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The Intramolecular Diels-Alder Reaction: Variations and Scope

Chapter
Part of the Reactivity and Structure Concepts in Organic Chemistry book series (REACTIVITY, volume 18)

Abstract

The Diels-Alder reaction has long been a useful tool in organic synthesis. Although the concept of covalently linking the diene and the dienophile was originated by Alder (1), it has only been in the last ten years that the intramolecular Diels-Alder reaction has been widely used. Partly this has been because efficient routes to the requisite trienes have only recently been available, and partly it has been because there has not been enough data in the literature to allow one to predict with confidence the stereochemical outcome of a prospective cyclization.

Keywords

Alder Reaction Aldol Condensation Unsaturated Ester Acetylenic Ester Stereochemical Outcome 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer-Verlag Berlin Heidelberg 1984

Authors and Affiliations

  1. 1.Department of ChemistryUniversity of DelawareNewarkUSA

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