Skip to main content
SpringerLink
Log in

Diolefin Iron Complexes — Useful and Versatile Tools in Organic Synthesis

  • Conference paper
Book cover Organometallics in Organic Synthesis 2

Abstract

This review aims to present our current work, which focuses on the preparation and use of Wittig reagents via allyl-Fe(CO)4 and dienyl-Fe(CO)3 complexes. We have applied these reagents, among others, to the highly stereoselective synthesis of naturally occurring triolefins. In a related topic, the reactivity of functionalized tricarbonyl(diene)iron complexes will be discussed with regard to their use in selective C-C coupling reactions.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 84.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Birch AJ, Jenkins ID, in Alper H.(ed) (1976) Transition-Metal Organometallics in Organic Synthesis, Academic Press, London

    Google Scholar 

  2. Reihlen H, Gruhl A, von Hessling G, Pfrengle O (1930) Liebigs Ann Chem 482: 161

    Article  CAS  Google Scholar 

  3. Bestmann HJ (1979) Pure Appl Chem 51: 515

    Article  CAS  Google Scholar 

  4. Pommer H (1977) Angew Chem 89: 437, Int Ed Engl 16: 423

    Article  CAS  Google Scholar 

  5. Whitesides TH, Arhart RW, Slaven RW (1973) J Am Chem Soc 95: 5792

    Article  CAS  Google Scholar 

  6. Salzer A, Hafner A (1983) Helv Chim Acta 66: 1774

    Article  CAS  Google Scholar 

  7. Gibson DH, Erwin DK (1975) J Organomet Chem 86: C31

    Article  CAS  Google Scholar 

  8. Gower M, John GR, Kane-Maguire LAP, Odiaka TI, Salzer 4 (1979) J Chem Soc Dal ton 2003

    Google Scholar 

  9. Greaves EO, Knox GR, Pauson PL (1969) J Chem Soc, Chem Comm 1124

    Google Scholar 

  10. Graf RE, Lillya CP (1976) J Organomet Chem 122: 377

    Article  CAS  Google Scholar 

  11. Hafner A, von Philipsborn W, Salzer A (1986) Helv Chim Acta 69: 1757

    Article  CAS  Google Scholar 

  12. Nesmeyanow AN, Rybin LV, Gubenko NT, Rybinskaya MI, Petrovski PV (1974) J Organomet Chem 71: 271

    Article  Google Scholar 

  13. Salzer A, Buchmann B unpublished results

    Google Scholar 

  14. Brill TB, Landon SJ (1984) Chem Rev 84: 577

    Article  CAS  Google Scholar 

  15. Lewis ES, Hamp D (1983) J Org Chem 48: 2025

    Article  CAS  Google Scholar 

  16. Worms KH, Schmidt-Dunker M (1976) in: Kosopaloff GM, Maier L (ed) Organophosphorous Compounds. Wiley Interscience, New York

    Google Scholar 

  17. Cotton JD, Heazlewood RL (1969) Aust J Chem 22: 2673

    Article  CAS  Google Scholar 

  18. Birch AJ, Jenkins ID, Liepa AJ (1975) Tetrahedron Lett 1723

    Google Scholar 

  19. Evans J, Howe DV, Johnson BFG, Lewis J (1973) J Organomet Chem 61: C48

    Article  CAS  Google Scholar 

  20. Jaouen G, Lewis J, Johnson BFG (1982) J Organomet Chem 231: C21

    Article  CAS  Google Scholar 

  21. Salzer A (1984) Chimia 38: 421

    CAS  Google Scholar 

  22. Bieri JH, Prewo R, Salzer A, Baumann U unpublished results

    Google Scholar 

  23. Hafer A, Bieri JH, Prewo R, von Philipsborn W, Salzer A (1983) Angew. Chem. 95: 736, Int Ed Engl 22: 713

    Article  Google Scholar 

  24. Jaenicke L, Seferiadis K (1975) Chem Ber 108: 224

    Article  Google Scholar 

  25. Moore RE (1977) Accts Chem Res 10: 40

    Article  CAS  Google Scholar 

  26. Näf F, Decorzant R, Thommen W, Willhalm B, Ohloff G (1975) Helv Chim Acta 58: 1016

    Article  Google Scholar 

  27. Mahler JE, Pettit R (1963) J Am Chem Soc 85: 3955

    Article  CAS  Google Scholar 

  28. Bloch R, Benecou C, Guibe-Jampel E (1985) Tetrahedron Lett 26: 1302

    Google Scholar 

  29. Kiinzer M (1986) Diploma Thesis, University of Zurich

    Google Scholar 

  30. Green M, Greenfield S, Kersting M (1985) J Chem Soc, Chem Comm 18

    Google Scholar 

  31. Kuhn R, Badstübner W, Grundmann C (1936) Chem Ber 69: 98

    Google Scholar 

  32. Houben Weyl (1976) Methoden der Organischen Chemie, Vol 7, Part I. Thieme Stuttgart, 96

    Google Scholar 

  33. Hafner 4, von Philipsborn W, Salzer A (1985) Angew Chem 97: 136, Int Ed Engl 24: 126

    Google Scholar 

  34. Zobl-Ruh S, von Philipsborn W (1981) Helv Chim Acta 64: 2378

    Article  CAS  Google Scholar 

  35. Adams, CM, Cerioni G, Hafner A, Kalchhauser H, von Philipsborn W, Prewo R, Schwenk 4 (1988) Helv Chim Acta 71: 1116

    Article  CAS  Google Scholar 

  36. Monpert A, Martelli R, Gree R, Carrie R (1981) Tetrahedron Lett 22: 1961

    Article  CAS  Google Scholar 

  37. Franck-Neumann in de Meijere A, torn Dieck H (eds) (1988) Organometallics in Organic Synthesis, Springer Verlag Berlin

    Google Scholar 

  38. Whitlock HW, Reich C, Woessner WD (1971) J Am Chem Soc 93: 2483

    Article  CAS  Google Scholar 

  39. Goldschmidt Z, Bakal Y (1984) J Organomet Chem 269: 191

    Article  CAS  Google Scholar 

  40. Prewo R, unpublished results, cited in ref. 42

    Google Scholar 

  41. Ruppli U (1989) Thesis, University of Zurich)

    Google Scholar 

  42. Hafner A (1986) Thesis, University of Zurich

    Google Scholar 

  43. Adams CM (1987) Thesis, University of Zurich

    Google Scholar 

  44. Agosta di Iglesias DI, Bayo V, Retamar JA (1969) Arch Bioquim Quirn Farm 15: 19

    Google Scholar 

  45. Krebs S (1989) Diploma Thesis, University of Zurich

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Anorganisch-Chemisches Institut der Universität Zürich, Winterthurerstr. 190, CH 8057, Zürich, Switzerland

    A. Salzer

Authors
  1. A. Salzer
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. Institut für Anorganische Chemie der Universität Würzburg, Am Hubland, D-8700, Würzburg, Germany

    Helmut Werner

  2. Institut für Organische Chemie der Universität Würzburg, Am Hubland, D-8700, Würzburg, Germany

    Gerhard Erker

Rights and permissions

Reprints and permissions

Copyright information

© 1989 Springer-Verlag Berlin Heidelberg

About this paper

Cite this paper

Salzer, A. (1989). Diolefin Iron Complexes — Useful and Versatile Tools in Organic Synthesis. In: Werner, H., Erker, G. (eds) Organometallics in Organic Synthesis 2. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-74269-9_16

Download citation

  • DOI: https://doi.org/10.1007/978-3-642-74269-9_16

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-50531-0

  • Online ISBN: 978-3-642-74269-9

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation