRefGoogle Scholar
  28. 27.
    Mori S, Mouri M (1989) Analyt Chem 61: 2171CrossRefGoogle Scholar
  29. 28.
    Glöckner G, Stickler M, Wunderlich W (1987) Fresenius Z Anal Chem 328: 76CrossRefGoogle Scholar
  30. 29.
    Glöckner G, Stickler M, Wunderlich W (1988) Fresenius Z Anal Chem 330: 46CrossRefGoogle Scholar
  31. 30.
    Glöckner G (1987) J Chromatogr 403: 280CrossRefGoogle Scholar
  32. 31.
    Snyder LR (1968) Principles of adsorption chromatography, Marcel Dekker, New YorkGoogle Scholar
  33. 32.
    Rahlwes D, Kirste RG (1977) Makromol Chem 178: 1793CrossRefGoogle Scholar
  34. 33.
    Müller AHE (1981) Makromol Chem 182: 2863CrossRefGoogle Scholar
  35. 34.
    Glöckner G, Müller AHE (1989) J Appl Polym Sci 38:1761CrossRefGoogle Scholar
  36. 35.
    Wunderlich W (1970) Angew Makromol Chem 11: 201CrossRefGoogle Scholar
  37. 36.
    Wunderlich W (1972) J Polym Sci C Polym Symp 39: 145CrossRefGoogle Scholar
  38. 37.
    Cranwels K, Smets G (1950) Bull Soc Chim Belges 59: 443CrossRefGoogle Scholar
  39. 38.
    Stejskal J, Kratochvil P, Straková D (1981) Macromolecules 14: 150CrossRefGoogle Scholar
  40. 39.
    Stejskal J, Kratochvil P, Straková D, Procházka O (1986) Macromolecules 19:1575CrossRefGoogle Scholar
  41. 40.
    Glöckner G, Stickler M, Wunderlich W (1989) J Appl Polym Sci 37: 3147CrossRefGoogle Scholar
  42. 41.
    Sato H, Takeuchi H, Suzuki S, Tanaka Y (1984) Makromol Chem, Rapid Commun 5: 719CrossRefGoogle Scholar
  43. 42.
    Stockmayer WH (1945) J Chem Phys 13: 199CrossRefGoogle Scholar
  44. 43.
    Sato H, Takeuchi H, Tanaka Y (1985) Int Rubber Conf Kyoto [18B15]: 596Google Scholar
  45. 44.
    Hertier WR, Sogah DY, Farnham WB, Rajanbabu TV (1983) J Am Chem Soc 105: 5706CrossRefGoogle Scholar
  46. 45.
    Mai P, Müller AHE (1987) Makromol Chem, Rapid Comm 8: 247CrossRefGoogle Scholar
  47. 46.
    Müller MA, Stickler M (1987) Makromol Chem, Rapid Comm 7: 575CrossRefGoogle Scholar
  48. 47.
    Müller MA, Augenstein M, Dumont E, Pennewiß H New Polymerie Materials (submitted for publ.)Google Scholar
  49. 48.
    Augenstein M, Stickler M (1990) Makromol Chemie 191:415CrossRefGoogle Scholar
  50. 49.
    Hagnauer GL, Setton I (1978) J Liq Chromatogr 1: 55CrossRefGoogle Scholar
  51. 50.
    Hagnauer GL (1980) Polym Compos 1: 81CrossRefGoogle Scholar
  52. 51.
    Crabtree DJ, Hewitt DB (1977) Chromatogr Sci 8: 63Google Scholar
  53. 52.
    Shiono S, Karino I, Ishamura A, Enomoto J (1980) J Chromatogr 193: 243CrossRefGoogle Scholar
  54. 53.
    Byrne CA, Hagnauer GL, Schneider NS (1983) Polym Compos 4: 206CrossRefGoogle Scholar
  55. 54.
    Noel D, Cole KC, Hechler J-J, Chouliotis A, Overbury KC (1986) J Appl Polym Sci 32: 3097CrossRefGoogle Scholar
  56. 55.
    Klee J, Hörold H-H Tänzer W, Fedtke M (1986) Acta Polym 37: 272CrossRefGoogle Scholar
  57. 56.
    Klee J, Hörold H-H, Tänzer W, Fedtke M (1987) Angew Makromol Chem 147: 71CrossRefGoogle Scholar
  58. 57.
    Mestan SA, Morris CEM (1984) J Macromol Sci, Rev Macromol Chem Phys C24: 117Google Scholar
  59. 58.
    Sebenik A, Lapanje S (1978) Angew Makromol Chem 70:59CrossRefGoogle Scholar
  60. 59.
    Cásiraghi G, Sartori G, Bigi F, Cornia M, Dradi E, Casnati G (1981) Makromol Chem 182: 2151CrossRefGoogle Scholar
  61. 60.
    van der Maeden FPB, Biemond MEF, Janssen PCGM (1978) J Chromatogr 149–539Google Scholar
  62. 61.
    Much H, Pasch H (1982) Acta Polym 33: 366CrossRefGoogle Scholar
  63. 62.
    Werner W, Barber O, Chromatographia 15 (1982) 101CrossRefGoogle Scholar
  64. 63.
    Mechin B, Hanton D, LeGoff J, Tanneur JP (1984) Europ Polym J 20: 333CrossRefGoogle Scholar
  65. 64.
    Mechin B, Hanton D, LeGoff J, Tanneur JP (1986) Europ Polym J 22: 115CrossRefGoogle Scholar
  66. 65.
    Preussler V, Slais K, Hanus J (1987) Angew Makromol Chem 150: 179CrossRefGoogle Scholar
  67. 66.
    Mori S, Saito T, Takeuchi M (1989) J Chromatogr 478: 181Google Scholar
  68. 67.
    Schulz WW, Kaiadas J, Schulz DN (1984) J Polym Sci A-1, Polym Chem 22: 3795Google Scholar
  69. 68.
    Glöckner G (1990) J Appl Polym Sci, Appl Polym Symp, Barth HG, ed. 45:1Google Scholar
  70. 69.
    Wild L, Ryle TR (1977) Polym Prepr, Am Chem Soc, Polym Chem Div 18: 182Google Scholar
  71. 70.
    Wild L, Ryle TR, Knobeloch DC, Peat IR (1982) J Polym Sci A-l, Polym Phys 20: 441CrossRefGoogle Scholar
  72. 71.
    Wild L, Ryle TR, Knobeloch DC (1982) Polym Prepr, Am Chem Soc, Polym Chem Div 23: 133Google Scholar
  73. 72.
    Kelusky EC, Elston CT, Murray RE (1987) Polym Engn Sci 27: 1562CrossRefGoogle Scholar
  74. 73.
    Usami T, Gotoh Y, Takayama S (1986) Macromolecules 19: 2722CrossRefGoogle Scholar
  75. 74.
    Nakano S, Goto Y (1981) J Appl Polym Sci 26: 4217CrossRefGoogle Scholar
  76. 75.
    Gotoh Y, Usami T, Takayama S (1988) Poster Presentation at 1st ISPAC Meeting Toranto, June 2–3Google Scholar
  77. 76.
    Hazlitt L (1990) J Appl Polym Sci, Appl Polym Symp, Barth HG, ed. 45:25Google Scholar
  78. 77.
    Bergström C, Avela E (1979) J Appl Polym Sci 23:163CrossRefGoogle Scholar
  79. 78.
    Sparidans RW (1990) Graduation research report, Eindhoven University of Technology, Instrumental Analysis and Polymer ChemistryGoogle Scholar
  80. 79.
    Sato H, Sasaki M, Ogino K (1989) Polym J 21: 965CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 1991

Authors and Affiliations

  • Gottfried Glöckner
    • 1
  1. 1.Technische Universität DresdenDresdenGermany

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