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Rare-Earth Germanates

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Organic Crystals, Germanates, Semiconductors

Part of the book series: Crystals ((CRYSTALS,volume 4))

Abstract

The intense rise of contemporary science and technology has engendered the development and investigation of different materials possessing valuable physical properties. Of special interest are the rare-earth compounds, chiefly because of the possibility of utilizing them in diverse areas of modem engineering (for example: quantum generators, optical converters, scintillators, luminophores, etc.)1–7). However, only the oxides and fluorides have been thoroughly studied in practice. To date, most acute is the problem of producing and investigating other rare-earth compounds, particularly those of silicates and germinates. In virtue of their specific composition, RE germinates can find broad application in radioelectronics (as laser materials), in luminophore production (luminophores covering the whole optical radiation range, X-ray luminescent screens, thermoluminiscent, dosimeters), in glass-ceramic manufacture (special kinds of glass and ceramics), in the nuclear instrumentation industry (nuclear radiation detectors), and in numerous other capacities.

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References

  1. Toropov, N. A. et al.: Rare-Earth silicates and their analogues, Leningrad, Nauka, 1971, p. 230 (Russ.)

    Google Scholar 

  2. Kaminsky, A. A.: Laser crystals, Moscow: Nauka, 1975, p. 256 (Russ.)

    Google Scholar 

  3. Befov, K. P. et al.: Rare-Earth ferromagnetics and antiferromagnetics. Moscow, Nauka, 1975, p. 320 (Russ.)

    Google Scholar 

  4. Aleksandrova, I. T. et al.: Geology of rare element deposits. Rare-earth silicates, Part 26, Moscow, Nedra, 1966, p. 220 (Russ.)

    Google Scholar 

  5. Progress in the Science and Technology of the Rare-Earths (Ed. Le Roy Eyring) Vol. 1, Oxford-London, 1964

    Google Scholar 

  6. Les Elements des Terres Rares. Colloque Internat. du CNRS (Ed. du CNRS) N 180, Vol. 1, Paris, 1970

    Google Scholar 

  7. Demianets, L. N., Lobachev, A. N., Emelchenko, G. A.: Germanates of Rare-Earth Elements, Moscow: Nauka, 1980

    Google Scholar 

  8. Lobachev, A. N. et al.: Kristal u. Technik 5, 425 (1970)

    Article  CAS  Google Scholar 

  9. Felsche J.: Structure and Bonding 13, 99 (1973)

    CAS  Google Scholar 

  10. Belov, N. V.: Essaies on structural mineralogy, Moscow, Nauka, 1976, p. 344

    Google Scholar 

  11. Buisson, G., Michel C.: Mat. Res. Bull. 3, 193–194 (1968)

    Article  CAS  Google Scholar 

  12. Gorbunov, Yu. A. et al.: Sov. Phys.-Kristallografiya 19, 1081 (1974)

    CAS  Google Scholar 

  13. Cocbain, A. G., Smith, J. V.: Amer. Mineral. 50, 2023 (1965)

    Google Scholar 

  14. Emelchenko, G. A., Ilyukhin, V. V.: Sov. Phys.-Dokl. Akad. Nauk (SSSR) 217, 824 (1974)

    CAS  Google Scholar 

  15. Petrova, M. A.: Physical-chemical study of silicates of rare-earth elements. Theses. Inst. Chemi. Silicates, Acad. Sci. USSR, Leningrad, 1974, p. 20

    Google Scholar 

  16. Merinov, B. A. et al.: Sov. Phys.-Dokl. Akad. Nauk SSSR 241, 353 (1978)

    CAS  Google Scholar 

  17. Smolin, Yu. I., Shepelev, Yu. F., Upatova, T. V.: Sov. Phys.-Dokl. Akad. Nauk SSSR 187, 322 (1969)

    CAS  Google Scholar 

  18. Smolin, Yu. I., Shepelev, Yu. F., Butikova, I. K.: Sov. Phys.-Kirstallograflya 16, 911 (1971)

    CAS  Google Scholar 

  19. Smolin, Yu. I.: ibid.Sov. Phys.-Kirstallograflya 15, 47 (1970)

    Google Scholar 

  20. Shannon, R. D., Prewitt, C. T.: J. Solid State Chem. 2, 199 (1970)

    Article  CAS  Google Scholar 

  21. Nikolsky, Yu. V. et al.: Sov. Phys: Dokl. Akad. Nauk SSSR 233, 362 (1977)

    Google Scholar 

  22. Kharakh, E. A., Chichagov, A. V., Belov, N. V.: Sov. Phys.-Kristallografiya 15, 1064 (1970)

    CAS  Google Scholar 

  23. Chichagov, A. V. et al.: Dokl. Akad. Nauk SSSR 189, 88 (1969)

    CAS  Google Scholar 

  24. Emelchenko, G. A. et al.: Sov. Phys.-Dokl. Akad. SSSR 222, 343 (1975)

    CAS  Google Scholar 

  25. Kornev, A. N. et al.: Sov. Phys.-Dokl. Akad. Nauk SSSR 206, 1109 (1972)

    CAS  Google Scholar 

  26. Zhdanova, T. A. et al.: Sov. Phys.-Dokl. Akad. Nauk SSSR 224, 1069 (1975)

    CAS  Google Scholar 

  27. Christensen, A. N.: Acta Chem. Scand. 24, 1055 (1972)

    Google Scholar 

  28. Gorbunov, Yu. A., Maksimov, B. A., Belov, N. V.: Sov. Phys-Dokl. Akad. Nauk SSSR 208, 91 (1973)

    CAS  Google Scholar 

  29. Gorbunov, Yu. A., Maksimov, B. A., Belov, N. V.: ibid.Sov. Phys-Dokl. Akad. Nauk SSSR 211, 591 (1973)

    Google Scholar 

  30. Gorbunov, Yu. A. et al.: ibid.Sov. Phys-Dokl. Akad. Nauk SSSR 219, 91 (1974)

    Google Scholar 

  31. Klientova, G. A. et al.: Sov. Phys.-Dokl. Akad. Nauk SSSR 224, 817 (1975)

    Google Scholar 

  32. Nikolsky Yu. V. Maksimov B. A. Belov N. V. ibid.Sov. Phys-Dokl. Akad. Nauk SSSR 222, 87 (1975)

    Google Scholar 

  33. Shannon, R. D. et al.: Inorg. Chem. 17, 958 (1978)

    Article  CAS  Google Scholar 

  34. Mill. B. V.: Sov. Phys.-Dokl. Akad. Nauk SSSR 165, 555 (1965)

    CAS  Google Scholar 

  35. Roy, R.: J. Amer. Ceram. Soc. 37, 581 (1954)

    Article  CAS  Google Scholar 

  36. Lasarev, A. N.: Izv. Akad. Nauk SSSR. Neorgan. Mater. 4, 1287 (1968)

    Google Scholar 

  37. Smolin, Yu. A., Tkachev, S. P.: Sov. Phys.-Kristallografiya 14, 22 (1969)

    CAS  Google Scholar 

  38. Michel, C., Buisson, G., Bertaut, E. F.: Comet. Rend. Acad. Sci., Paris 264B, 397 (1967)

    CAS  Google Scholar 

  39. Bondar, I. A. et al.: High temperature chemistry of silicates and oxides. (Toropov, N. A. ed.) pp. 31–36. Moscow, Nauka, 1972

    Google Scholar 

  40. Belokoneva, E. A. et al.: Sov. Phys.-Kristallografiya 17, 490 (1972)

    CAS  Google Scholar 

  41. Shannon, R. D., Sleight, A. W.: Inorg. Chem. 7, 1949 (1968)

    Article  Google Scholar 

  42. Kornilova, E. I., Prikhod'ko, M. E., Lileev, I. S.: Izv. Akad. Nauk SSSR, Neorgan. Mater. 1, 227 (1965)

    CAS  Google Scholar 

  43. Tenisheva, T. F., Lasarev, A. N., Pavlyukovich, T. M.: Izv. Akad. Nauk SSSR, Ser. khim. 1553 (1965)

    Google Scholar 

  44. Glushkova, V. B., Davtyan, I. A., Keler, E. K.: Izv. Akad. Nauk SSSR 3, 119 (1967)

    CAS  Google Scholar 

  45. Kolesova, V. A.: Izv. Akad. Nauk SSSR, Otdel. khim. nauk N11, 2082 (1962)

    Google Scholar 

  46. Tarte, P.: Nature 191, 1002 (1961)

    Article  CAS  Google Scholar 

  47. Chichagov, A. V., Litvin, B. N., Belov, N. V.: Sov. Phys.-Kristallografiya 14, 119 (1969)

    CAS  Google Scholar 

  48. Chichagov, A. V., Litvin, B. N., Belov, N. V.: Sov. Phys.-Dokl. Akad. Nauk SSSR 177, 574 (1967)

    CAS  Google Scholar 

  49. Blasse, B., Brill, A.: J. Inorg. Nucl. Chem. 29, 2231 (1967)

    Article  CAS  Google Scholar 

  50. Emelchenko G. A. et al.: Phys.-Kirstallografiya 19, 1272 (1974)

    CAS  Google Scholar 

  51. Demianets, L. N., Emelchenko, G. A., Lobachev, A. N.: Zh. Koordin. khimii 1, 1205 (1975)

    Google Scholar 

  52. Demianets, L. N. et al.: Izv. Akad. Nauk SSSR, Neorgan. Mater. 12, 143 (1976)

    Google Scholar 

  53. Maksimov, B. A., Kharitonov, Yu. A., Belov, N. V.: Dokl. Akad. Nauk SSSR 213, 1072 (1973)

    CAS  Google Scholar 

  54. Geller, S.: Z. Krist. 125, 1 (1969)

    Article  Google Scholar 

  55. Mill, B.V., Roniger, G.: Sov. Phys.-Kristallografiya 18, 126 (1973)

    CAS  Google Scholar 

  56. Bauer, G.: Naturwissenschaften 58, 622 (1971)

    Article  Google Scholar 

  57. Struntz, H., Freigang, H., Contag, B.: Neues Jahrb. Mineral. Monatsch. H. 2, 47 (1960)

    Google Scholar 

  58. Schwarz, H.: Angew. Chem. 79, 548 (1967)

    Google Scholar 

  59. Geller, S., Miller, C. E., Treuting, R. G.: Acta Cryst. 13, 179 (1960)

    Article  CAS  Google Scholar 

  60. Geller, S. et al.: J. Phys. Chem. Solids 12, 111 (1960)

    Article  CAS  Google Scholar 

  61. Bondar, I. A., Petrova M. A.: Zh. Neorgan. Khimii 14, 2340 (1969)

    CAS  Google Scholar 

  62. Bondar, I. A., Petrova, M. A., Udalov, Yu. P.: Single crystal growth of refractory and rare metals, pp. 37–42, Moscow, Nauka, 1973

    Google Scholar 

  63. Bondar, A. I.:in: Less elements des terres rares. Colloque Internat. CNRS, Paris N 180, Vol. 1, 337 (1970)

    Google Scholar 

  64. Wanklyn, B. M.: J. Mater. Sci. 8, 649 (1973)

    Article  CAS  Google Scholar 

  65. Wanklyn, B.M.: Rare-earth germanates. Nat. Conf. Crystal Growth, Lancaster University, p. 33 (1970)

    Google Scholar 

  66. Emelchenko, G. A., Demianets, L. N., Lobachev, A. N.: J. Solid State Chem. 14, 209 (1975)

    Article  CAS  Google Scholar 

  67. Chichagov, A. V., Litvin, B. N., Belov, N. V.: Geokhimiya N 9, 1044 (1968)

    Google Scholar 

  68. Emelchenko, G. A. et al.: Sov. Phys-Kristallografiya 19, 436, (1974)

    Google Scholar 

  69. Betova, E. N. et al.:in: Growth of crystals, 12, pp. 87–91, Erevan, EGU 1977

    Google Scholar 

  70. Emelchenko, G. A., Demianets, L. N., Lobachev, A. N.: Mater. Res. Bull. 9, 1151 (1974)

    Article  CAS  Google Scholar 

  71. Demianets, L. N., Emelchenko, G. A., Lobachev, A. N.: High Temperatures — High Pressures 6, 699 (1974)

    Google Scholar 

  72. Emelchenko, G. A.: Izv. Akad. Nauk SSSR, Neorgan. Mater. 12, 494 (1976)

    Google Scholar 

  73. Demianets, L. N., Emelchenko, G. A., Lobachev, A. N., in: Problems of crystallology, pp. 227–234, Moscow, MGU 1976

    Google Scholar 

  74. Kudryavtseva, O. V., Litvin, B. N., in: Problems of crystallology, pp. 171–176, Moscow, MGU 1976

    Google Scholar 

  75. Belova, E. N. et al., in: Mechanism and kynetics of crystal growth. IV Allunion Conf. growth of crystals, Tzakhkadzor, Akad. Nauk Arm. SSR Press, Erevan, Part 2, pp. 228–234, 1972

    Google Scholar 

  76. Fedosova, S. P., Gribina, I. A., Belov, N. V., in: Problems of crystallology, pp. 204–207, Moscow, MGU 1976

    Google Scholar 

  77. Mill, B. V.: Zh. Neorgan. Khimii N7, 1533 (1966)

    Google Scholar 

  78. Emelchenko, G. A. et al., in: Crystal chemistry of inorganic compounds, pp. 195–206, Kishinev, Shtiintsa 1976

    Google Scholar 

  79. Emechenko, G. A., Grechushnikov, B. N., Ilyukhin, V.V., in: Spectroscopy of crystals. pp. 265–269, Moscow, Nauka 1976

    Google Scholar 

  80. Blasse, G., Brill, A.: Philips Res. Rent. 22, 481 (1967)

    CAS  Google Scholar 

  81. El'yashevich, M. A.: Spectra of rare-earths. Moscow, GITTKh, 1953

    Google Scholar 

  82. Wyborne, B. G.: Spectroscopic properties of rare-earths, London, John Wiley and Sons 1965

    Google Scholar 

  83. Stewens, K. W. H.: Proc. Phys. Soc. A 65, 209 (1952)

    Google Scholar 

  84. Polyak, V. G., Skoko, V. A.: Standart program of minimization of the function of many variables, N IV Moscow, MGU 1967, 68 p.

    Google Scholar 

  85. Ikramov, Kh. D.: Standart program of calculation of own values and own vectors of complex matrix by Yakobi method, N44 Moscow, MGU 1971

    Google Scholar 

  86. Braumik, M. L., Nugent, L. J.: J. Chem. Phys. 43, 1680 (1965)

    Article  Google Scholar 

  87. Brill, A. et al.: Internat. Conf. Luminescence, B. 2. 1688, Budapest 1966

    Google Scholar 

  88. Bondar, I. A.: Izv. Akad. Nauk SSSR, Neorgan. Mater. 15, 1008 (1979)

    CAS  Google Scholar 

  89. Emelchenko, G. A. et al.: Thermoluminescence of rare-earth germinates. Abstr. 8. Ural Conf. Spectroscopy, pp. 52–53, Sverdlovsk 1975

    Google Scholar 

  90. Ropp, R. C.: J. Electrochem. Soc. 115, 841 (1968)

    Article  CAS  Google Scholar 

  91. Borchardt, H. J.: Efficiency of Eu3+ fluorescence in oxygen-dominates host lattices. Proc. First Rare-Earth Research Conf. 1, Ames, Iowa, pp. 65–75, 1965

    Google Scholar 

  92. Ropp, R. C. et al.: Electrochem. Technol. 4, 24 (1966)

    CAS  Google Scholar 

  93. Blasse, G., Bril, A.: J. Chem. Phys. 45, 3327 (1966)

    Article  CAS  Google Scholar 

  94. Blasse, G.: J. Chem. Phys. 45, 2356 (1966)

    Article  CAS  Google Scholar 

  95. Bril, A., Wanmaker, W. L.: J. Electrochem. Soc. 111, 1363 (1964)

    Article  CAS  Google Scholar 

  96. Emelchenko, G. A.: Synthesis and study of rare-earth germinate single crystals. Theses on candidate degree, Moscow, Inst. Crystallography Acad. Sci. USSR 1974

    Google Scholar 

  97. Jorgensen, C. K.: Orbital energy difference and chemical bonding in rare-earth, Proc. Fifth Rare-Earth Conf., Ames, Iowa, 1, 1 (1965)

    Google Scholar 

  98. Emelchenko, G. A., Grechushnikov, B. N.: Spectra of diffuse scattering of RE germinates. Abstr. 8 Ural Conf. Spectroscopy pp. 55–56, Sverdlovsk, 1975

    Google Scholar 

  99. Bryant, B. W.: J. Amer. Opt. Soc. 55, 771 (1965)

    Article  CAS  Google Scholar 

  100. Popov, V. V., Petrova, M. A.: Izv. Akad. Nauk SSSR, Neorgan. Mater. 9, 61 (1973)

    CAS  Google Scholar 

  101. Hong H.Y.-P., Kafalas, J. A., Bayard, M.: Mater. Res. Bull. 13, 757 (1978)

    Article  CAS  Google Scholar 

  102. Fournier, J., Kohemuller, R.: Compt. Rend. Sci (Paris) 266, Serie C, 1361 (1968)

    CAS  Google Scholar 

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  1. Institute of Crystallography, Academy of Science of the USSR, Leninsky Prospect 59, USSR - Moscow B, 117333

    Ludmila N. Demianets, Anatoly N. Lobachev & Gennadi A. Emelchenko

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  1. Ludmila N. Demianets
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  2. Anatoly N. Lobachev
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  3. Gennadi A. Emelchenko
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Demianets, L.N., Lobachev, A.N., Emelchenko, G.A. (1980). Rare-Earth Germanates. In: Organic Crystals, Germanates, Semiconductors. Crystals, vol 4. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-67764-9_2

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  • DOI: https://doi.org/10.1007/978-3-642-67764-9_2

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