Abstract
There has always been great interest in the limits of applicability of statistical mechanics. For example the point is often made that statistical concepts describe macroscopic systems very well. On the other hand, a tiny dynamical system such as a single isolated molecule may behave in a non-ergodic manner.
Research supported by Joint Services Electronics Program and Office of Naval Research.
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References
For a review, see N. Bloembergen and E. Yablonovitch, Phys. Today 31, No. 5, 23 (May 1978).
R.S. McDowell, J.P. Aldridge and R.F. Holland, J. Phys. Chem. 80, 1203 (1976).
H. Kildal, J. Chem. Phys. 67, 1287 (1977).
A.V. Nowak and J.L. Lyman, J. Quant. Spectr. Rad. Transf., 15, 1945 (1975).
J.F. Bott, Appl. Phys. Lett. 32, 624 (1978).
E. Yablonovitch, Opt. Lett. 1, 87 (1977).
H.S. Kwok and E. Yablonovitch, Appl. Phys. Lett. 30, 158 (1977).
E. Yablonovitch and J. Goldhar, Appl. Phys. Lett. 25, 580 (1974).
S.L. Shapiro (ed.): Ultrashort Light Pulses, Topics in Applied Physics, Vol.18 (Springer, Berlin, Heidelberg, New York 1977).
D.S. Frankel, Jr., J. Chem. Phys. 65, 1696 (1976).
R.S. Taylor, T.A. Znotin, E.A. Ballik and B.K. Garside, J. Appl. Phys. 48, 4435 (1977).
T.F. Deutsch and S.R.J. Brueck, to be published.
F. Keilmann, Appl. Phys. 14, 29 (1977).
The measured energy deposited with pump pulses of varying duration in the picosecond range will be discussed in a forthcoming paper. H.S. Kwok and E. Yablonovitch, to be published.
The scan in Fig.5(c) was actually taken with the P(28) line of the CO2 laser since the ν3 resonance was temperature shifted by preheating. All other scans were made at P(20).
The usual condition for adiabatic decay of a given level population in Δω/ΔωL >> l where Δω is the frequency mismatch and ΔωL is the laser linewidth.
J.G. Black, E. Yablonovitch, N. Bloembergen and S. Mukamel, Phys. Rev. Lett. 38, 1131 (1977).
The anharmonic shift observed by W. Fuss, J. Hartmann, and W.E. Schmid, Appl. Phys. 15, 297 (1978), is consistent with the deposited energy being distributed among all the modes rather than localized in ν3.
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Kwok, H.S., Yablonovitch, E. (1978). Collisionless Intramolecular Vibrational Relaxation in SF6 . In: Shank, C.V., Ippen, E.P., Shapiro, S.L. (eds) Picosecond Phenomena. Springer Series in Chemical Physics, vol 4. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-67099-2_42
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DOI: https://doi.org/10.1007/978-3-642-67099-2_42
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