Methanol as Raw Material

  • Gisela Henrici-Olivé
  • Salvador Olivé

Abstract

Methanol is synthesized from CO and H2 in large quantities at low price and with a high degree of purity (Danner, 1970; see also Sect. 8.4). This is the reason for the large amount of work towards syntheses starting with methanol, and aiming at the same or similar compounds obtainable from the direct hydrogenation of CO. In this Chapter, the most important of these methanol based processes will be discussed.

Keywords

Cobalt Pyridine Carbonylation Iodide Dehydration 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Braca G, Sbrana G, Valentini G, Andrich G, Gregorio G (1979) in: Tsutsui M (ed) Fundamental Research in Homogeneous Catalysis. Plenum Press, New York, Vol. 3, p. 221Google Scholar
  2. Braca G, Sbrana G, Valentini G, Cini M (1982) J Mol Catal 17:323CrossRefGoogle Scholar
  3. Burns GR (1955) J Amer Chem Soc 77:6615CrossRefGoogle Scholar
  4. Chang CD, Chu CTW (1982) J Catal 74:203CrossRefGoogle Scholar
  5. Chang CD, Chu CTW (1983) J Catal 79:244CrossRefGoogle Scholar
  6. Chang CD, Silvestri AJ (1977) J Catal 47:249CrossRefGoogle Scholar
  7. Chen MJ, Feder HM, Rathke JW (1982) J Mol Catal 17:331CrossRefGoogle Scholar
  8. Christensen BC, Scurrell MS (1977) J Chem Soc Faraday Trans 2036Google Scholar
  9. Danner CA (ed) (1970) Methanol Technology and Economics. Chem Eng Progr Symp Ser No 98:66Google Scholar
  10. Doyle G (1983) J Mol Catal 18:251 (and references therein)CrossRefGoogle Scholar
  11. DRP (1941) 867,849 (to BASF)Google Scholar
  12. Fârcaliu D (1983) J Catal 82:252CrossRefGoogle Scholar
  13. Forster D (1975) J Amer Chem Soc 97:951CrossRefGoogle Scholar
  14. Forster D (1976) J Amer Chem Soc 98:846CrossRefGoogle Scholar
  15. Forster D, Singleton TC (1982) J Mol Catal 17:299 (and references therein)CrossRefGoogle Scholar
  16. Fujimoto K, Shikada T, Ornata K, Tominaga K (1982) Ind Eng Chem Prod Res Dev 21:429CrossRefGoogle Scholar
  17. Fujimoto K, Ornata K, Shikada T, Tominaga H (1983) Ind Eng Chem Prod Res Dev 22:436CrossRefGoogle Scholar
  18. Gauthier-Lafaye J, Perron R, Colleuille Y (1982) J Mol Catal 17:339CrossRefGoogle Scholar
  19. Haggin J (1981) Chem Eng News 59:(20), 52; see also Chem Eng News 60:(13), 28 (1982)Google Scholar
  20. Hecht O, Kröper H (1948) Naturforschung und Medizin in Deutschland (FIAT Rev., German Sci.) 1939–46, Vol 36, Pt I, p 136Google Scholar
  21. Henrici-Olivé G, Olivé S (1977) Coordination and Catalysis. Verlag Chemie, Weinheim, New York, Chap. 10. 2Google Scholar
  22. Hohenschutz H, von Kutepow N, Himmele W (1966) Hydrocarbon Processing 45:141Google Scholar
  23. Inui T, Matsuda H, Takegami Y (1981) J Chem Soc Chem Commun 906Google Scholar
  24. Inui T, Ishihara T, Morinaga N, Takeuchi G, Matsuda H, Takegami Y (1983) Ind Eng Chem Prod Res Dev 22:26CrossRefGoogle Scholar
  25. Itoh H, Hattori T, Murakami Y (1981) J Chem Soc Chem Commun 1091Google Scholar
  26. Kaeding WD, Butter SA (1980) J Catal 61:155CrossRefGoogle Scholar
  27. Kieffer R, Varela J, Deluzarche A (1983) J Chem Soc Chem Commun 763Google Scholar
  28. Kim L, Wald MM, Brandenberger SG (1978) J Org Chem 43:3432CrossRefGoogle Scholar
  29. Lee W, Maziuk J, Thiemann WK (1978) 26 DGMK-Haupttagung, Berlin, Preprints, p 675Google Scholar
  30. Meisel SL, Mc Cullough JP, Lechthaler CH, Weisz PB (1976) CHEMTECH 86Google Scholar
  31. Nefedov BK, Sergeeva NS, Zheva TV, Shutkina EM, Eidus YaT (1976) Izvest Akad Nauk SSSR, Ser Khim 582Google Scholar
  32. Ono Y, Mori T (1981) J Chem Soc Faraday Trans I 77:2209CrossRefGoogle Scholar
  33. Pearson DE (1974) J Chem Soc Chem Commun 397Google Scholar
  34. Perot G, Cormerais FX, Guismet M (1982) J Chem Res (S), 58Google Scholar
  35. Pichler H, Ziesecke KH (1949) Brennstoff-Chem 30:13, 60, 81, 313Google Scholar
  36. Poutsma ML (1976) in Zeolite Chemistry and Catalysis (Rabo JA, ed), ACS Monograph 171:Amer Chem Soc Washington DC, p 437Google Scholar
  37. Roper M, Loevenich H, Korff J (1982) J Mol Catal 17:315CrossRefGoogle Scholar
  38. Roth JF, Craddock JH, Hershman A, Paulik FE (1971) CHEMTECH 600Google Scholar
  39. Slocum DW (1980) in Johns WH (ed) Catalysis in Organic Chemistry, Academic Press, New York, p 245Google Scholar
  40. Thomas JM, Millward GR (1982) J Chem Soc Chem Commun 1380 (and references therein)Google Scholar
  41. van den Berg JP, Wolthuizen JP, van Hooff JHC (1980) in Rees LV (ed) Proc. 5th Internat. Conf. on Zeolites. Heyden, London, p 649Google Scholar
  42. Weisz PB, Frilette VJ, Maatman RW, Mower EB (1962) J Catal 1:307CrossRefGoogle Scholar
  43. Whan DA (1981) Chem & Ind 532Google Scholar
  44. Ziesecke KH (1952) Brennstoff Chem 33:385Google Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 1984

Authors and Affiliations

  • Gisela Henrici-Olivé
    • 1
  • Salvador Olivé
    • 1
  1. 1.Department of ChemistryUniversity of California, San DiegoLa JollaUSA

Personalised recommendations