Raman Spectroscopic Investigations Concerning the Solvation Behaviour of Aluminium Chloride in Mixed Solvents
The solvation behaviour of the Al3+ cation in mixed solvents (water - aprotic solvent) was investigated by means of Raman and 27 Al-NMR spectroseopy. It will be expected a number of resolvation processes, because the organic solvents HMPT (DN = 38,8) and DMF (DN = 26,6) are able to Substitute water molecules bonded in aquo eomplexes of Al3+ cations.
KeywordsBand Shape High Frequency Side Solvation Behaviour Glassy Solid Aquo Complex
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