The Free Rotor, NH3, in Metal Hexammine Ions
The low-energy INS spectrum of Co(NH3)6(PF6)2 shows clear evidence of almost free rotation of the NH3 groups. A slightly moairied V6, hindrance potential is shown to fit the observed data reasonably well.
KeywordsBarrier Height Free Rotation Rotational Level Inelastic Neutron Scatter Tunnel Splitting
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