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ESR Spectroscopy of Short-Lived Radical Pairs in Solutions

  • Yu. N. Molin
Conference paper

Abstract

Short-lived radical pairs are, presently, the subject of permanent scientific attention caused by both the radical pair chemical transformation proper, and their specific role in the appearance of such phenomena as the chemically-induced polarization of electrons and nuclei, the effect of external magnetic field and the resonance microwave (mw) fields on radical reaction, magnetic isotopic effect (see e.g. (1)). Unfortunately, the ISR spectra of radical pairs in solutions cannot be detected by means of a conventional ESR technique due to their low stationary concentration. The present review is concerned with more sensitive methods based on the radical pair spin state modulation, and, hence, its reaction under the action of the resonance mw radiation, and the intrinsic interactions of the magnetic nature in pair radicals. In the broad sense, they may be referred to the methods based on the reaction yield detected magnetic resonance (2).

Keywords

Chem Phys Radical Pair Nuclear Polarization Quantum Beat Pair Partner 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

References

  1. 1.
    Salikhov KM, Molin YN, Sagdeev RZ, Buchachenko AL (1984) Spin polarization and magnetic effects in radical reactions. Elsevier, Amsterdam Oxford New York TokyoGoogle Scholar
  2. 2.
    Frankevich EL, Kubarev SI (1981) In: Clarke (ed) Triplet state OD MR speetroscopy. John Willey and SonsGoogle Scholar
  3. 3.
    Anisimov OA, Grigoryants VM, Molchanov YK, Molin YN (1979) Chem Phys Lett 66:265CrossRefGoogle Scholar
  4. 4.
    Molin YN, Anisimov OA (1983) Rad Phys Chem 21:77Google Scholar
  5. 5.
    Trifunac AD, Smith JP (1980) Chem Phys Lett 73:94CrossRefGoogle Scholar
  6. 6.
    Melekhov VI, Anisimov OA, Yeselov AY, Molin YN (1986) Chem Phys Lett 127:97CrossRefGoogle Scholar
  7. 7.
    Werst DW, Trifunac AD (1988) J Phys Chem (in press)Google Scholar
  8. 8.
    Saik YO, Anisimov OA, Lozovoy YY, Molin YN (1985) Z Neturforsh 40a:239Google Scholar
  9. 9.
    Okazaki M, Shiga T (1986) Nature 323:240CrossRefGoogle Scholar
  10. 10.
    Bagryanskaya EG, Grishin YA, Avdievitch NI, Sagdeev RZ, Molin YN (1986) Chem Phys Lett 128:162CrossRefGoogle Scholar
  11. 11.
    Bagryanskaya EG, Grishin YA, Sagdeev RZ, Molin YN (1985) Chem Phys Lett 114:138CrossRefGoogle Scholar
  12. 12.
    Anisimov OA, Bizyaev YL, Lukzen NN, Grigoryantz YM, Molin YN (1983) Chem Phys Lett 101:131CrossRefGoogle Scholar
  13. 13.
    Yeselov AY, Melekhov VI, Anisimov OA, Molin YN (1987) Chem Phys Lett 136:263CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 1988

Authors and Affiliations

  • Yu. N. Molin
    • 1
  1. 1.Institute of Chemical Kinetics and CombustionNovosibirskUSSR

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