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Extraction of Volatile Fatty Acids from Spent Medium with a Supported Liquid Membrane

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Abstract

Experimental and analytical studies on extraction of volatile fatty acids (VFAs) from aqueous solution using a supported liquid membrane (SLM) were carried out. Teflon soaked with 20% (w/w) of tri-n- octyl phosphine oxide (TOPO) in kerosene was used as a supporting membrane. The extraction rate of VFAs transferred from acid source across the SLM to the sink was measured. It was observed that only undissociated form of VFAs can penetrate into the SLM and the complex formation between TOPO and VFA (1/1 molar ratio) inside the membrane enhanced a flux of VFA across the membrane. This phenomenon was analyzed by the mathematical models for transfer of permeate across the SLM by carrier-facilitating mechanism. In this extraction system, diffusion of the VFA-TOPO complex inside the membrane was most probably the rate-limiting step for the transfer of VFAs.

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References

  1. Schultz, J. S., Goddard, J. D., and Suchdeo, S. R.: AIChE J. 20, 417 (1974)

    Article  CAS  Google Scholar 

  2. Wittenburg, J. B.: Physiol. Rev. 50, 559 (1970)

    Google Scholar 

  3. Kreuzer, F. and Hoofd, L. J. C.: Respir. Physiol. 15, 104 (1972)

    Article  CAS  Google Scholar 

  4. Otto, N. C. and Quinn, J. A.: Chem. Eng. Sci. 26, 949 (1971)

    Article  CAS  Google Scholar 

  5. Otto, N. C. and Quinn, J. A.: Biotechnol. Bioeng. Symp. 3, 311 (1972)

    Google Scholar 

  6. Suchdeo, S. R. and Schultz, J. S.: Chem. Eng. Sci. 29, 13 (1974)

    Article  CAS  Google Scholar 

  7. Donaldson, T. L. and Quinn, J. A.: Chem. Eng. Sci. 30, 103 (1975)

    Article  CAS  Google Scholar 

  8. Lee, K. H., Evans, D. F., and Cussler, E. L.:AIChE J. 24, 860 (1978)

    Article  CAS  Google Scholar 

  9. Takahashi, K. and Takeuchi, H.: J. Chem. Eng. Jpn. 18, 205 (1985)

    Article  CAS  Google Scholar 

  10. Harada, M., Yamazaki, F., Adachi, M., and Eguchi, W.: J. Chem. Eng. Jpn. 17, 527 (1984)

    Article  CAS  Google Scholar 

  11. Caracciolo, F., Cussler, E. L., and Evans, D. F.: AIChE J. 21, 160 (1975)

    Article  CAS  Google Scholar 

  12. Danesi, P. D.: Sep. Sci. Tech. 19, 857 (1984–1985)

    Google Scholar 

  13. Ishikawa, H., Murakami, T., Hata, M., and Hikita, H.: Chem. Eng. Sci. 34, 123 (1985)

    CAS  Google Scholar 

  14. Khon, P. M. : Chem. Eng. 83, 58 (March 15, 1976)

    Google Scholar 

  15. Helsel, R. W.: Chem. Eng. Prog. 73, 55 (May 1977)

    CAS  Google Scholar 

  16. Levy, P. F., Sanderson, J. E., Kispert, R. G., and Wise, D. L.: Enzyme Microb. Tech. 3, 207 (1981)

    Article  CAS  Google Scholar 

  17. Levy, P. F., Sanderson, J. E., and Wise, D. L.: Biotechnol., Bioeng. Symp. 11, 239 (1981)

    CAS  Google Scholar 

  18. Busche, R. M., Shimshick, E. J., and Yates, R. A.: Biotechnol. Bioeng. Symp. 12, 249 (1982)

    CAS  Google Scholar 

  19. Kertest, A. S. and King, C. J.: Biotech. Bioeng. 28, 269 (1986)

    Article  Google Scholar 

  20. Wardell, J. M. and King, J. C.: J. of Chem. and Eng. Data 23, 144 (1978)

    Article  CAS  Google Scholar 

  21. Lang, E. and Lang, H.: Z. Anal. Chem. 20, 8 (1972)

    Article  Google Scholar 

  22. Sleat, R. and Mah, R. A.: Appl. Environ. Microbiol. 47, 884 (1984)

    CAS  Google Scholar 

  23. Nishio, N., Kitaura, S. and Nagai, S.: J. Ferment. Technol. 60, 423 (1982)

    CAS  Google Scholar 

  24. Lehninger, A. L. : Principles of Biochemistry, Worth Publishers, Inc., New York 1982

    Google Scholar 

  25. Noble, R. D., Sep. Sci. Technol. 20, 577 (1985)

    Article  CAS  Google Scholar 

  26. Goddard, J. D., Schultz, J. S. and Bassett, R. J.: Chem. Eng. Sci. 25, 665 (1970)

    Article  CAS  Google Scholar 

  27. Goddard, J. D., Schultz, J. S. and Sucheo, S. R.: AIChE J. 20, 625 (1974)

    Article  CAS  Google Scholar 

  28. Joshi S. V., Astarita, A. and Savage, D. W.: AIChE Symp. Ser. 202, 63 (1981)

    Google Scholar 

  29. Hoofd, L., and Kreuzer, F.: AIChE Symp. Ser. 202, 123 (1981)

    Google Scholar 

  30. Carnahan, B., Luther, H. A. and Wilkes, J. O.: Applied Numerical Methods, John Wiley & Sons, New York 1969

    Google Scholar 

  31. Cherchhouse, R. F.: in: Handbook of Applicable Mathematics, ( Laderman W., ed.), John Wiley & Sons, New York 1981

    Google Scholar 

  32. Folkner, C. A. and Noble, R. D.: J. Membrane Sci. 12, 289 (1983)

    Article  CAS  Google Scholar 

  33. Schmidt, R.: Adv. in Nonlinear Parameter Optimization, Springer-Verlag, Berlin 1980

    Google Scholar 

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© 1989 Springer-Verlag Berlin Heidelberg

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Yano, T., Nuchnoi, P., Nishio, N., Nagai, S. (1989). Extraction of Volatile Fatty Acids from Spent Medium with a Supported Liquid Membrane. In: Fiechter, A., Okada, H., Tanner, R.D. (eds) Bioproducts and Bioprocesses. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-74227-9_26

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  • DOI: https://doi.org/10.1007/978-3-642-74227-9_26

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-74229-3

  • Online ISBN: 978-3-642-74227-9

  • eBook Packages: Springer Book Archive

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