Abstract
Three low stoichiometry (H2O)m(SO2)n or m:n complexes have been prepared by codeposition of H20 and S02 with excess or argon or nitrogen. Concentration effect identified the 1:1, 1:2 and 2:1 species; isotopic substitution in both submolecules provided assignments to the internal modes of each partner,wtiich allowed to precise the nature of the interactions within these aggregates.
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© 1987 Springer-Verlag Berlin Heidelberg
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Schriver, A., Schriver, L., Perchard, J.P. (1987). Matrix Isolation Spectroscopy of Low Stoichiometry Complexes Between Water and Sulfur Dioxide. In: Kleeberg, H. (eds) Interactions of Water in Ionic and Nonionic Hydrates. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-72701-6_46
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DOI: https://doi.org/10.1007/978-3-642-72701-6_46
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-540-17846-0
Online ISBN: 978-3-642-72701-6
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