Abstract
The polarized luminescence of single crystal [Pt (CN)2 bipy] is reported. On raising the temperature from 1.9 K to 7 K or increasing the magnetic field from 0 to 1 T the Ela-polarized emission band (E: electric field vector, a: crystallographic a axis) is blue shifted by -175 cm-1. A temperature increase to 295 K or a magnetic field increase to 6 T reduces the emission lifetime by a factor of ~103 and ~102, respectively.
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Textor, M., Oswald, H. R., Röntgenographische und spektroskopische Untersuchungen an zwei Modifikationen von Dichloro-2,2’-dipyridyl- platin(II). Z. anorg. allg. Chem. 407, 244 (1974).
Biedermann, J., Wallfahrer, M., Gliemann, G., Magnetic-field and temperature effects on the optical properties of dicyano-2,2’- bipyridyl-platinum(II) single crystals. J. of Luminescence (1987) in press.
Bielli, E., Gidney, P.M., Gillard, R.D., Heaton, B.T., Spectroscopic studies on some compounds (including dimorphic solids) of platinum(II) with 2,2’-bipyridyl and its analogeous. J. C. S. Dalton 4, 2133 (1974).
Hidvegi, I., Ammon, W. v., Gliemann, G., Magnetic field effects on the luminescence of quasi-one-dimensional crystals Mx[Pt(CN)4] · yH2O. J. Chem. Phys. 76, 4361 (1982)
Ammon, W. v., Hidvegi, I., Gliemann, G., Magnetic field effects on the luminescence of Ln2 [Pt (CN)4] 3 · yH2O single crystals. J. Chem. Phys. 80, 2837 (1984).
Gliemann, G., Yersin, H., Spectroscopic properties of the quasi one-dimensional tetracyanoplatinate(II) compounds. Structure and Bonding 62, 87 (1985).
Gliemann, G., Magnetic field effects on the luminescence of transition metal complexes. Comments Inorg. Chem. 5, 263 (1986).
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© 1987 Springer-Verlag Berlin · Heidelberg
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Biedermann, J., Wallfahrer, M., Gliemann, G. (1987). Polarized Luminescence of (Pt(CN)2bipy) Single Crystals-Magnetic Field and Temperature Effects. In: Yersin, H., Vogler, A. (eds) Photochemistry and Photophysics of Coordination Compounds. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-72666-8_1
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DOI: https://doi.org/10.1007/978-3-642-72666-8_1
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