Skip to main content

Part of the book series: Moderne Methoden der Pflanzenanalyse/Modern Methods of Plant Analysis ((PFLANZENANAL.,volume 3))

Abstract

Rubber and gutta are both polymers of isoprene and have the empirical formula (C5H8)n. There is one double bond for each unit. The rubber hydrocarbon possesses the cis configuration and gutta hydrocarbon the trans configuration (Meyer, 1950, p. 186; Davis and Blake, 1937, p. 119; Saunders and Smith, 1949). Balata or balata gutta has been shown to possess the trans configuration also (Hendricks, Wildman and Jones, 1947) and future references to gutta in this chapter will include balata. Both hydrocarbons react with halogens form compounds which in many respects are indistinguishalbe from each other. As is true of rubber, gutta is readily oxidized and this oxidation occurs rapidly in solution if the solvent readily absorbs oxygen. In contrast to rubber, gutta is very resistent to ozone (Davis and Blake, 1937). Violet and ultra-violet light catalyze the oxidation of both hydrocarbons.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

eBook
USD 16.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  • Addicott, F. T.: Stain Technology 19, 99–102 (1944).; Am. J. of Bot. 82, 520–6 (1945).— Allen, P. J., and R. Emerson: Ind. and Engng. Chem. 41, 346–65 (1949). — American Society of Testing Materials, Standards, Part 6, D 297–50 T. p. 47–82 (1952). — Anonymous. United States Department of Agriculture, Natural Rubber Research Station, Salinas, California. Procedures for the analysis of rubber bearing plants and related materials. — Artschweger, E.: United States Department of Agriculture, Tech. Bull. 842, 1–33 (1943). Contribution to the morphology and anatomy of guayule (Parthenium argentatum).

    Google Scholar 

  • Barron, H.: Modern Rubber Chemistry, New York: D. van Nostrand Co. 1948. — Benedict, H. M., P. M. Brooks and R. F. Puckett: Plant Physiol. 25,120–34 (1950). — Bonner, J., and B. Arreguin: Arch, of Biochem. 21, 109-24 (1949). — Buehrer, T. F., and L. Benson: University of Arizona, College of Agriculture, Tech. Bull. 108 (1945). Rubber content of native plants of the Southwestern Desert. — Burchfield, H. P.: Ind. and Engng. Chem. Analyt. Ed. 16, 424–6 (1944); 17, 806–810 (1945).

    Google Scholar 

  • Davis, C. C., and J. T. Blake: The Chemistry and Technology of Rubber, New York: Reinhold Publishing Co. 1937.

    Google Scholar 

  • Fanning, R. J.,and N. Bekkedahl: Analyt. Chem. 23,1653–6 (1951). — Fendler, G.: Ber. Deutsch. Pharm. Ges. 14, 208 (1904). — Fox, C. P.: Ind. and Engng. Chem. 1, 735–6 (1909).

    Article  Google Scholar 

  • Gerke, H. R., et al.: Ind. and Engng. Chem. Analyt. Ed. 11, 593–7 (1939). — Gowans, W. J., and F. E. Clark: Analyt. Chem. 24, 529–533 (1952).

    Article  Google Scholar 

  • Haasis, F. W.: Ind. and Engng. Chem. Analyt. Ed. 16,480–1 (1944). — Hall, H. M., and T. H. Goodspeed: University of California Publications in Botany 7,159–278 (1919). A rubber plant survey of western North America. — Hendricks, S. B., S. G. Wildman and E. J. Jones: Rubber Chem. and Technol. 19,501–9 (1946). — Holmes, R. L., and H. W. Robbins: Analyt. Chem. 19,313–7(1947). — Hoover, S. R., T. J. Dietz, J. Naghski and J. W. White: Ind. and Engng. Chem. 87,803–9 (1945).

    Article  CAS  Google Scholar 

  • Kemp, A. R., and H. Peters: Ind. and Engng. Chem. 88, 1391–8 (1941).

    Article  Google Scholar 

  • Lloyd, F. E.: Carnegie Institute of Washington, Publication No. 139, 1–213 (1911). Guayule (Parthenium argentatum Gray) a rubber plant of the Chihuahuan desert.

    Google Scholar 

  • Maher, W. C.: Stanford Research Institute, July 1947. Report of Natural Rubber Research Project. — Martin, G.: India Rubber Journ. 108, 1 (1943). — McGavack, J., and P. Faulks: Rubber Age 58, 204–6 (1945). — Meeks, J. W., T. F. Bannigan Jr. and R. W. Planck: India Rubber World 122, 301–4 (1950). — Meeks, J. W., R. V. Crook, C. E. Pardo and F. E. Clark: Paper presented at meeting of the Rubber Division of the American Chemical Society, Los Angeles, March 1953. — Meyer, K. H.: Natural and Synthetic High Polymers, 2nd edition. New York: Interscience Publishers Inc. 1950.

    Google Scholar 

  • Ross, W. H., and J. O. Hardesty: Journ. ASS. Off. Agric. Chem. 25, 238–46 (1942).

    CAS  Google Scholar 

  • Saunders, R. A., and D.C. Smith: J. Appl. Physics 20,953–65 (1949). — Schlesinger, W., and H. M. Leper: Ind. and Engng. Chem. 43, 398–402 (1951). — Shaternikova, A. N., and I. V. Berg: Soviet Botan. 15,161–3 (1947). — Skau, E., et al.: J. of Physical Chem. 49,304–15(1945). — Spence, D.: Gummi Ztg. 22,188(1908). — Spence, D., and M. L. Caldwell: Ind. and Engng. Chem. Analyt. Ed. 5,371–5 (1933). — Stewart, W. S., and R. W. Hummer: Bot. Gaz. 106, 333–40 (1944).

    Article  CAS  Google Scholar 

  • Traub, H. P.: United States Department of Agriculture, Tech. Bull. 920, 1–37 (1946). Rapid photometric methods for determining rubber and resins in guayule tissue and rubber in crude rubber products.

    Google Scholar 

  • Whittelsey, T.: J. Ind. Engng. Chem. 1,245–9 (1909). — Whittenberger, R. T.: Stain Technology 19,93–8 (1944). — Willits, C. O., C. L. Ogg, W. L. Porter and M. L. Swain: J. Ass. Off. Agric. Chem. 29,370–87 (1946). — Willits, C. O., M. L. Swain and C. L. Ogg: Ind. and Engng. Chem. Analyt. Ed. 18,439–42 (1946).

    Article  Google Scholar 

Download references

Authors

Editor information

K. Paech M. V. Tracey

Rights and permissions

Reprints and permissions

Copyright information

© 1955 Springer-Verlag OHG.

About this chapter

Cite this chapter

Benedict, H.M. (1955). The Determination of Rubber and Gutta in Plants. In: Paech, K., Tracey, M.V. (eds) Moderne Methoden der Pflanzenanalyse/Modern Methods of Plant Analysis. Moderne Methoden der Pflanzenanalyse/Modern Methods of Plant Analysis, vol 3. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-64958-5_6

Download citation

  • DOI: https://doi.org/10.1007/978-3-642-64958-5_6

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-64960-8

  • Online ISBN: 978-3-642-64958-5

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics