Synergetics pp 34-42 | Cite as

Mechanisms of Chemical Oscillators

  • R. M. Noyes
Conference paper
Part of the Springer Series in Synergetics book series (SSSYN, volume 3)

Abstract

Chemical oscillators are particularly dramatic examples of the processes possible in systems far from equilibrium. Although two different oscillating systems were reported by MORGAN [1] and by BRAY [2] about sixty years ago, most chemists were unaware such reactions existed. Even those who knew of these articles were skeptical of the alleged facts, and it was often asserted that such processes were forbidden by thermodynamics.

Keywords

Combustion Hydrogen Peroxide Dioxide Manifold Bromide 

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References

  1. 1.
    J.S. Morgan: J. Chem. Soc. 109, 274 (1916)Google Scholar
  2. 2.
    W.C. Bray: J. Am. Chem. Soc. 43, 1262 (1921)CrossRefGoogle Scholar
  3. 3.
    B.P. Belousov: Ref. Radiats. Med. 1958, 145 (1959)Google Scholar
  4. 4.
    A.M. Zhabotinsky: Dokl. Akad. Nauk SSSR 157, 392 (1964)Google Scholar
  5. 4a.
    A.M. Zhabotinsky: Biofizika 9, 306 (1964)Google Scholar
  6. 5.
    P. Glansdorff, I. Prigogine: Thermodynamic Theory of Structure, Stability, and Fluctuations (Wiley-Interscience: New York 1971)MATHGoogle Scholar
  7. 6.
    R.J. Field, E. Körös, R.M. Noyes: J. Am. Chem. Soc. 94, 8649 (1972)CrossRefGoogle Scholar
  8. 7.
    J.-J. Jwo, R.M. Noyes: J. Am. Chem. Soc. 97, 5422 (1975)CrossRefGoogle Scholar
  9. 8.
    S. Barkin, M. Bixon, R.M. Noyes, K. Bar-Eli: Internat. J. Chem. Kinetics 10, 619 (1978)CrossRefGoogle Scholar
  10. 9.
    D. Edelson, R.J. Field, R.M. Noyes: Internat. J. Chem. Kinetics 7, 417 (1975)CrossRefGoogle Scholar
  11. 10.
    D. Edelson, R.M. Noyes, R.J. Field: Internat. J. Chem. Kinetics (in press)Google Scholar
  12. 11.
    K. Showalter, R.M. Noyes, K. Bar-Eli: J. Chem. Phys. (in press)Google Scholar
  13. 12.
    R.J. Field, R.M. Noyes: J. Chem. Phys. 60, 1877 (1974)ADSCrossRefGoogle Scholar
  14. 13.
    S. Barkin, M. Bixon, R.M. Noyes, K. Bar-Eli: Internat. J. Chem. Kinetics 9, 841 (1977)CrossRefGoogle Scholar
  15. 14.
    R.J. Field, R.M. Noyes: Faraday Symposia Chem. Soc. 9, 21 (1974)CrossRefGoogle Scholar
  16. 15.
    R.J. Field, R.M. Noyes: Accounts Chem. Research 10, 214 (1977)CrossRefGoogle Scholar
  17. 16.
    R.M. Noyes, R.J. Field: Accounts Chem. Research 10, 273 (1977)CrossRefGoogle Scholar
  18. 17.
    A.T. Winfree: Faraday Symposia Chem. Soc. 9, 38 (1974)CrossRefGoogle Scholar
  19. 18.
    R.J. Field, R.M. Noyes: J. Am. Chem. Soc. 96, 2001 (1974)CrossRefGoogle Scholar
  20. 19.
    R.J. Field, R.M. Noyes: Nature 237, 390 (1972)ADSCrossRefGoogle Scholar
  21. 20.
    K. Showalter, R.M. Noyes: J. Am. Chem. Soc. 98, 3730 (1976); a detailed manuscript is in preparationCrossRefGoogle Scholar
  22. 21.
    R.J. Field: private communicationGoogle Scholar
  23. 22.
    R.A. Schmitz, K.R. Graziani, J.L. Hudson: J. Chem. Phys. 67, 3040 (1977)ADSCrossRefGoogle Scholar
  24. 23.
    M. Marek, I. Stuchl: Biophys. Chem. 3, 241 (1975)CrossRefGoogle Scholar
  25. 24.
    Y. Sawada: private communicationGoogle Scholar
  26. 25.
    K. Showalter: private communicationGoogle Scholar
  27. 26.
    W. Geiseler, H.H. Föllner: Biophys. Chem. 6, 107 (1977)CrossRefGoogle Scholar
  28. 27.
    K. Bar-Eli, R.M. Noyes: J. Phys. Chem. 81, 1988 (1977)CrossRefGoogle Scholar
  29. 28.
    K. Bar-Eli, R.M. Noyes: J. Phys. Chem. 82, 1352 (1978)CrossRefGoogle Scholar
  30. 29.
    P. de Kepper, A. Rossi, A. Pacault: C.R. Hebd. Seances Acad. Sci. 283C, 371 (1976)Google Scholar
  31. 30.
    E. Körös, M. Orbán: Nature 273, 371 (1978)ADSCrossRefGoogle Scholar
  32. 31.
    K.R. Sharma, R.M. Noyes: J. Am. Chem. Soc. 98, 4345 (1976)CrossRefGoogle Scholar
  33. 32.
    D. Edelson, R.M. Noyes: J. Phys. Chem. (submitted)Google Scholar
  34. 33.
    T.S. Briggs, W.C. Rauscher: J. Chem. Education 50, 496 (1973)ADSCrossRefGoogle Scholar
  35. 34.
    A. Pacault, P. de Kepper, P. Hanusse, A. Rossi: C.R. Hebd. Seances Acad. Sci. 281C, 215 (1975)Google Scholar
  36. 35.
    P. de Kepper, A. Pacault: C.R. Hebd. Seances Acad. Sci. 282C, 199 (1976)Google Scholar
  37. 36.
    P. de Kepper: C.R. Hebd. Seances Acad. Sci. 283C, 25 (1976)Google Scholar
  38. 37.
    J.-C. Roux, C. Vidal: C.R. Hebd. Seances Acad. Sci. 284C, 293 (1977)Google Scholar
  39. 38.
    C. Vidal, J.-C. Roux, A. Rossi: C.R. Hebd. Seances Acad. Sci. 284C, 585 (1977)Google Scholar
  40. 39.
    K. Showalter, R.M. Noyes: J. Am. Chem. Soc. 100, 1042 (1978)CrossRefGoogle Scholar
  41. 40.
    H. Degn: European Molecular Biology Organization Workshop, Dortmund, October 4–6, 1976Google Scholar
  42. 41.
    K. Smith, R.M. Noyes: unpublishedGoogle Scholar
  43. 42.
    P.G. Dickens, J.E. Dove, J.W. Linnett: Trans. Faraday Soc. 60, 539 (1964)CrossRefGoogle Scholar
  44. 43.
    M.J. Pilling, R.M. Noyes: Internat. J. Chem. Kinetics (submitted)Google Scholar
  45. 44.
    A.R. McBirney, R.M. Noyes: J. Petrology (in press)Google Scholar
  46. 45.
    P. Schmid, R.M. Noyes: unpublishedGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 1979

Authors and Affiliations

  • R. M. Noyes

There are no affiliations available

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