Abstract
Among the few oscillatory chemical reactions proceeding in solution the BELOUSOV-ZHABOTINSKY [BZ[ reaction has been studied more thoroughly. The BZ reaction is essentially the catalytic oxidation and bromination of a variety of aliphatic compounds — mostly dicar-boxylic acids and diketones — with acid bromate. Detailed investigations revealed that the occurrence of chemical oscillation is due to the existence of two kinetic states in the system, and the transition from one state to the other is controlled by the bromide ion concentration [1]. Extensive experimental investigations disclosed that all components of the BZ system, but bromate, can be substituted. It is a widely accepted view that such types of reactions require a catalyst.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
R.J. Field, E. Kőrös and A Noyes: J. Am.Chem. Soc., 94, 8649 [1972[
L. Kuhnert and E. Linder : Z. Chem., 17, 19 [1917[
E. Kőrös and M. Orbán: Nature, 273, 371 [1978[
M. Orbán and E. Kőrös: J. Phys. Chem., 82, 1672 [1978[
E. Kőrös, M. Burger, Zs. Nagy and M. Orbán: Acta Pharm. Hung., 48, 172 [1978[
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1979 Springer-Verlag Berlin Heidelberg
About this paper
Cite this paper
Orbán, M., Körös, E. (1979). Chemical Oscillations During the Oxidative Bromination of Some Aromatic Compounds with Bromate. In: Pacault, A., Vidal, C. (eds) Synergetics. Springer Series in Synergetics, vol 3. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-67262-0_6
Download citation
DOI: https://doi.org/10.1007/978-3-642-67262-0_6
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-67264-4
Online ISBN: 978-3-642-67262-0
eBook Packages: Springer Book Archive