Advertisement

Physical Data for, and Theoretical Analysis of, Polyquinanes

  • Leo A. Paquette
  • Annette M. Doherty
Part of the Reactivity and Structure Concepts in Organic Chemistry book series (REACTIVITY, volume 26)

Abstract

The two 3,7-disubstituted diquinanes 510 and 511 have been investigated by single crystal X-ray diffraction techniques and shown to possess the illustrated W conformation [224]. Nonbonded H----H distances of 1.754(4) and 1.713(3) Å have been measured by low-temperature neutron diffraction experiments for 512 and 513 [225]. At 2.921(4) Å, the distance between the pairs of double bonds in 514 is also quite short [226].

Keywords

Crystal Structure Data Force Field Calculation Empirical Force Field Central Double Bond Double Quantum Coherence 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Copyright information

© Springer-Verlag Berlin Heidelberg 1987

Authors and Affiliations

  • Leo A. Paquette
    • 1
  • Annette M. Doherty
    • 1
  1. 1.Evans Chemical LaboratoriesThe Ohio State UniversityColumbusUSA

Personalised recommendations