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Nuclear Magnetic Resonance Wide Line Studies of Water Sorption and Hydrogen Bonding in Cellulose

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Natural and Synthetic High Polymers

Abstract

Cellulose may be described as a poly-alcohol that is insoluble in water. The insolubility is due to the formation of strong intermolecular hydrogen bonding between hydroxyl groups. The association complex thus formed has, as a rule, a crystalline structure with a monoclinic unit cell, containing four anhydroglucose units. The space group is usually assumed to be P 2. The glucopyranose rings are joined in the b-axis direction by glucosidic valence bonds so that the unit cell contains 2 cellobiose units, the rings being essentially parallel to the (001)-plane. The chains contained in the (002)-plane are displaced so that an anhydroglucose ring is situated approximately at the centre of the cell and all the chains in this plane are assumed to be running in the opposite direction to those contained in the adjacent (001)-planes.

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References

  1. Liang, C. Y., Marchessault, R. H.: J. Polymer Sci. 37, 385 (1959)

    Article  CAS  Google Scholar 

  2. Liang, C. Y., Marchessault, R. H.: J. Polymer Sci. 43, 71 (1960).

    Article  Google Scholar 

  3. Mann, J., Marrinan, H. I.: J. Polymer Sci. 21, 301 (1956).

    Article  Google Scholar 

  4. Meyer, K. H., Misch, L.: Helv. Chim. Acta 20, 232 (1937).

    Article  CAS  Google Scholar 

  5. Cf. Hermans, P. H.: Physics and Chemistry of Cellulose Fibers, p. 13. New York: Elsevier 1949.

    Google Scholar 

  6. Carlström, D.: J. Biophys. Biochem. Cytol. 3, 669 (1957).

    Article  Google Scholar 

  7. Oberlin, M.: Thèse à la Faculté de Sciences de l’Université de Paris, Paris: Jouve, Editeurs 1960.

    Google Scholar 

  8. Hermans, P. H.: Kolloid-Z. 102, 169 (1943).

    Article  CAS  Google Scholar 

  9. Sumi, Y., Hale, R. D., RÃ¥nby, B. G.: Tappi 46, 126 (1963).

    CAS  Google Scholar 

  10. Hess, K., Kiessig, H.: Kolloid-Z. 130, 10 (1953).

    Article  Google Scholar 

  11. Hess, K., Mahl, H.: Naturwiss. 41, 68 (1954)

    Google Scholar 

  12. Hess, K., Mahl, H.: Naturwiss. 41, 86(1954).

    Google Scholar 

  13. Sakurada, I., Hutino, K.: Kolloid-Z. 77, 347 (1936).

    Article  Google Scholar 

  14. Hermans, P. H., Weidinger, A.: J. Colloid Sci. 1, 185 (1946).

    Article  CAS  Google Scholar 

  15. Hermans, P. H.: Contribution to the Physics of Cellulose Fibers. Amsterdam-New York: Elsevier 1946.

    Google Scholar 

  16. Treiber, E.: Die Chemie der Pflanzenzellwand, p. 157. Berlin-Göttingen-Heidelberg: Springer 1957.

    Google Scholar 

  17. McDonald, T. R. R., Beevers, C. A.: Acta Cryst. 5, 654 (1952).

    Article  CAS  Google Scholar 

  18. Ferrier, W. G.: Acta Cryst. 13, 678 (1960).

    Article  CAS  Google Scholar 

  19. Meyer, K. H., Misch, L.: Helv. Chim. Acta 20, 232 (1937).

    Article  CAS  Google Scholar 

  20. — Hermans, P. H.: Kolloid-Z. 102, 169 (1943).

    Article  CAS  Google Scholar 

  21. — Treiber, E.: Die Chemie der Pflanzenzellwand, p. 157. Berlin-Göttingen-Heidelberg: Springer 1957.

    Google Scholar 

  22. — Mann, J., Roldan-Gonzalez, L., Wellard, H. J.: J. Polymer Sci. 42, 165 (1960).

    Article  CAS  Google Scholar 

  23. — Jones, D. W.: J. Polymer Sci. 32, 371 (1958);

    Article  CAS  Google Scholar 

  24. — Jones, D. W.: J. Polymer Sci. 42, 173 (1960).

    Article  CAS  Google Scholar 

  25. — Bjørnhaug, A., Ellefsen, Ø., Tønnesen, B. A.: Norsk Skogsind. 6 (1953).

    Google Scholar 

  26. — Norman, N.: Textile Res. J. 33, 711 (1963).

    CAS  Google Scholar 

  27. — Petitpas, Th., Mering, J.: Compt. Rend. 243, 47 (1956);

    CAS  Google Scholar 

  28. — Oberlin, M.: Thèse à la Faculté de Sciences de l’Université de Paris. Paris: Jouve, Editeurs 1960.

    Google Scholar 

  29. Howsmon, J. A., Sisson, W. A.: Cellulose and Cellulose Derivatives, 2nd ed. Part 1, p. 321. Ott, Spurlin and Grafflin (editors). New York: Interscience Publishers, Inc. 1954.

    Google Scholar 

  30. Hermans, P. H.: Physics and Chemistry of Cellulose Fibres, p. 206 ff. New York 1949.

    Google Scholar 

  31. Cf. Anderson, D. M., Low, P. F.: Soil Sci. Soc. Am. Proc. 22, 99 (1958);

    Article  Google Scholar 

  32. — Forslind, E.: Rheology. Svensk Naturvetenskap 1966, p. 9 (a Progress Report (in Swedish)).

    Google Scholar 

  33. van Vleck, J. H.: Phys. Rev. 74, 1168 (1948)

    Article  Google Scholar 

  34. — Abragam, A.: The Principles of Nuclear Magnetism. Oxford 1961.

    Google Scholar 

  35. Hailwood, A. G., Horrobin, S.: Trans. Faraday Soc. 42B, 48 (1946). Cf. also Morton, I. E., Hearle, L W. S.: Phys. Prop. of Textile Fibres. London 1962.

    Google Scholar 

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Author information

Authors and Affiliations

  1. Nuclear Magnetic Resonance Group, The Royal Institute of Technology, Stockholm, Sweden

    E. Forslind

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  1. E. Forslind
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Editor information

Editors and Affiliations

  1. Physikalisches Institut, Universität Basel, Germany

    P. Diehl

  2. Institut für Anorganische Chemie, Universität Stuttgart, Germany

    E. Fluck

  3. Institut für Physikalische Chemie, Rhein.-Westf. Technischen Hochschule Aachen, Germany

    R. Kosfeld

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© 1971 Springer-Verlag Berlin Heidelberg

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Forslind, E. (1971). Nuclear Magnetic Resonance Wide Line Studies of Water Sorption and Hydrogen Bonding in Cellulose. In: Diehl, P., Fluck, E., Kosfeld, R. (eds) Natural and Synthetic High Polymers. NMR Basic Principles and Progress / NMR Grundlagen und Fortschritte, vol 4. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-65089-5_9

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  • DOI: https://doi.org/10.1007/978-3-642-65089-5_9

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-65091-8

  • Online ISBN: 978-3-642-65089-5

  • eBook Packages: Springer Book Archive

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