II. The Nature of the Chemical Bond in Borides

  • G. V. Samsonov
  • B. A. Kovenskaya

Abstract

The character of the chemical bond between the atoms of a compound depends on its electronic structure.

Keywords

Titanium Magnesium Anisotropy Carbide Chromium 

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References

  1. ARABEY, B.G., GORYACHEV, YU.M., KOVENSKAYA, B.A.: Ob electronnom strojenii tetraboridov RZM yttrijevcj grouppy. J. Exp. Teoret. Chim. 10, 1012–1016 (1974)Google Scholar
  2. ARIA, R.M., MOROSOVA, M.P., SEMENOV, G.A., RYBAKOVA, G.A.: Mg-B sistema i opredelenije entalpii obrazovaniya Mg-Bχ J. Phys. Chim. 45, 181–182 (1971)Google Scholar
  3. BILTZ, H.: Über Elektronenzuständen von Hartstoffen mit Natrium-Chlorid-Struktur. Z.f. Physik 153, 338–358 (1958)CrossRefGoogle Scholar
  4. BLUM, P., BERTAUT, F.: To the investigation of borides with augmented contents of boron. Acta Cryst. 7, 81–86 (1954)CrossRefGoogle Scholar
  5. BUSCHOW, K.H.J., CREYGHTON, J.H.N.: Magnetic properties of rare earth tetraborides. J. Chem. Phys. 57, 3910–3916 (1972)CrossRefGoogle Scholar
  6. CADEVILLE, M.G., DANIEL, E.: Sur la structure électronique de certaines borures des métaux de transition. J. Phys. 27, 449–456 (1966)CrossRefGoogle Scholar
  7. Castaing, J.: Structure électronique et propriétés magnetiques des diborures des métaux de transition. Office national d’etudes et de recherches aerospatiales publ. N 140, Paris (1971)Google Scholar
  8. CASTAING, J., CANDRON, R., TOMPANCE, G., COSTA, P.: Electronic structure of the transition metals diborides. Solid State Commun. 7, 1453–1456 (1969)CrossRefGoogle Scholar
  9. Dempsey, E.: Bonding in the refractory hard metals. Phil. Mag. 8, 285–291 (1963)CrossRefGoogle Scholar
  10. ERN, V., SWITENDICK, A.C.: Electronic band structure of TiC, TiN and TiO. Phys. Rev. A137, 1927–1931 (1965)CrossRefGoogle Scholar
  11. FISCHER, J., FLODMARK, S.: Covalent B-B bonds in certain metal borides crystals. J. Chem. Phys. 22, 11–16 (1954)Google Scholar
  12. FISK, Z., COOPER, A.S., SCHMIDT, P.H., CASTELLANO, R.N.: Preparation and lattice parameters of the rare earth tetraborides. Mat. Res. Bull. 7, 285–291 (1972)CrossRefGoogle Scholar
  13. Flodmark, S.: Electrons distribution and energy bands in the metal borides. Arkiv Fysik 14, 513–516 (1959)Google Scholar
  14. GARF, E.S., GORYACHEV, YU.M., PADERNO, YU.B.: Redkozemelnyje metally i ikh sojedinjeniya, pp. 101–108. Kiev: Izdatjelstvo Naukova Dumka 1970Google Scholar
  15. GERMANIDZE, M.S., GELD, P.V., LJETUN, S.M.: Teplojemkost, entropiya i davlenije dissociacii dodecaborida magniya. J. Prik. Chim. 39, 1941–1944 (1966)Google Scholar
  16. GILLES, D.C., LEWIS, D.: Bond strength in certain group IV and group V metals diborides. J. Less-Common Metals 16, 162–171 (1968)CrossRefGoogle Scholar
  17. GOLDSCHMIDT, H.J.: Splavy vnedreniya, pp. 364–378. Moskwa: Izdatelstvo Mir 1971Google Scholar
  18. GORYACHEV, YU.M., KOVENSKAYA, B.A., ARABEY, B.G.: Electronnyj energeticheskij spectr tetraborida neodima. J. Exp. Teoret. Chim. 10, 862–868 (1974)Google Scholar
  19. GORYACHEV, YU.M., ODINTSOV, V.V., PADERNO, YU.B.: Structura energeticheskikh polos v kubicheskikh dodecaboridakh metallov. J. Prik. Chim. 12, 344–349 (1971)Google Scholar
  20. JAMAZAKI, M.: Calculation of energy bands in the metal borides MeB6 by the group theory method. J. Phys. Soc. Japan 12, 1–6 (1957)CrossRefGoogle Scholar
  21. JOHNSON, R.W., DAANE, A.H.: Electron requirements of bands in metal diborides. J. Chem. Phys. 38, 425–432 (1963)CrossRefGoogle Scholar
  22. JURETSCHKE, H., STEINITZ, P.I.: Hall effect and electrical conductivity of transition metals diborides. J. Phys. Chem. Sol. 4, 118–124 (1958)CrossRefGoogle Scholar
  23. KEIHN, F.G., KEPLIN, E.I.: High-temperature thermal expansion of certain group IV and group V diborides. J. Am. Ceram. Soc. 50, 81–86 (1967)CrossRefGoogle Scholar
  24. Kiessling, R.: Interstitial structures. Powd. Metallurg. Bull. 3, 177–184 (1959)Google Scholar
  25. KOVENSKAYA, B.A.: Issledovanije nekotorykh phisicheskikh svoistv electronnogo strojeniya boridov perekhodnykh metallov IV-VI groupp periodicheskoj sistemy. Avtoreferat Kandidats. Dissertacii, Kiev 1971Google Scholar
  26. KOVENSKAYA, B.A.: KOVENSKAYA, B.A.: Phisicheskije svoistva boridnykh phaz chroma. Izvestiya AN SSSR. Neorganicheskije Materialy N 12, 2134–2138 (1966)Google Scholar
  27. KOVENSKAYA, B.A., SEREBRYAKOVA, T.I.: Physicheskije svoistva boridnykh phaz niobia. Poroshkovaya Metal. N 5, 42–48 (1970)Google Scholar
  28. KUDINTSEVA, G.A., POLYAKOVA, M.D., SAMSONOV, G.B.: Prigotovljenije i nekotoryje svoistva geksaborida yttriya. Phys. Metal. Metal. 6, 272–275 (1958)Google Scholar
  29. KUENTZLER, R.: Structure électronique de borures des métaux de transition par mésures de chaleur spécifique. J. Phys. 32, 634–672 (1971)Google Scholar
  30. LIPSCOMB, W.N., BRITTON, D.: Valence structure of the higher borides. J. Chem. Phys. 33, 275–280 (1960)CrossRefGoogle Scholar
  31. LONGUET-HIGGINS, H.C., ROBERTS, M. de V.: The electronic structure of the MeB6 borides. Proc. Roy Soc. A224, 336–341 (1954)CrossRefGoogle Scholar
  32. L’VOV, S.N., NEMCHENKO, V.F., L’VOV, S.N.: Vysokotemperaturnyje neorganicheskije sojedinjeniya. pp. 445–451, Kiev: Izdatjelstvo Naukova Dumka 1965Google Scholar
  33. MARKEVICH, G.S., KONDRASHOV, YU.D., MARKOVSKII, L.YA.: O novoj boridnoj phazje v sistjemje berillij-bor. J. Neorganicheskoj chim. 5, 1783–1787 (1960)Google Scholar
  34. MARKEVICH, G.S., MARKOVSKII, L.YA.: O chimicheskoj stojkosti boridov berilliya po otnosheniju k kislorodu, azotu i ugljerodu pri vysokikh temperaturakh. J. Prik. Chim. 33, 1008–1012 (1960)Google Scholar
  35. MEERSON, G.A., ZHURAVLEV, N.N., MANELIS, R.M., RUNOV, A.D., STEPANOVA, A.A., GRISHINA, L.L., GRAMM, N.V.: Nekotoryje svojstva boridov yttriya. Izvestiya AN SSSR. Neorganicheskije Materialy N 2, 608–616 (1968)Google Scholar
  36. MOROSOVA, M.P., RYBAKOVA, G.A.: Entalpii obrazovanija di-i tetraboridov magniya. Trudy Gosudarstvennogo Inst. Prik. Chim. N 66, 35–41 (1970)Google Scholar
  37. NESHPOR, V.S., SAMSONOV, G.V.: Electrophysicheskije svoistva i kharacter svyazi v sojedinjeniyakh berilliya s borom i ugljerodom. Izvestiya AN SSSR. Neorganicheskije Materialy N 1, 50–54 (1971)Google Scholar
  38. ODINTSOV, V.V.: Poluchenije i nekotoryje physicheskije svoistva dodecaboridov so structuroj tipa UB12. Kiev: Avtoreferat kandidatskoj dissertacii 1971Google Scholar
  39. PADERNO, YU.B., GARF, E.S., NEMYSKY, T.: Electrophysicheskije svoistva plavlennykh geksaboridov shchjelochno- i redkozemelnykh metallov. Poroshkovaya Metal. N 10, 55–58 (1969)Google Scholar
  40. PIPER, J.: Galvanomagnetic effects in ZrB2 single crystals. J. Phys. Chem. Sol. 27, 1907–1910 (1966)CrossRefGoogle Scholar
  41. ROBINS, D.: Bonding in carbides, silicides and borides. Powd. Metal. Bull. 2, 172–176 (1958)Google Scholar
  42. RYBAKOVA, G.A.: Termokhimicheskoje izuchenije boridov berilliya i magniya. Leningrad: Avtoreferat Kandidat. Dissertacii 1972Google Scholar
  43. SAMSONOV, G.V., GORYACHEV, YU.M., KOVENSKAYA, B.A.: O nekotorykh osobjennostyakh temperaturnoj zavisimosti electrophisicheskikh svoistv Mo2B5 i W2B5. Doklady AN SSSR A10, 943–946 (1972)Google Scholar
  44. SAMSONOV, G.V., GORYACHEV, YU.M., KOVENSKAYA, D.A., ARABEY, B.G.: Raschjet energeticheskogo spektra tetraboridov tzeriya. J. Exp, Teoret. Chim. 10, 716–720 (1974)Google Scholar
  45. SAMSONOV, G.V., KOVENSKAYA, B.A., SEREBRYAKOVA, T.I.: O chimicheskoj svyazi v boridakh perekhodnykh metallov. Doklady AN SSSR A12, 976–980 (1971a)Google Scholar
  46. SAMSONOV, G.V., PADERNO, YU.B.: Boridy redkozemelnykh metallov. Kiev: Izdatjelstvo AN USSR 1961Google Scholar
  47. SAMSONOV, G.V., PRYADKO, I.F., PRYADKO, L.F.: Konfiguratsionnaya model veshchestva. Kiev: Izdatelstvo Naukova Dumka 1971bGoogle Scholar
  48. SEVERYANINA, E.N.: Poluchenije i issljedovanije physicheskikh svoistv tetraboridov redkozemelnych metallov. Kiev: Avtoreferat Kandidat. Dissertacii 1974Google Scholar
  49. TYAN, Y.S., TOTH, L.E., CHANG, Y.A.: A study of electrons transition theory in the hard-melting metals borides by the investigation of the low-temperature heat capacity. J. Phys. Chem. Sol. 30, 785–792 (1969)CrossRefGoogle Scholar
  50. VAHLDIEK, F.W.: Electrical resistivity, elastic modulus and Debye temperature of titanium diboride. J. Less-Common Metals 12, 209–212 (1967)Google Scholar
  51. ZHURAVLEV, N.N., BJELOUSOVA, I.A., MANELIS, R.M., BJELOUSOVA, N.A.: Rentgenographicheskoje opredjeljenije koefficientov termicheskogo rasshireniya boridov lantana i yttriya. Kristallographiya 15, 836–838 (1970)Google Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 1977

Authors and Affiliations

  • G. V. Samsonov
  • B. A. Kovenskaya

There are no affiliations available

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