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11B NMR of Two-Coordinate Boron

  • Heinrich Nöth
  • Bernd Wrackmeyer
Conference paper
Part of the NMR Basic Principles and Progress / NMR Grundlagen und Fortschritte book series (NMR, volume 14)

Abstract

The preparation and investigation of boron compounds containing two-coordinate boron is still a great challenge for boron chemists. Until now this problem has been studied with limited success and only a few examples are known. The possibility of preparing cationic species of the type [R2N—B—NR2]+ by the reaction of (R2N)2BX with A1C13 or SbCl5 has been mentioned [68/57], but no report has appeared yet. The transition metal complexes [R2NBFe(CO)4] n or [BrBFe(CO)4] n may contain two-coordinate boron [70/15], but no structural data are available.

Keywords

Nuclear Magnetic Resonance Structural Data Metal Complex Nuclear Magnetic Resonance Spectroscopy Magnetic Resonance Spectroscopy 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Copyright information

© Springer-Verlag Berlin Heidelberg 1978

Authors and Affiliations

  • Heinrich Nöth
    • 1
  • Bernd Wrackmeyer
    • 1
  1. 1.Institut für Anorganische ChemieUniversität MünchenMünchen 2Germany

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