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Transition Metal Clusters and Isolated Atoms in Zeolite Cages

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Chemistry and Physics of Solid Surfaces VIII

Part of the book series: Springer Series in Surface Sciences ((SSSUR,volume 22))

Abstract

Surface science research has made much use of metal single crystals. Results have been obtained of high relevance to chemisorption and catalysis, in particular with respect to the nature of the chemisorption bonds, their dipole moments and their crystal face specificity. The coverage dependence of specific parameters and the important phenomenon of surface reconstruction have also been studied quantitatively. Among the methods used, only field ion and field electron microscopy make use of highly curved surfaces which expose a variety of crystal faces of high and low Miller indices, so that the surface migration can be studied across face boundaries [5.1–3]. Other surface science methods use macroscopic single crystals and focus on one large crystal face, usually of rather high atom density.

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  1. Center for Catalysis and Surface Science, Northwestern University, 60208, Evanston, Illinois, USA

    W. M. H. Sachtler

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  1. W. M. H. Sachtler
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  1. Department of Chemistry and Laboratory for Surface Studies, The University of Wisconsin-Milwaukee, 53201, Milwaukee, WI, USA

    Ralf Vanselow Ph.D.

  2. Department of Chemistry, Private Bag, University of Auckland, Auckland, New Zealand

    Russell Howe

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Sachtler, W.M.H. (1990). Transition Metal Clusters and Isolated Atoms in Zeolite Cages. In: Vanselow, R., Howe, R. (eds) Chemistry and Physics of Solid Surfaces VIII. Springer Series in Surface Sciences, vol 22. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-75762-4_5

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  • DOI: https://doi.org/10.1007/978-3-642-75762-4_5

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