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Miscellaneous Reductions

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Silicon Reagents for Organic Synthesis

Part of the book series: Reactivity and Structure Concepts in Organic Chemistry ((REACTIVITY,volume 14))

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Abstract

In addition to ionic hydrogenations, dissolving metal reductions and hydrosilation reactions which we have previously considered, there are a number of reduction reactions which utilize organosilicon reagents. These have been divided into seven sections: 1) tin hydride mediated reductions, 2) reductions which utilize silyl radicals, 3) reductions with trichlorosilane (Cl3SiH)/tertiary amines, 4) reductions of phosphine oxides, 5) reductions of sulfoxides, 6) reductions of amine oxides, and 7) reductions of α-halo ketones. The organizing principle of the first three sections is the combination of reagents used or the reactive intermediates involved. The latter four sections are concerned with reductions of specific functional groups.

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  1. Department of Chemistry, University of Southern California, 90007, University Park, Los Angeles, CA, USA

    William P. Weber

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© 1983 Springer-Verlag Berlin Heidelberg

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Weber, W.P. (1983). Miscellaneous Reductions. In: Silicon Reagents for Organic Synthesis. Reactivity and Structure Concepts in Organic Chemistry, vol 14. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-68661-0_20

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  • DOI: https://doi.org/10.1007/978-3-642-68661-0_20

  • Publisher Name: Springer, Berlin, Heidelberg

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