Research on Homopolymers and Copolymers of Propylene
The structure of a macromolecule may be considered as a detailed recording of catalytic events. Hence the determination of the microstructure of suitable macromolecules is a means to clarify the stereochemical polymerization mechanism. By this route we tackled some problems concerning the stereospecific polymerization of α-olefins. In particular, we will discuss some results concerning the mechanism of addition to the double bond and the steric control.
KeywordsMethylenic Proton Isotactic Polypropylene Sequence Distribution Syndiotactic Polypropylene Stereospecific Polymerization
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