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The Response Mechanism of Copper Ion-Selective Electrodes in the Presence of Halides and Organic Ligands

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Book cover Ion Measurements in Physiology and Medicine

Abstract

The problem of so-called erratic behavior of ion-selective electrodes is theoretically one of the most attractive and practically one of the most important in the field of ion-selective electrodes. When this happens the question arises: what is the source of error? Should the theory of the electrode be revised or the analytical procedure changed? The response of Cu2+-selective electrodes in the presence of halides (chlorides, bromides) and some organic ligands: polyamines (DIEN, TRIEN, TETREN), polyaminopolycarboxylic acids (EDTA, DTP A, TTHA), monoamino-polycarboxylic acids (IDA, NTA) and aminoacetic acid (glycine) is discussed below to illustrate the general problem of erratic behavior of ion-selective electrodes.

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References

  1. Ghali E, Dandapani B, Lewenstam A (1982) Electrodissolution of synthetic covellite in hydrochloric acid. J Appl Electrochem 12: 369–376

    Article  CAS  Google Scholar 

  2. Gulens J (1980) Surface effect in relation to the response of solid-state ion-selective electrodes. Ion-Selective Electrode Review 2:117–159

    CAS  Google Scholar 

  3. Hulanicki A, Lewenstam A (1976) Diffusion-layer model for copper solid-state chalcocite membrane electrode; sensitivity to copper (II) ions. Talanta 23: 661–665

    Article  PubMed  CAS  Google Scholar 

  4. Hulanicki A, Trojanowicz M, Cichy M (1976) The chalcocite copper membrane electrode. Talanta 23: 47–50

    Article  PubMed  CAS  Google Scholar 

  5. Hulanicki A, Krawczynski T, Lewenstam A (1983) Effect of some chelating ligands on the potential response of copper ion-selective (chalcocite) electrode. Anal Chim Acta (in press)

    Google Scholar 

  6. Westall JC, Morel FMM, Hume DN (1979) Chloride interference in cupric ion-selective electrode measurements. Anal Chem 51:1792–1798

    Article  CAS  Google Scholar 

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Authors
  1. A. Lewenstam
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Editors and Affiliations

  1. Institut för Physiologie und Kardiologie, Waldstr. 6, D-8520, Erlangen, Germany

    Manfred Kessler , David Keith Harrison  & Jens Höper ,  & 

  2. Dept. of Chemistry, University of North Carolina, Chapel Hill, NC, 27514, USA

    R. P. Buck

  3. Dept. of Physiology, School of Medicine, The Center for Health Science, University of California, Los Angeles, California, 90024, USA

    G. Eisenman

  4. Biosensors Inc., PO Box 640, Chester, New Jersey, 07930, USA

    J. Hill

  5. Faculty of Medicine, American Univ. of Beirut, Beirut, Lebanon

    R. N. Khuri

  6. Direktor des Max-Planck-Instituts für Systemphysiologie, Rheinlanddamm 201, 4600, Dortmund 1, Germany

    D. W. Lübbers

  7. Medical Center, Dept. of Physiology and Biophysics, New York University, 550 First Avenue, New York, NY, 10016, USA

    C. Nicholson

  8. Laboratorium für Organische Chemie, Universitätsstr. 16, 6000, Frankfurt M. 70, Germany

    W. Simon

  9. The Middlesex Hospital, Mortimer St., London W N, 8AA, England

    T. Treasure

  10. Institute of Medical Physiology, Dept. A, University of Copenhagen, DK-2200, Copenhagen N, Denmark

    T. Zeuthen

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© 1985 Springer-Verlag Berlin Heidelberg

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Lewenstam, A. (1985). The Response Mechanism of Copper Ion-Selective Electrodes in the Presence of Halides and Organic Ligands. In: Kessler, M., et al. Ion Measurements in Physiology and Medicine. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-70518-2_5

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  • DOI: https://doi.org/10.1007/978-3-642-70518-2_5

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-15468-6

  • Online ISBN: 978-3-642-70518-2

  • eBook Packages: Springer Book Archive

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