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The Structure of Surfaces II pp 231–237Cite as

Surface Structures Determined by Kinetic Processes: Adsorption and Diffusion of Oxygen on Pd(100)

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Part of the book series: Springer Series in ((SSSUR,volume 11))

Abstract

Atomic oxygen forms a metastable c(2×2) phase on Pd(100) under conditions of rapid adsorption (high pressure) and slow diffusion (low sample temperature). One possible explanation is that oxygen molecules require an 8-fold ensemble of empty sites for dissociative chemisorption, and that subsequent adatom motion is limited and creates no neighboring pairs of filled sites. We describe the properties of the adlayer predicted by such a model.

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Author information

Authors and Affiliations

  1. Department of Chemistry and Ames Laboratory, Iowa State University, Ames, IA 50011, USA

    S.-L. Chang, D. E. Sanders, J. W. Evans & P. A. Thiel

Authors
  1. S.-L. Chang
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  2. D. E. Sanders
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  3. J. W. Evans
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  4. P. A. Thiel
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Editor information

Editors and Affiliations

  1. FOM-Institute for Atomic and Molecular Physics, Kruislaan 407, NL-1098 SJ, Amsterdam, The Netherlands

    Johannes Friso van der Veen

  2. Materials and Chemical Sciences Division, Lawrence Berkeley Laboratory, Berkeley, CA, 94720, USA

    Michel A. Van Hove

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© 1988 Springer-Verlag Berlin Heidelberg

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Chang, SL., Sanders, D.E., Evans, J.W., Thiel, P.A. (1988). Surface Structures Determined by Kinetic Processes: Adsorption and Diffusion of Oxygen on Pd(100). In: van der Veen, J.F., Van Hove, M.A. (eds) The Structure of Surfaces II. Springer Series in Surface Sciences , vol 11. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-73343-7_38

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  • DOI: https://doi.org/10.1007/978-3-642-73343-7_38

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-73345-1

  • Online ISBN: 978-3-642-73343-7

  • eBook Packages: Springer Book Archive

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