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Chemical Equilibria of Sulfides as Studied with a Hydrogen Sulfide Sensor

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Proceedings of Symposium on Paddy Soils
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Abstract

Owing to its theoretical and practical significance, the subject of sulfides in paddy soils has attracted much attention to many soil scientists(l,2) For the determination of sulfides in soils, chemical methods are generally used. But with these methods it is unavoidable to disturb the chemical equilibria originally existing in the soil during extraction and the subsequent determination, and it is also not possible to distinguish the molecular hydrogen sulfide from the ionic HS and S. In recent years there have appeared two papers pertaining to the study of sulfide in submerged soils with a sulfide-selective electrode(3,4). But it is necessary to make some assumptions in converting the measured sulfide ion into hydrogen sulfide, and thus the obtained results are still indirect.

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References

  1. Yu Tian-ren, Liu Zhi-guang, Oxidation-reduction processes in paddy soils and their relationship with the growth of rice plant. Acta Pedologica Sinica., 12,380–389 (1964). (in Chinese with English summary)

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  2. Mitsui, S., Inoganic Nutrition, Fertilization and Soil Amelioration for Lowland Rice. Yokendo, Tokyo (1954).

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  3. Allam, A. I., Sulfide determination in submerged soils with an ionselective electrode. Soil Sci., 114, 456–467 (1972).

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  4. Ayotade, K. A., Kinetics and reactions of hydrogen sulfide in solution of flooded rice soil. Plant & Soil, 46, 381–389 (1977).

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  5. Ross, J. W., Raseman, J. H., Krueger, J. A., Potentiometric gas sensing electrodes. Pure Appl. Chem., 36, 473–489 (1973).

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© 1981 Science Press, Beijing and Springer-Verlag Berlin Heidelberg

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Shu-zhen, P. (1981). Chemical Equilibria of Sulfides as Studied with a Hydrogen Sulfide Sensor. In: Proceedings of Symposium on Paddy Soils. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-68141-7_19

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  • DOI: https://doi.org/10.1007/978-3-642-68141-7_19

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-68143-1

  • Online ISBN: 978-3-642-68141-7

  • eBook Packages: Springer Book Archive

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