Abstract
The preparation and investigation of boron compounds containing two-coordinate boron is still a great challenge for boron chemists. Until now this problem has been studied with limited success and only a few examples are known. The possibility of preparing cationic species of the type [R2N—B—NR2]+ by the reaction of (R2N)2BX with A1C13 or SbCl5 has been mentioned [68/57], but no report has appeared yet. The transition metal complexes [R2NBFe(CO)4] n or [BrBFe(CO)4] n may contain two-coordinate boron [70/15], but no structural data are available.
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© 1978 Springer-Verlag Berlin Heidelberg
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Nöth, H., Wrackmeyer, B. (1978). 11B NMR of Two-Coordinate Boron. In: Nöth, H., Wrackmeyer, B. (eds) Nuclear Magnetic Resonance Spectroscopy of Boron Compounds. NMR Basic Principles and Progress / NMR Grundlagen und Fortschritte, vol 14. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-66757-2_3
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DOI: https://doi.org/10.1007/978-3-642-66757-2_3
Publisher Name: Springer, Berlin, Heidelberg
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