Abstract
Most of the cholesteric mesophases formed by esters of cholesterol exhibit selective reflection of circularly polarized light in the u. v. region at temperatures close below the clearing point /1/. The well known reflection colours in the visible either occur near phase transitions to the smectic phase or in so-called compensated mixtures /1/. However, cooling down cholesteric esters only a few tenths of a Kelvin below the clearing point bright colours appear (mostly blue colours) which disappear on further cooling /2/. As early as in 1906 Lehmann /3/ noted that these colours belong to an optically isotropic modification. In his opinion this modification represents a stable phase distinct from that of the ordinary cholesteric one.
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Stegemeyer, H., Bergmann, K. (1980). Experimental Results and Problems Concerning “Blue Phases”. In: Helfrich, W., Heppke, G. (eds) Liquid Crystals of One- and Two-Dimensional Order. Springer Series in Chemical Physics, vol 11. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-67848-6_38
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