Abstract
The carbon isotopic composition of natural graphites from rocks belonging to different facies of metamorphism and in magmatic rocks provides evidence for their formation from sedimentary organic matter (mostly of plant origin). In these rocks subjected to regional and contact metamorphism, a preferential mobilization of the light carbon fraction of organic matter may occur, as a result of which the residual organic substance or graphite is enriched in heavy carbon (13C). Besides, during metamorphism of organic matter in carbonate rocks, an enrichment in13C in the organic substance (or graphite) usually takes place due to 13C/12C exchange with the host rock. The principal reason for the consistent slant of δ13C values of graphites in a positive direction seems to be a repetitive (multiple) removal of carbon in the form of isotopically light carbon dioxide during progressive degradation of fossil plant matter contained in the rock.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Dobner A, Graf W, Hahn-Weinheimer P, Hirner A (1978) Stable carbon isotopes of graphite from Bogala Mine, Sri Lanka. Lithos 11: 251–255
Eichmann R, Schidlowski M (1974) Isotopic composition of carbonaceous matter from the Pre- cambrian uranium deposits of the Blind River district, Canada. Naturwissenschaften 61: 449
Florensov NA (1947) Geological assay of the Botogolskoye graphite deposit in eastern Sayans. In: Botogolskoye graphite deposit and perspectives of its application, Irkutsk Publ House Ogiz, pp 88–164 (in Russian)
Gavelin S (1957) Variations in isotopic composition of carbon from metamorphic rocks in northern Sweden and their geological significance. Geochim Cosmochim Acta 12: 297–314
Hoefs J, Schidlowski M (1967) Carbon isotope composition of carbonaceous matter from the Precambrian of the Witwatersrand system. Science (Wash DC) 155: 1096–1097
Hoefs J, Frey M (1976) The isotopic composition of carbonaceous matter in a metamorphic profile from the Swiss Alps. Geochim Cosmochim Acta 40: 945–951
Konnikov AF (1975) On the isotopic composition of carbonate and graphite carbons in deep metamorphized carbonate rocks of eastern Sayan. Doklady AN SSSR 224, No 5, pp 1177–1184 (in Russian)
Korzhinsky AF, Mamchur GP (1978) Isotopic composition of graphite and carbon in the Archean carbonate of the Ukrainian Shield as an indicator of graphite formation conditions (in Russian). Zapiski Vsesoyuzn mineral obshchestva (transactions of the all-union mineral society) 1978, part 107, issue 4, pp 442–448 (in Russian)
Kropotova OJ, Milovskiy AJ, Chekh F (1976) Isotopic composition of carbon in some graphites. Vestnik of Moscow University N2, pp 66–71 (in Russian)
Lobzova RV, Vinogradov VI, Lebedey VS (1971) On the genesis of the Botogol’skoye graphite deposit based on carbon isotopic composition data. Geol Rudn Mestor 4: 50–56 (in Russian)
Lobzova RV, Mamchur GP, Shabo EV (1980) On the origin of the Dzhimarinskoye graphite deposit. Abstracts of papers. 7th all-union symp on stable isotopes geochemistry, 1980. Moscow, pp 323–324 (in Russian)
Maslyankevich YV (1966) Certain petrological aspects of the problem of abiogenic carbon dioxide. In: “The problems of origin of oil and gas and the formation of their commercial deposits”. Naukova Dumka, Kiev, pp 137–143 (in Russian)
Oehler DZ, Schopf JW, Kvenvolden KA (1972) Carbon isotopic studies of organic matter in Precambrian rocks. Science (Wash DC) 175: 1246–1248
Sobolev VS (1947) Petrography of the alkaline massif of the Botogolskoye deposit. In: Botogolskoye graphite deposit and perspectives of its application, Irkutsk Publ House Ogiz, pp 165–218 (in Russian)
Sobolev VS, Florensov NA (1948) Genesis of Botogolskoye graphite deposit. Sov Geologiya 32: 29–35 (in Russian)
Solonenko VP (1950) Genesis of alkaline rocks and graphite of the Botogolskoye deposit. Izv AN SSSR series geol 6: 108–118 (in Russian)
Valley JW, O’Neil JR (1981) ’ 3C/’ 2C exchange between calcite and graphite: a possible thermometer in Grenville marbles. Geochim Cosmochim Acta 45:411–419
Wada H, Oana S (1975) Carbon and oxygen isotope studies of graphite bearing carbonates in the Kasuga area, Gifu Prefecture, central Japan. Geochem J 9: 149–160
Yakhontova PP (1926) Graphite. In: Ginzburg JJ et al. (eds) “Non-metallic minerals”. PS Publ House KEPS 6: 317–338 (in Russian)
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1984 Springer-Verlag Berlin Heidelberg
About this paper
Cite this paper
Chukhrov, F.V., Ermilova, L.P., Nosik, L.P. (1984). On the Isotopic Composition of Carbon in Epigenetic Graphites. In: Wauschkuhn, A., Kluth, C., Zimmermann, R.A. (eds) Syngenesis and Epigenesis in the Formation of Mineral Deposits . Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-70074-3_12
Download citation
DOI: https://doi.org/10.1007/978-3-642-70074-3_12
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-70076-7
Online ISBN: 978-3-642-70074-3
eBook Packages: Springer Book Archive