Physical Data for, and Theoretical Analysis of, Polyquinanes

  • Leo A. Paquette
  • Annette M. Doherty
Part of the Reactivity and Structure Concepts in Organic Chemistry book series (REACTIVITY, volume 26)

Abstract

The two 3,7-disubstituted diquinanes 510 and 511 have been investigated by single crystal X-ray diffraction techniques and shown to possess the illustrated W conformation [224]. Nonbonded H----H distances of 1.754(4) and 1.713(3) Å have been measured by low-temperature neutron diffraction experiments for 512 and 513 [225]. At 2.921(4) Å, the distance between the pairs of double bonds in 514 is also quite short [226].

Keywords

Enthalpy Benzene Hydrocarbon Adduct Coherence 

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Copyright information

© Springer-Verlag Berlin Heidelberg 1987

Authors and Affiliations

  • Leo A. Paquette
    • 1
  • Annette M. Doherty
    • 1
  1. 1.Evans Chemical LaboratoriesThe Ohio State UniversityColumbusUSA

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