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Contact Dermatitis to Epoxy Resins in Composite Material

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Current Topics in Contact Dermatitis

Summary

An outbreak of allergic contact dermatitis in an aircraft factory where epoxy resinimpregnated materials were employed has been investigated. Of 30 operatives, 20 gave positive reactions to the composite material. In these patients, patch tests with epoxy resin 1% (Firma) gave a positive reaction in only four cases. Patch tests with diglycidyl ether of bisphenol A (DGEBA), tetraglycidyl-4-4′-methylene dianiline (TGMDA), triglycidyl derivative of p-aminophenol (TGPAP) and o-diglycidyl phthalate were performed in 18 of the patients. TGMDA, TGPAP and o-diglycidyl phthalate picked up all the 11 patients positive to the composite materials.

These data confirm that the composite materials must be used as is for patch testing due to the unreliability of the tests performed with common epoxy resin 1% in petrolatum. In addition, they indicate that TGMDA, TGPAP and o-diglycidyl phthalate, which are new constituents of carbon fibre epoxy resin system, can be used in order to reveal the sensitization.

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References

  1. Burrows D, Fregert S, Campbell H, Trulsson L (1984) Contact dermatitis from the epoxy resins tetraglycidyl-4,4′-methylene dianiline and o-diglycidyl phthalate in composite material. Contact Dermatitis 11: 80–82.

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  2. Fregert S, Thorgeirsson A (1977) Patch testing with low molecular oligomers of epoxy resins in humans. Contact Dermatitis 3: 301–303.

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  3. Lembo G, Balato N, Cusano F, Ayala F (1983) Dermatiti da contatto da résine epossidiche in una industria aeronautica. Riv Med Lav Ig Ind 7: 57–64.

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© 1989 Springer-Verlag Berlin Heidelberg

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Lembo, G., Balato, N., Cusano, F., Baldo, A., Ayala, F. (1989). Contact Dermatitis to Epoxy Resins in Composite Material. In: Frosch, P., Dooms-Goossens, A., Lachapelle, JM., Rycroft, R.J.G., Scheper, R.J. (eds) Current Topics in Contact Dermatitis. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-74299-6_78

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  • DOI: https://doi.org/10.1007/978-3-642-74299-6_78

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-74301-6

  • Online ISBN: 978-3-642-74299-6

  • eBook Packages: Springer Book Archive

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