Abstract
Over the last 25 years there has been a considerable change in the approach to solid-state crystal chemistry, mainly derived from thorough studies of a few transition metal oxide systems among them rutile — reduced and/or admixed with other oxides of lower valent metals, i.e. M2O3 + TiO2, where M = Ti or another trivalent cation. Structural progress was considerably accelerated by the application of the electron microscope and we will summarize some of this work. We demonstrate thereby the inherent weakness of X-ray diffraction and especially of powder techniques to study these systems.
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References
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Hyde, B.G. (1976). Rutile: Planar Defects and Derived Structures. In: Wenk, HR. (eds) Electron Microscopy in Mineralogy. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-66196-9_22
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DOI: https://doi.org/10.1007/978-3-642-66196-9_22
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